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91.
Yun‐hui Wu Zhi‐fu Deng Ze‐fei Peng Rong‐min Zheng Shu‐qi Liu Shu‐ting Xing Jun‐yun Li De‐qun Huang Lan Liu 《Advanced functional materials》2019,29(36)
Low‐melting liquid metal is a hugely promising material for flexible conductive patterns due to its excellent conductivity and supercompliance, especially low‐cost and environmental liquid processing technology. However, the ever‐present fluidity characteristic greatly limits the stable shape and reliability of prepared liquid metal conductive electronics. Herein, a novel solidification strategy of liquid GaIn alloys by Ni doping and heat treatment is first reported, which can efficiently create a solid phase in the liquid metal and provide an effective solution for practical applications. Particularly, the liquid characteristic is preserved for conveniently fabricating different flexible electronic circuits, and then the solidification is carried out on prepared conductive patterns by heat treatment. The solidification mechanism is revealed by the interface chemical reaction between Ni and GaIn, creating the solid phase of intermetallic compound (Ga4Ni3 and InNi3) during heat treatment. Moreover, a biphasic GaInNi can be obtained by regulating the atomic ratio of gallium, indium, and nickel. As a result, the obtained GaInNi possesses extremely low sheet resistance (15 ± 4.5 to 135 ± 2.5 mΩ sq?1) and the variation of ΔR/R0 exhibits low level (0–2) when strained up to 100%, which offers a promising strategy to prepare stretchable and reliable liquid metal electronics. 相似文献
92.
Dake Hu Tianqi Zhao Xiaofan Ping Husong Zheng Lei Xing Xiaozhi Liu Jingying Zheng Lifei Sun Lin Gu Chenggang Tao Dong Wang Liying Jiao 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(21):7051-7055
Two‐dimensional (2D) PtSe2 shows the most prominent layer‐dependent electrical properties among various 2D materials and high catalytic activity for hydrogen evolution reaction (HER), and therefore, it is an ideal material for exploring the structure–activity correlations in 2D systems. Here, starting with the synthesis of single‐crystalline 2D PtSe2 with a controlled number of layers and probing the HER catalytic activity of individual flakes in micro electrochemical cells, we investigated the layer‐dependent HER catalytic activity of 2D PtSe2 from both theoretical and experimental perspectives. We clearly demonstrated how the number of layers affects the number of active sites, the electronic structures, and electrical properties of 2D PtSe2 flakes and thus alters their catalytic performance for HER. Our results also highlight the importance of efficient electron transfer in achieving optimum activity for ultrathin electrocatalysts. Our studies greatly enrich our understanding of the structure–activity correlations for 2D catalysts and provide new insight for the design and synthesis of ultrathin catalysts with high activity. 相似文献
93.
Biao Ma Peng Wu Xing Wang Zhengyu Wang Hai‐Xia Lin Hui‐Xiong Dai 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(38):13469-13473
A rhodium(III)‐catalyzed domino annulation of simple olefins with diazo oxindoles to give spirooxindole pyrrolone products is described. This reaction can be formally viewed as the result of an anomalous tandem C?H activation, carbene insertion, Lossen rearrangement, and a nucleophilic addition process. The potential utility of this reaction was further demonstrated by the late‐stage diversification of drug molecules. 相似文献
94.
本文是研制卫星电视接收站(TVRO)的技术总结.文中对系统G/T值、宽频带、解调门限、视频特性、伴音特性及平均无故障工作时间等六项主要技术关键进行了论述. 相似文献
95.
交叉定位模糊区的精确几何分析 总被引:1,自引:0,他引:1
针对近似几何方式无法准确衡量交叉定位误差的问题,研究了交叉定位模糊区与目标方位的关系。基于精确几何法展开分析,通过对模糊区与目标几何关系的研究,数学推导得出模糊区的完整数学表达,描述了模糊区面积的变化规律。模糊区面积的最小值出现在两个测向站附近,测向交叉点(θ1=π/6,θ2=5π/6)的模糊区面积是局部极值,并与近似几何方式的结论进行了对比,讨论了两者的适用范围。在特定条件下,近似几何分析可以代替精确几何分析。通过仿真验证了相关结论的合理性,从而可实现定位策略的优化。 相似文献
96.
本研究提出了一种采用增益芯片和光栅外腔的双波长可调谐半导体激光器。增益芯片采用了富铟团簇量子限制结构作为其量子限制结构,由于该结构独特的平顶增益特性,可以使激光器在双波长调谐范围内实现光强稳定。本研究中的谐振腔包括内部谐振腔和外部谐振腔,其中内部谐振腔由增益芯片的两个自然解理面构成,以支撑整个系统工作在特定波长。外部谐振腔由增益芯片的一个自然解理面和光栅构成,可实现969.1~977.9 nm的工作波长范围。最终该系统基于单个增益芯片和单个光栅实现了同步双波长输出,双波长的频率差在THz范围。本研究有望为实现双波长差频太赫兹源提供一种可能的解决方案。 相似文献
97.
98.
本文研究了DCS——偶氮胂与稀土的显色反应,在测定水中稀土时,用PMBP萃淋树脂分离干扰元素。用计算机处理实验数据,相关系数r=0.9992,分析结果令人满意。 相似文献
99.
100.
Isolating Reactions at the Picoliter Scale: Parallel Control of Reaction Kinetics at the Liquid–Liquid Interface 下载免费PDF全文
Gia Chuong Phan‐Quang Hiang Kwee Lee Prof. Xing Yi Ling 《Angewandte Chemie (International ed. in English)》2016,55(29):8304-8308
Miniaturized liquid–liquid interfacial reactors offer enhanced surface area and rapid confinement of compounds of opposite solubility, yet they are unable to provide in situ reaction monitoring at a molecular level at the interface. A picoreactor operative at the liquid–liquid interface is described, comprising plasmonic colloidosomes containing Ag octahedra strategically assembled at the water‐in‐decane emulsion interface. The plasmonic colloidosomes isolate ultrasmall amounts of solutions (<200 pL), allowing parallel monitoring of multiple reactions simultaneously. Using the surface‐enhanced Raman spectroscopy (SERS) technique, in situ monitoring of the interfacial protonation of dimethyl yellow (p‐dimethylaminoazobenzene (DY)) is performed, revealing an apparent rate constant of 0.09 min?1 for the first‐order reaction. The presence of isomeric products with similar physical properties is resolved, which would otherwise be indiscernible by other analytical methods. 相似文献