硅(100)非重构表面上乙炔吸附反应的理论研究

采用量于力学AM1半经验分子理论轨道方法计算了在Si(100)非重构光滑附氢表面上乙炔化学吸附反应过程中的体系生成热,由此得到各步骤反应的活化焓和反应热数值.结果表明,乙炔分子容易在Si(100)表面上形成稳定的双位σ键吸附.     

Three New Apianen lactones Compounds from Dioscorea Cirrhosa Lour

Dioscorea Cirrhosa Laour. which is a species of the Dioscorea, grows abundantly in southern and eastern China. Its roots are used in Chinese medicine as a remedy for various diseases, especially use for tumours and cancers. These results have prompted a search for its chemical constituents. Continuing out previous work,further studies on the constituents of the drug yielded three new compounds along with three known compounds in the EtOAc Fr of EtOH extraction.     

An Air‐Supported Liquid Crystal System for Real‐Time and Label‐Free Characterization of Phospholipases and Their Inhibitors

A new air‐supported liquid crystal (LC) system for analyzing interfacial phenomena that occur based on the molecular interaction between LCs and adsorbed molecules of interest at the aqueous/LC interface is reported. Compared with existing LC‐based detection systems, the miniature system reported here requires less sample and involves simpler preparation. Using this system, the enzymatic hydrolysis of various phospholipases such as phospholipase A₂ (PLA₂), phospholipase C (PLC) and phospholipase D (PLD) are characterized. The hydrolysis of phospholipid monolayers self‐assembled at aqueous/LC interface induces an orientational response from the LCs. As a result, an optical signal that reflects the spatial and temporal distribution of phospholipids during the enzymatic reaction can be generated in a real‐time manner. When well‐known phospholipase inhibitors are introduced together with respective phospholipases, no orientational response of LCs is observed. In the case of inhibitors MJ33 and compound 48/80, cross‐inhibitions among phospholipases are also observed. This work demonstrates that the air‐supported LC system provides a facile label‐free assay for characterizing phospholipase activities and for screening enzyme inhibitors. It could potentially be useful for different high throughput and cost‐effective enzyme screening assays.     

能量色散偏振X射线荧光光谱法测定生铁中锰和钛

探讨了应用能量色散偏振X射线荧光光谱仪测定生铁中锰和钛进行炉前快速分析的方法.对测定锰及钛时仪器的工作条件,试样的制备以及工作曲线的制作等因素作了较系统的试验,该方法所得测定结果与化学法测定结果或标样标准值相吻合,相对标准偏差小于1.5%,与化学法相比,锰和钛的测定时间由50 min缩短到2 min.     

改性Y型分子筛对硫醇硫醚的吸附脱除研究

通过液相离子交换法制备了Cu(I)Y、Ni Y、Ce Y分子筛,以XRD、低温N2吸附-脱附、NH3-TPD、吡啶红外Py-FTIR等方法对其进行物性表征。利用固定床技术、WK-2D微库伦仪及硫化学发光检测GC-SCD色谱评价了改性分子筛对于硫含量300μg/g模拟油(含硫化合物二丙硫醚、环己硫醇和1-庚硫醇与壬烷配制)及HDS汽油的吸附脱硫性能。结果表明,吸附剂对模拟油和HDS燃料油品中硫醇硫醚具有吸附效果,且改性后的分子筛在吸附脱硫过程中,强的B酸对于吸附脱硫有负作用,会使油品中硫醇硫醚发生催化反应,聚合的大分子硫化物遮盖及阻塞吸附活性位点,从而使吸附剂不能够完全地吸附硫化物,造成吸附硫容较小,而弱L酸无催化活性对吸附脱硫有正面影响。     

基于C8051F040的高性能CAN总线节点模块设计

经过分析CAN总线节点的功能,提出了CAN总线节点模块设计方案,介绍了典型C8051F040的CAN总线网络结构和CAN控制器结构,在硬件电路设计部分中,对模块实现原理及设计要点进行了详细的介绍,软件部分阐述了CAN总线节点模块的固件程序。给出了以此芯片为核心的CAN总线节点模块的应用层软件。设计的CAN总线节点模块功能强、性能高效,目前已经运用于工业现场使用的测量系统中。     

一种微带反射阵列天线单元特性研究

带开路短截线的贴片是微带反射阵列天线设计中最常用的单元形式之一。结合应用于民用航天领域的薄膜反射阵列天线设计,比较和分析不同物理参数、阵列环境下单元电讯性能变化特点,并优化设计单层薄膜反射阵列天线试验阵面,给出分析结果,供不同应用背景下的反射阵列天线设计参考。     

AODV routing overhead analysis based on link failure probability in MANET

This article puts forward an Ad-hoc on-demand distance vector routing(AODV)routing overhead analysis method in mobile Ad-hoc network(MANET).Although multiple routing protocols have been proposed to improve the performance,scarcely any paper analyzed the routing overhead caused by routing setup and maintenance processes in mathematical way.Routing overhead consumes part of network resources and limits the supported traffic in the network.For on-demand routing protocols like AODV,the routing overhead depends on the link failure probability to a great extent.This article analyzes the collision probability caused by hidden-node problem and the impact on link failure probability.In chain and rectangle scenarios,it presents a mathematical analysis of the theoretical routing overhead of AODV protocol based on link failure probability.Simulations on OPNET 14.5platform match well with the theoretical derivation which confirms the effectiveness of the analysis method.     

基于Allan方差的MEMS陀螺仪性能评价方法

介绍了Allan方差的基本定义,以及采用Allan方差对陀螺零偏数据进行处理所需的测试系统构成及测试要点。详细推导了采用Allan方差法对陀螺仪噪声进行估算的过程,描述了应用MATLAB进行数据处理平台建设的主要流程。最后运用Allan方差理论对MEMS陀螺信号进行了定量分析,得到了MEMS陀螺仪的量化噪声系数、角度随机游走系数、偏差不稳定性系数、速率随机游走系数和速率斜坡系数5个误差源系数,实验表明该方法能有效地辨识微机械陀螺的各项随机误差成分,可以正确评价陀螺仪的性能指标,为陀螺仪的设计改进提供了依据。