Switchable assembly of ultra narrow CdS nanowires and nanorods

We report on a simple route for the production of uniform and ultra narrow wurtzite CdS nanowires and nanorods. The nanorods are medium friendly (can exist in organic and aqueous phase) thus making them flexibly suitable for various applications. The centimeter range switchable ordering of the nanowires/rods into 3D microstrings by application of low magnitude DC electric field simply via two graphite electrodes is demonstrated. More sophisticated electrodes can be used for the same system to achieve more complex and fine patterns that can find potential use in nanoelectronics. The aligned microstrings (also wires/rods) show strong polarization dependence along their long axes. The polarized emission with respect to the unique c-axis makes the system suitable for orientation sensitive devices.     

Incoherent scatterer in a Luttinger liquid: a new paradigmatic limit

We address the problem of a Luttinger liquid with a scatterer that allows for both coherent and incoherent scattering channels. The asymptotic behavior at zero temperature is governed by a new stable fixed point: A Goldstone mode dominates the low energy dynamics, leading to universal behavior. This limit is marked by equal probabilities for forward and backward scattering. Notwithstanding this nontrivial scattering pattern, we find that the shot noise as well as cross-current correlations vanish. We thus present a paradigmatic picture of an impurity in the Luttinger model, alternative to the Kane-Fisher picture.     

The effect of a mild base on curcumin in methanol and ethanol

Steady-state and time-resolved emission techniques were employed to study the effect of acetate, a mild base, on the luminescence of curcumin in methanol and ethanol. We found that the steady-state emission intensity as well as the average fluorescence decay time are reduced by a factor of 5 when the acetate concentration is raised to about 1.8 M. We attribute this large effect to an excited-state proton transfer (ESPT) from the acidic groups of curcumin to the acetate anion. We analyze the experimental data in terms of an ESPT reaction occurring between a photoacid and a base.     

Heaviness in toral rotations

We investigate the dimension of the set of points H(A, α) in the d-torus which have the property that their orbit under rotation by some α hits a fixed closed target A more often than expected for all finite initial portions of time. An upper bound for the lower Minkowski dimension of this set is found in terms of the upper Minkowski dimension of ∂A:

An isoperimetric inequality for the Wiener sausage

Let (ξ(s)) _{s?≥ 0} be a standard Brownian motion in d?≥ 1 dimensions and let (D _s ) _{s ≥?0} be a collection of open sets in ${\mathbb{R}^d}$ . For each s, let B _s be a ball centered at 0 with vol(B _s ) =?vol(D _s ). We show that ${\mathbb{E}[\rm {vol}(\cup_{s \leq t}(\xi(s) + D_s))] \geq \mathbb{E}[\rm {vol}(\cup_{s \leq t}(\xi(s) + B_s))]}$ , for all t. In particular, this implies that the expected volume of the Wiener sausage increases when a drift is added to the Brownian motion.     

Nanoimprinted Polyethyleneimine: A Multimodal Template for Nanoparticle Assembly and Immobilization

Polyethyleneimine (PEI) is used as a scaffold for integrated top‐down/bottom‐up fabrication. In this synergistic strategy, patterned PEI surfaces are created using thermal nanoimprint lithography (NIL) using a sacrificial polystyrene (PS) overlayer. These imprinted surfaces act as versatile templates for assembling nanoparticles and dyes, with the amine groups of the PEI enabling electrostatic assembly, carbodiimide coupling, and dithiocarbamate attachment to the nanoimprinted features. The efficient assembly of particles and dyes is confirmed through fluorescence and atomic force microscopy. In these studies the PS overlayer serves two roles. First, the PS layer protects the PEI surface during the plasma‐etch removal of the residual layer of the NIL process. Second, the PS overlayer serves as a mask, enabling sequential functionalization of the sides and the tops of the PEI features.     

Adiabatic pumping in interacting systems

A dc current can be pumped through an interacting system by periodically varying two independent parameters such as the magnetic field and a gate potential. We present a general expression for the adiabatic pumping current in interacting systems, written in terms of instantaneous properties of the system at equilibrium, and find the limits of its applicability. This expression generalizes the scattering approach for noninteracting particles. We apply our formula for a quantum critical system that exhibits the two-channel Kondo effect, where single particle excitations are not well defined. We find that if the quantum critical point is contained in the pumping trajectory, the pumped spin between the channels approaches h, and if it is not contained in the trajectory, the spin approaches zero when the temperature T --> 0. We discuss the non-Fermi liquid features of this system at finite T.     

H2S Removal from Groundwater by Chemical Free Advanced Oxidation Process Using UV-C/VUV Radiation

Sulfide species may be present in groundwater due to natural processes or due to anthropogenic activity. H₂S contamination poses odor nuisance and may also lead to adverse health effects. Advanced oxidation processes (AOPs) are considered promising treatments for hydrogen-sulfide removal from water, but conventional AOPs usually require continuous chemical dosing, as well as post-treatment, when solid catalysts are applied. Vacuum-UV (VUV) radiation can generate ·OH in situ via water photolysis, initiating chemical-free AOP. The present study investigated the applicability of VUV-based AOP for removal of H₂S both in synthetic solutions and in real groundwater, comparing combined UV-C/VUV and UV-C only radiation in a continuous-flow reactor. In deionized water, H₂S degradation was much faster under the combined radiation, dominated by indirect photolysis, and indicated the formation of sulfite intermediates that convert to sulfate at high radiation doses. Sulfide was efficiently removed from natural groundwater by the two examined lamps, with no clear preference between them. However, in anoxic conditions, common in sulfide-containing groundwater, a small advantage for the combined lamp was observed. These results demonstrate the potential of utilizing VUV-based AOP for treating H₂S contamination in groundwater as a chemical-free treatment, which can be especially attractive to remote small treatment facilities.     

Helical liquids and Majorana bound states in quantum wires

We show that the combination of spin-orbit coupling with a Zeeman field or strong interactions may lead to the formation of a helical electron liquid in single-channel quantum wires, with spin and velocity perfectly correlated. We argue that zero-energy Majorana bound states are formed in various situations when such wires are situated in proximity to a conventional s-wave superconductor. This occurs when the external magnetic field, the superconducting gap, or, most simply, the chemical potential vary along the wire. These Majorana states do not require the presence of a vortex in the system. Experimental consequences of the helical liquid and the Majorana states are also discussed.