Nonamenable products are not treeable

LetX andY be infinite graphs such that the automorphism group ofX is nonamenable and the automorphism group ofY has an infinite orbit. We prove that there is no automorphism-invariant measure on the set of spanning trees in the direct productX×Y. This implies that the minimal spanning forest corresponding to i.i.d. edge-weights in such a product has infinitely many connected components almost surely. Research partially supported by NSF grant DMS-9803597.     

Intersection-equivalence of Brownian paths and certain branching processes

We show that sample paths of Brownian motion (and other stable processes) intersect the same sets as certain random Cantor sets constructed by a branching process. With this approach, the classical result that two independent Brownian paths in four dimensions do not intersect reduces to the dying out of a critical branching process, and estimates due to Lawler (1982) for the long-range intersection probability of several random walk paths, reduce to Kolmogrov's 1938 law for the lifetime of a critical branching process. Extensions to random walks with long jumps and applications to Hausdorff dimension are also derived.     

Biased Random Walks, Lyapunov Functions, and Stochastic Analysis of Best Fit Bin Packing

We study the average case performance of the Best Fit algorithm for on-line bin packing under the distributionU{j, k}, in which the item sizes are uniformly distributed in the discrete range {1/k, 2/k,…,j/k}. Our main result is that, in the casej = k − 2, the expected waste for an infinite stream of items remains bounded. This settles an open problem posed by Coffmanet al.[[4]]. It is also the first result which involves a detailed analysis of the infinite multidimensional Markov chain underlying the algorithm.     

Visibility preserving terrain simplification— an experimental study

The terrain surface simplification problem has been studied extensively, as it has important applications in geographic information systems and computer graphics. The goal is to obtain a new surface that is combinatorially as simple as possible, while maintaining a prescribed degree of similarity with the original input surface. Generally, the approximation error is measured with respect to distance (e.g., Hausdorff) from the original or with respect to visual similarity. In this paper, we propose a new method of simplifying terrain surfaces, designed specifically to maximize a new measure of quality based on preserving inter-point visibility relationships. Our work is motivated by various problems of terrain analysis that rely on inter-point visibility relationships, such as optimal antenna placement.

We have implemented our new method and give experimental evidence of its effectiveness in simplifying terrains according to our quality measure. We experimentally compare its performance with that of other leading simplification methods.     

Differential cryptanalysis of Lucifer

Differential cryptanalysis was introduced as an approach to analyze the security of DES-like cryptosystems. The first example of a DES-like cryptosystem was Lucifer, the direct predecessor of DES, which is still believed by many people to be much more secure than DES, since it has 128 key bits, and since no attacks against (the full variant of) Lucifer were ever reported in the cryptographic literature. In this paper we introduce a new extension of differential cryptanalysis, devised to extend the class of vulnerable cryptosystems. This new extension suggests key-dependent characteristics, calledconditional characteristics, selected to increase the characteristics' probabilities for keys in subsets of the key space. The application of conditional characteristics to Lucifer shows that more than half of the keys of Lucifer are insecure, and the attack requires about 2³⁶ complexity and chosen plaintexts to find these keys. The same extension can also be used to attack a new variant of DES, called RDES, which was designed to be immune against differential cryptanalysis. These new attacks flash new light on the design of DES, and show that the transition of Lucifer to DES strengthened the later cryptosystem.     

Fractional products of sets

For integers d > 1 and arbitrary 1 ? α ? d, α-products in d-fold Cartesian products are produced by probabilistic methods. Some explicit constructions are given by solutions of instances of the Turán problem for graphs.     

Temperature dependence of the fluorescence properties of curcumin

Steady-state and time-resolved techniques were employed to study the nonradiative process of curcumin dissolved in ethanol and 1-propanol in a wide range of temperatures. We found that the nonradiative rate constants at temperatures between 175-250 K qualitatively follow the same trend as the dielectric relaxation times of both neat solvents. We attribute the nonradiative process to solvent-controlled proton transfer. We also found a kinetic isotope effect on the nonradiative process rate constant of ~2. We propose a model in which the excited-state proton transfer breaks the planar hexagonal structure of the keto-enol center of the molecule. This, in turn, enhances the nonradiative process driven by the twist angle between the two phenol moieties.     

Pressure effect on the nonradiative process of thioflavin-T

Time-resolved emission techniques were employed to study the nonradiative process of thioflavin-T (ThT) in 1-propanol, 1-butanol, and 1-pentanol as a function of the hydrostatic pressure. Elevated hydrostatic pressure increases the alcohol viscosity, which in turn strongly influences the nonradiative rate of ThT. A diamond-anvil cell was used to increase the pressure up to 2.4 GPa. We found that the nonradiative rate constant, k(nr), decreases with pressure. We further found a remarkable linear correlation between a decrease in k(nr) (increase in the nonradiative lifetime, τ(nr)) and an increase in the solvent viscosity. The viscosity was varied by a factor of 1000 and k(nr) was measured at high pressures, at which the nonradiative rate constant of the molecules decreased from (7 ps)(-1) to (13 ns)(-1), (13 ps)(-1) to (17 ns)(-1) and (17 ps)(-1) to (15 ns)(-1) for 1-propanol, 1-butanol, and 1-pentanol, respectively. The viscosity-dependence of k(nr) is explained by the excited-state rotation rate of the two-ring systems, with respect to each other.     

Hierarchical superstructure of alkylamine-coated ZnS nanoparticle assemblies

We describe methodology for producing highly uniform, ordered and reproducible superstructures of surfactant-coated ZnS nanorod and nanowire assemblies, and propose a predictive multiscale "packing model" for superstructure formation based on electron microscopy and powder X-ray diffraction data on the superstructure, as well as on individual components of the nanostructured system. The studied nanoparticles showed a hierarchical structure starting from the individual faceted ZnS inorganic cores, onto which the crystalline surfactant molecules are adsorbed, to the superstructure of the nanoparticle arrays. Our results point out the critical role of the surfactant headgroup and polarity in nanoparticle assembly, and demonstrate the relationship between the molecular structure of the surfactant and the resulting superstructure of the nanoparticle assemblies.