Chiral Salen Manganese Complex Immobilized on SBA-15： A New Heterogenized Enantioselective Catalyst for the Epoxidation of Alkenes

Jacobsen‘s catalyst was immobilized onto SBA-15 by multi-step grafting, and this heterogenized catalyst exhibited comparable catalytic performance with the corresponding homogeneous counterpart for the epoxidation of alkenes, and the catalyst could be recycled effectively several times.     

Studies on Solid State Reactions of Coordination Compounds（LXXI）──Solid State Reactions of o－Aminobenzoic Acid with Copper（Ⅱ） Acetate and Formate at Room Temperature

ＳｔｕｄｉｅｓｏｎＳｏｌｉｄＳｔａｔｅＲｅａｃｔｉｏｎｓｏｆＣｏｏｒｄｉｎａｔｉｏｎＣｏｍｐｏｕｎｄｓ（ＬＸＸＩ）──ＳｏｌｉｄＳｔａｔｅＲｅａｃｔｉｏｎｓｏｆｏ－ＡｍｉｎｏｂｅｎｚｏｉｃＡｃｉｄｗｉｔｈＣｏｐｐｅｒ（Ⅱ）ＡｃｅｔａｔｅａｎｄＦｏｒｍ...     

Li^＋／MgO上乙烷氧化脱氢制乙烯的研究（Ⅱ）：催化作用机理

借助ＸＲＤ、ＩＲ、ＴＧ等技术对Ｌｉ＾＋／ＭｇＯ进行了表征，结果表明，酸、碱中心的数目，强度、催化性与Ｌｉ＾＋的添加量相关 ，起酸碱作用的表面金属离子、表面低配位氧集团、Ｏ（Ｌ ｉ＾＋Ｏ＾－）是其反应的活性物种，反应机理可能由离子基、游离基协同完成。     

雷酚萜醇的结构研究

雷酚萜醇属雷公藤二萜类化合物。雷公藤(Tripterygium wilfordii Hook f)系卫矛科(Celastraceae)雷公藤属植物。民间用于治疗风湿病、抗炎、抗肿瘤及抑制免疫系统等。     

α碘-α-甲氧羰亚甲基三苯胂的合成及其与芳醛的反应

胂叶立德分子中砷原子是以4 d 轨道稳定α-碳负离子,比相应的膦叶立德具有更强的亲核性,甲氧羰亚甲基三苯胂能与醛、酮顺利反应。因此,研究稳定的胂叶立德更具有合成     

修饰剂结构对桥氧双核锰2，2＇－联吡啶配合物电化学的影响

修饰剂结构对桥氧双核锰２，２＇－联吡啶配合物电化学的影响吴丛笑，郑军伟，陆天虹（中国科学院长春应用化学研究所电分析化学开放实验室，长春，１３００２２）关键词桥氧双核锰２，２＇－联吡啶配合物，烟酸，异烟酸，２－羧酸吡啶锰酶在生物体系中作为一类重要的氧化...     

Zn/AlCl3促进下二硫醚与α,β-不饱和化合物的共轭加成

二芳基二硫醚与锌粉在DMF 中110 ℃反应, 生成二硫醚与锌的复合物; 后者在无水AlCl₃存在下与丙烯酸酯、丙烯腈反应分别生成β-芳硫基丙酸酯和相应的腈, 产率48%～91%.     

阿托伐他汀钙与β-环糊精相互作用的研究及应用

采用线性扫描伏安法和循环伏安法并结合紫外分光光度法研究了新型抗血脂紊乱药物阿托伐他汀钙(AC)与β-环糊精(-βCD)的相互作用.探讨了-βCD对AC的峰电流及AC对-βCD吸附峰电流的影响,测得在0.06mol/LKH2PO4-Na2HPO4(pH=7.17)缓冲溶液中,AC与-βCD包结比为1:1,用电流法测得包结物的形成常数为9.09×104L/mol.根据碱性介质条件下β-CD分子与AC形成包结物而使β-CD吸附峰电流减小的特性,建立了一种利用β-CD间接测定AC的伏安方法.     

Current Trend in Synthesis,Post‐Synthetic Modifications and Biological Applications of Nanometal‐Organic Frameworks (NMOFs)

Since the early reports of MOFs and their interesting properties, research involving these materials has grown wide in scope and applications. Various synthetic approaches have ensued in view of obtaining materials with optimised properties, the extensive scope of application spanning from energy, gas sorption, catalysis biological applications has meant exponentially evolved over the years. The far‐reaching synthetic and PSM approaches and porosity control possibilities have continued to serve as a motivation for research on these materials. With respect to the biological applications, MOFs have shown promise as good candidates in applications involving drug delivery, BioMOFs, sensing, imaging amongst others. Despite being a while away from successful entry into the market, observed results in sensing, drug delivery, and imaging put these materials on the spot light as candidates poised to usher in a revolution in biology. In this regard, this review article focuses current approaches in synthesis, post functionalization and biological applications of these materials with particular attention on drug delivery, imaging, sensing and BioMOFs.     

二水·2-羰基丙酸水杨酰腙合铜(Ⅱ)配合物的晶体结构及生物活性

在水中,以2-羰基丙酸水杨酰腙与硫酸铜反应,制得新配合物Cu(C₁₀H₈N₂O₄)(H₂O)₂(C₁₀H₈N₂O₄^2-为2-羰基丙酸水杨酰腙负离子),并以水为溶剂培养了单晶,测试了晶体结构,该单晶为深绿色,属单斜晶系,空间群为C2/c,晶胞参数a=1.1297(1)nm,b=0.9824(8)nm,c=2.1973(3)nm,β=91.91(8)°,V=2.43749(8)nm³,Z=8,μ=1.817mm^-1,D_c=1.743Mg·m^-3,F(000)=1304,R=0.0264,wR=0.0654,GOF=1.052。其测试结果表明在配合物中Cu²⁺处于五配位的四方锥配位环境,配位原子分别来自1个三齿配体2-羰基丙酸水杨酰腙负二价离子的2个O原子和1个N原子,2个水分子中的O原子,其中1个水分子的O原子处于四方锥的锥顶,锥底的配位原子基本处于同一平面上。对该配合物所作的皿内抑菌试验和盆栽活体实验表明,配合物对小麦条锈病、白菜黑斑病及辣椒疫霉菌等分别有96%、89%、100%的抑制率,且有一定的助长作用。