Can Polyelectrolyte Mechanical Properties be Directly Modulated by an Electric Field? A Molecular Dynamics Study

Multifunctionality in polymers facilitates their application in emerging technologies. Electrical fields are a preferred stimulus because of the speed and ease of application to bulk polymers. While a wide range of electrically triggered actuators are developed, and electrically controlled adhesion between gels is demonstrated, modification of bulk mechanical properties via electrical stimuli remains elusive. Polymers with covalently incorporated ionic charge (polyelectrolytes) should be well suited to achieving this goal since the mechanical properties depend on electrostatic interactions and these charges are intrinsically susceptible to electric fields. Molecular dynamics simulations are utilized here to investigate whether electric fields can modulate the mechanical properties of polyelectrolytes and to understand the governing mechanisms. Mechanical property modulation by electric field is found to be sensitive to the charge distribution—charges must be tightly attached to the polymer backbone, and responsivity is greater if a single backbone contains both positive and negative charges. The dominant mechanisms are reorientation and stretching of the polymer chains, which also elongate the ionic clusters to maintain strong electrostatic interactions throughout deformation. These insights are critical for future experimental realization of polymers with electric field regulated mechanical properties.     

Polymer and biopolymer mediated self-assembly of gold nanoparticles

Gold nanoparticle-polymer composites are versatile and diverse functional materials, with applications in optical, electronic and sensing devices. This tutorial review focuses on the use of polymers to control the assembly of gold nanoparticles. Examples of synthetic polymers and biopolymers are provided, as well as applications of the composite materials in sensing and memory devices.     

Electroosmotic flow analysis of a branched U-turn nanofluidic device

In this paper, we present the analysis of electroosmotic flow in a branched -turn nanofluidic device, which we developed for detection and sorting of single molecules. The device, where the channel depth is only 150 nm, is designed to optically detect fluorescence from a volume as small as 270 attolitres (al) with a common wide-field fluorescent setup. We use distilled water as the liquid, in which we dilute 110 nm fluorescent beads employed as tracer-particles. Quantitative imaging is used to characterize the pathlines and velocity distribution of the electroosmotic flow in the device. Due to the device's complex geometry, the electroosmotic flow cannot be solved analytically. Therefore we use numerical flow simulation to model our device. Our results show that the deviation between measured and simulated data can be explained by the measured Brownian motion of the tracer-particles, which was not incorporated in the simulation.     

Measuring the photon polarization in B -->Kpipigamma

We propose a way of measuring the photon polarization in radiative B decays into K resonance states decaying to Kpipi, which can test the standard model and probe new physics. The photon polarization is shown to be measured by the up-down asymmetry of the photon direction relative to the Kpipi decay plane in the K resonance rest frame. The integrated asymmetry in K1(1400)-->Kpipi, calculated to be 0.34 plus/minus 0.05 in the standard model, is measurable at currently operating B factories.     

Quasiparticle tunneling through a barrier in the fractional quantum hall regime

Tunneling of fractionally charged quasiparticles (QPs) through a barrier is considered in the context of a multiply connected geometry. In this geometry global constraints do not prohibit such a tunneling process. The tunneling amplitude is evaluated and the crossover from mesoscopic QP-dominated to electron-dominated tunneling as the system's size is increased is found. The presence of disorder enhances both electron and QP-tunneling rates.     

Berry phase in a nonisolated system

We investigate the effect of the environment on a Berry phase measurement involving a spin-half. We model the spin + environment using a biased spin-boson Hamiltonian with a time-dependent magnetic field. We find that, contrary to naive expectations, the Berry phase acquired by the spin can be observed, but only on time scales which are neither too short nor very long. However this Berry phase is not the same as for the isolated spin-half. It does not have a simple geometric interpretation in terms of the adiabatic evolution of either bare spin states or the dressed spin resonances. This result is crucial for proposed Berry phase measurements in superconducting nanocircuits.     

Tuning carbon nanotube band gaps with strain

We show that the band structure of a carbon nanotube (NT) can be dramatically altered by mechanical strain. We employ an atomic force microscope tip to simultaneously vary the NT strain and to electrostatically gate the tube. We show that strain can open a band gap in a metallic NT and modify the band gap in a semiconducting NT. Theoretical work predicts that band gap changes can range between +/-100 meV per 1% stretch, depending on NT chirality, and our measurements are consistent with this predicted range.