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991.
992.
建立了超声辅助提取/离子色谱法测定铬污染场地中铬(Ⅵ)的方法。选用0.3 mol/L的KCl溶液作提取剂,对12组土壤样品中的铬(Ⅵ)进行超声辅助提取20 min。采用Metrosep A Supp 4-250(250 mm×4.0mm)型阴离子分离柱,以4 mmol/L Na2CO3-1 mmol/L NaHCO3混合溶液为淋洗液对样品进行分离分析。铬(Ⅵ)在0.0120 mg/L浓度范围有较好的线性关系,相关系数(r2)为0.999 8;该方法的检出限为0.003 mg/L,加标回收率为96.4%106.8%,相对标准偏差(RSD,n=3)为0.56%。该方法具有简便、快速、准确等优点,适用于铬污染场地的监测与调查。 相似文献
993.
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995.
以氢化松香为原料、乙醇胺为有机胺、乙酸乙酯为溶剂,在超声波辅助下进行胺化反应制备氢化枞酸乙醇胺盐,再经萃取、重结晶和酸化得到氢化枞酸,采用正交试验考察了超声功率、搅拌转速、反应温度、反应时间对氢化枞酸纯度的影响,结果表明,影响氢化枞酸纯度因素按显著程度依次为反应温度>反应时间>超声波功率>搅拌转速,确定了最佳的胺化反应条件为:反应温度40℃、反应时间40min、超声波功率400W、搅拌转速400r/min,所得氢化枞酸的纯度为94.5%。采用GC、GC-MS、FT-IR、熔点仪和旋光仪对氢化枞酸产品进行了分析鉴定。 相似文献
996.
Lipid profiling of human plasma from peritoneal dialysis patients using an improved 2D (NP/RP) LC-QToF MS method 总被引:1,自引:0,他引:1
Min Li Baosheng Feng Yuan Liang Wei Zhang Yu Bai Wen Tang Tao Wang Huwei Liu 《Analytical and bioanalytical chemistry》2013,405(21):6629-6638
An improved online two-dimensional liquid chromatography-quadrupole time-of-flight mass spectrometry (2D LC-QToF MS) system was developed for the lipid profiling of human plasma, in which different lipid classes were separated by the first dimensional normal-phase (NP) LC and different lipid molecular species were separated by the second dimensional reversed-phase (RP) LC. This 2D LC-QToF MS system was built based on a ten-port, two-position valve as the interface, the conditions of which had been optimized and discussed in detail. As two loops were used to trap and transfer the first dimensional elute to the second dimension separately, this new interface suppressed the sample band broadening in the first dimensional column, increased the recovery and repeatability of 2D LC interface, and offered the possibility for the realization of not-stop-flow NP/RP 2D LC system. Finally, 190 endogenous lipid species out of 10 lipid classes were determined within a single run from the plasma of peritoneal patients. This method was also applied to identify the difference in lipid profile between plasma from peritoneal dialysis patients with bad volume status and peritoneal dialysis patients with good volume status. The discovery of 30 potential biomarkers would be helpful to the malnutrition, inflammation, and atherosclerosis syndrome investigation. 相似文献
997.
ZHAO MengMeng LI WanFang MA Xin FAN WeiZheng TAO XiaoMing LI XiaoMing XIE XiaoMin ZHANG ZhaoGuo 《中国科学:化学(英文版)》2013,56(3):342-348
Asymmetric hydrogenation of α-keto Weinreb amides has been realized with [Ru((S)-Sunphos)(benzene)Cl]Cl as the catalyst and CeCl 3·7H2O as the additive.A series of enantiopure α-hydroxy Weinreb amides(up to 97% ee) have been obtained.Catalytic amount of CeCl3·7H2O is essential for the high reactivity and enantioselectivity and the ratio of CeCl3·7H2O to [Ru((S)-Sunphos)(benzene)Cl]Cl plays an important role in the hydrogenation reaction. 相似文献
998.
Dr. Xuecheng Chen Dr. Krzysztof Kierzek Karolina Wenelska Krzystof Cendrowski Jiang Gong Dr. Xin Wen Prof. Tao Tang Prof. Paul K. Chu Prof. Ewa Mijowska 《化学:亚洲杂志》2013,8(11):2627-2633
Core–shell‐structured mesoporous silica spheres were prepared by using n‐octadecyltrimethoxysilane (C18TMS) as the surfactant. Hollow mesoporous carbon spheres with controllable diameters were fabricated from core–shell‐structured mesoporous silica sphere templates by chemical vapor deposition (CVD). By controlling the thickness of the silica shell, hollow carbon spheres (HCSs) with different diameters can be obtained. The use of ethylene as the carbon precursor in the CVD process produces the materials in a single step without the need to remove the surfactant. The mechanism of formation and the role played by the surfactant, C18TMS, are investigated. The materials have large potential in double‐layer supercapacitors, and their electrochemical properties were determined. HCSs with thicker mesoporous shells possess a larger surface area, which in turn increases their electrochemical capacitance. The samples prepared at a lower temperature also exhibit increased capacitance as a result of the Brunauer–Emmett–Teller (BET) area and larger pore size. 相似文献
999.
Yu‐Long Wang Meng Feng Xian Tao Qing‐Yun Tang Ying‐Zhong Shen 《Acta Crystallographica. Section C, Structural Chemistry》2013,69(1):25-28
The lanthanum(III) complexes tris(3,5‐diphenylpyrazolato‐κ2N,N′)tris(tetrahydrofuran‐κO)lanthanum(III) tetrahydrofuran monosolvate, [La(C15H11N2)3(C4H8O)3]·C4H8O, (I), and tris(3,5‐diphenyl‐1,2,4‐triazolato‐κ2N1,N2)tris(tetrahydrofuran‐κO)lanthanum(III), [La(C14H10N3)3(C4H8O)3], (II), both contain LaIII atoms coordinated by three heterocyclic ligands and three tetrahydrofuran ligands, but their coordination geometries differ. Complex (I) has a mer‐distorted octahedral geometry, while complex (II) has a fac‐distorted configuration. The difference in the coordination geometries and the existence of asymmetric La—N bonding in the two complexes is associated with intramolecular C—H...N/O interactions between the ligands. 相似文献
1000.