Effects of monomer structure on the morphology of polymer networks and the electro-optical properties of polymer-dispersed liquid crystal films

Polymer-dispersed liquid crystal (PDLC) films were prepared by photochemical polymerisation with a series of (meth)acrylate monomers. The effects of monomer structure on the morphology of polymer networks in the PDLC films were studied. The acrylate monomers without sidegroup chain formed uniform polymer networks. The methacrylate monomers with methyl as their sidegroup chains formed lace-like networks. The size of the LC droplets increased with increasing the length of the flexible chain of both methacrylate and acrylate monomers. Meanwhile, the effects of the morphology of the polymer network on the electro-optical properties of PDLC films were also investigated.     

Identification of metabolites in WZS‐miniature pig urine after oral administration of Danshen decoction by HPLC coupled with diode array detection with electrospray ionization tandem ion trap and time‐of‐flight mass spectrometry

Danshen (DS) is a widely used traditional Chinese medicine for treating cardiovascular and cerebrovascular diseases. A simple, rapid and sensitive method was developed for identification of the in vivo metabolites in urine of WZS‐miniature pigs after oral administration of DS decoction by HPLC coupled with diode array detection with electrospray ionization tandem ion trap and time‐of‐flight mass spectrometry. This method has been successfully applied to simultaneous identification of 50 compounds (including 11 new ones) in pig urine. In addition, one new compound, (3‐hydroxyphenyl) crylic acid glycine methyl ester (C1), along with eight known ones were first isolated by column chromatography and identified by spectroscopic means, including 1D/2DNMR and mass spectrometry, as reference substances. Ten phenolic compounds (protocatechuic aldehyde, protocatechuic acid, caffeic acid, danshensu, ferulic acid, isoferulic acid, rosmarinic acid and salvianolic acid A/B/D) were found to be the main absorbed original constituents of DS decoction, which underwent the metabolic reactions of glucuronidation, sulfation, methylation, hydrogenation and glycine conjugation in vivo. In conclusion, the developed method is applicable to the analysis and identification of constituents in biological matrices after administration of DS decoction. Copyright © 2012 John Wiley & Sons, Ltd.     

基于JC-5600ATE的单/双电源运算放大器测试方法

集成运算放大器具有成本低、功能多等优点,可广泛用于自动控制系统、测量仪表等其他电子设备中。近年来集成运放的指标在不断提高,性能也在不断提升,伴随着运算放大器的发展,对用来考核运算放大器指标的测试技术也提出了相应的要求,对测试系统(Automatic Testing Equipment,以下简称ATE)的性能要求也相应变高。阐述了单、双电源集成运算放大器在JC-5600ATE上的测试方法,并分析了两者的测试差异。     

浅析广州市花都区预防梅毒母婴传播的实施成效

目的了解花都区开展预防梅毒母婴传播阻断项目的实施成效,降低梅毒母婴传播率。方法对首次就诊的孕产妇进行梅毒筛查,对检出的梅毒阳性孕产妇进行规范治疗,并对其所生婴儿进行随访管理。结果 2012—2016年感染产妇孕期确诊率达71.18%,接受规范治疗率达53.02%,新生儿预防性治疗率75.8%,儿童3月龄梅毒检测率为50.86%,6月龄检测率42.55%。结论实施预防梅毒母婴传播项目,可以有效地阻断梅毒的母婴传播,降低梅毒母婴传播率,提高妇女儿童的健康水平。     

Approach for the Direct Synthesis of β-Dichlorosubstituted Acetanilides Using Iodine Trichloride (ICl3) as the Oxidant and Catalyst

A reliable method for direct synthesis of β‐dichlorosubstituted acetanilides is reported. The key transformation involves the oxidative and catalytic cleavage of a carbon‐carbon bond in the presence of iodine trichloride (ICl₃). In this protocol ICl₃ is used not only as the catalyst but also as the oxidant which widely broadens the scope of its application in organic synthetic chemistry.     

Efficient algorithm for calculating short cycles in Tanner graph based on matrix computation

Loop distribution of Tanner graph affects the BER performance of low-density parity-check codes(LDPC) decoding.To count short cycles in the Tanner graph efficiently,a side by side recursion algorithm based on matrix computation was proposed.Firstly,5 basic graph structures were defined to realize recursive calculate in the implementation process.Compared with previous works,the algorithm provided many methods for counting the same length of cycles.The same result confirmed the correctness of the algorithm.The new algorithm could not only calculate the total number of cycles,but also gave the number each edge participating in fixed-length cycles.Its complexity was proportional to the product of D and square of N,where D was the average degree of variable nodes,and N denoted the code length.For LDPC codes,D was far less than N.For most of the LDPC codes,the calculation for numbers of cycle-length g、g+2、g+4 was only several seconds.     

呼出气体酒精含量探测器检定的注意事项

介绍呼出气体酒精含量探测器的工作原理和国家标准对使用探测器的要求,为确保探测器有效准确的量值溯源,采用呼出气体酒精含量探测器自动检测系统进行检定。该系统能够解决标准气体不易保存和定值容易发生改变的难题,同时控制吹气压力,保证探测器采样的一致性,并列举了检定操作时应注意的问题和细节。     

Spectral resource defragmentation based on PCE in flexible bandwidth optical networks

The granularity of the flexible bandwidth optical network is the spectral slots,which is much smaller than that of the wavelength switch optical network.For the dynamic clients’ connections setup and tear down processes,it will give rise to fragmentation of spectral resources.It is the decline in the probability of finding sufficient contiguous spectrum for new connections that result in the fragmentation of spectral resource.To be more specific,these spectra may be unavailable and waste.In this case,the severe waste of the spectrum will lead to low efficiency in spectral utilization and will not adapt to large capacity requirements of transmission in the future.Because path computation element(PCE) framework has the characteristics of the central disposal and deployment of the spectrum resource,we construct the spectral resource allocation scenario based on PCE framework in the flexible bandwidth optical network to use spectrum resource effectively.Based on the principle of the generation of the fragmentation,we put forward a spectrum resource defragmentation algorithm to consolidate the available spectrum for clients’ connections.The simulation results indicate that this algorithm is able to reduce fragmentation of network,improve the continuity of spectral resource,reduce the blocking rate of services in the network and improve the spectral efficiency significantly.     

Organophosphine/phosphite‐stabilized silver(I) complexes bearing N‐acetylbenzamide ligand: synthesis,characterization and potential application in metal organic chemical vapor deposition

New N‐silver(I) acetylbenzamide complexes of type L_n?AgNC₉H₈O₂ (L = PPh₃; n = 1, 2a; n = 2, 2b; n = 3, 2c; L = P(OEt)₃; n = 1, 2d; n = 2, 2e; n = 3, 2f) were prepared. These complexes were obtained in high yields and characterized by elemental analysis, ¹H NMR, ¹³C{H} NMR, ³¹P{H} NMR and IR spectroscopy, respectively. The molecular structure of 2b has been determined by X‐ray single‐crystal analysis in which the silver atom is in a distorted tetrahedral geometry and crystallizes as cis–trans. New N‐silver(I) acetylbenzamide complexes have a four‐membered ring, which could influence their chemical and physical properties and modulate volatility. Metal organic chemical vapor deposition experiments were carried out successfully at 400°C and 450°C using 2e as precursor for the deposition of silver films, respectively. The high‐purity silver film obtained at 400°C is dense and homogeneous. Copyright © 2012 John Wiley & Sons, Ltd.