苯磺酰苯胺类药物理化性能的研究

利用高效液相色谱和分光光度法，研究了新合成的5个苯磺酰苯胺类化合物的酸离解常数和脂溶性，结果表明，他们具有较弱的酸性和合适的脂溶性。预计会有较好的抗肝片吸虫活性。     

有向全图的幂敛指数和周期

设G是有向图,T(G)表示G的有向全图.本文得到了它们的幂敛指数k(G)和k(T)之间的关系:对任何有向图G,周期p(T(G))=1;当G是本原图时,k(T)≤k(G)+1,文中给出了取得k(G)+1的两类图;当G是无圈图时,k(T)=2k(G)-1,当G是有向圈时,k(T)=2|V(G)|-1,当G是强连通时得到了k(T)的一些估计.     

化学非平衡夸克-胶子物质中等质量双轻子的产生

研究了正在进行化学平衡的富重子夸克-胶子物质的双轻子产生，发现由于产生在RHIC能量 的化学非平衡的富重子夸克-胶子物质冷却慢和高的初始温度，导致中等质量双轻子产生重 大增强.因此，中等质量双轻子的增强可以是夸克-胶子物质形成的信号.同时，这个增强能 补偿由于初始夸克化学势增加引起的双轻子抑制，因而双轻子产额的抑制不再是夸克-胶子 物质产生的信号. 关键词： 化学非平衡夸克-胶子物质 热粲夸克 双轻子     

小阶跃反应性输入时点堆中子动力学方程的解析解

对小阶跃反应性输入（0<ρ,０<β）且有温度反馈时点堆中子动力学方程进行了研究. 导出任意初始功率条件下核反应堆功率、反应性与时间的解析表达式. 分析和讨论了初始功率与输入小阶跃反应性的大小对功率、反应性变化规律的影响，得到了一些新的结果. 关键词： 中子动力学 反应性 点堆 温度反馈     

激光沉积超导薄膜过程中出射粒子速度的飞行时间谱分析

采用飞行时间谱技术,测量了准分子激光烧蚀沉积高温超导薄膜过程中,由靶面出射粒子的飞行速度。研究了粒子速度与充氧压及其激光能量密度的关系。讨论了高能粒子在薄膜原位低温外延生长中的作用。     

约束系统量子化中Dirac方法与Faddeev-Jackiw方法的等价性

对约束系统量子化中Dirac方法和 Faddeev-Jackiw方法进行了讨论，并对它们的运动方程、正则量子化的等价性进行证明.找出了两种方法中约束的对应关系. 关键词： Faddeev-Jackiw方法 Dirac方法 约束系统 正则量子化     

利用光纤数字同步传送网2.048 Mbit/s支路传送高精度标准时间信号

首次提出一种利用光同步数字传送网的2.048Mbit/s信号传送高精度时间编码信号的方法和实验结果。它可以使整个通信网的交换机、计费系统、网管系统、基站控制器等设备实现与UTC的时间同步。目前的实验证明,时间同步的不确定度优于±5μs。     

Direct imaging of a high-power diode laser cavity using a transparent indium-tin-oxide (ITO) contact

We describe a novel "see-through" indium-tin-oxide contact on the n-side of a high power unstable resonator semiconductor laser (URSL) that allows direct observation of the cavity during high power operation. Under optimized annealing conditions this transparent ITO contact has a low enough specific contact resistivity to permit normal high power CW operation of the URSL and allows the observation of filamentation. This contact scheme is applicable to a wide range of semiconductor lasers and is especially appropriate for high power devices. The same structure can also be used to obtain a 2-D thermal map of the laser cavity.     

Ab initio study on structure and phase transition of A- and B-type rare-earth sesquioxides Ln2O3 (Ln=La-Lu, Y, and Sc) based on density function theory

Ab initio energetic calculations based on the density functional theory (DFT) and projector augmented wave (PAW) pseudo-potentials method were performanced to determine the crystal structural parameters and phase transition data of the polymorphic rare-earth sesquioxides Ln₂O₃ (where Ln=La-Lu, Y, and Sc) with A-type (hexagonal) and B-type (monoclinic) configurations at ground state. The calculated results agree well with the limited experimental data and the critically assessed results. A set of systematic and self-consistent crystal structural parameters, energies and pressures of the phase transition were established for the whole series of the A- and B-type rare-earth sesquioxides Ln₂O₃. With the increase of the atomic number, the ionic radii of rare-earth elements Ln and the volumes of the sesquioxides Ln₂O₃ reflect the so-called “lanthanide contraction”. With the increase of the Ln³⁺-cation radius, the bulk modulus of Ln₂O₃ decreases and the polymorphic structures show a degenerative tendency.     

Synthesis of grafted poly(p‐phenyleneethynylene) with energy donor–acceptor architecture via atom transfer radical polymerization: Towards nonaggregating and hole‐facilitating light‐emitting material

In this contribution, we demonstrate a new effective methodology for constructing highly efficient and durable poly(p‐phenyleneethynylene) (PPE) containing emissive material with nonaggregating and hole‐facilitating properties through the introduction of hole‐transporting blocks into the PPE system as the grafting coils as well as building the energy donor–acceptor architecture between the grafting coils and the PPE backbone. Poly(2‐(carbazol‐9‐yl)ethyl methacrylate) (PCzEMA), herein, is chosen as the hole‐transporting blocks, and incorporated into the PPE system as the grafting coils via atom transfer radical polymerization. The chemical structure of the resultant copolymer, PPE‐g‐PCzEMA, was characterized by NMR and gel permeation chromatography, showing that the desirable copolymer was obtained with the narrow polydispersity. The increased thermal stability of PPE‐g‐PCzEMA was confirmed by thermogravimetric analysis and differential scanning calorimetry along with its macroinitiator. The optoelectronic properties of this copolymer were studied in detail by ultraviolet‐visible absorption, photoluminescence emission and excitation spectra, and cyclic voltammogram (CV). The results indicate that PPE‐g‐PCzEMA exhibits the solid‐state luminescent property dominated by individual lumophores, and also the energy transfer process from the PCzEMA blocks to the PPE backbone with a relatively higher energy transfer efficiency in the solid‐state compared to that of the solution state. Additionally, the hole‐injection property is greatly facilitated due to the presence of PCzEMA, as confirmed by CV profiles. All these data indicate that PPE‐g‐PCzEMA is a good candidate for use in optoelectronic devices. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3776–3787, 2007