二苯基(含硅烃基)锡化合物的合成及结构表征

合成了二苯基-[(乙基二甲基硅基)亚甲基]碘化锡和10个二苯基-[(乙基二甲基硅基)亚甲基]锡芳香酸酯,利用IR、1 H NMR、13 C NMR和元素分析对它们的分子结构进行了表征,结果显示中心锡原子为四配位的单体结构;生物活性测定的初步结果表明,该类化合物具有一定的杀螨活性。更多还原     

Variable-rate colour image quantization based on quadtree segmentation

A novel variable-sized block encoding with threshold control for colour image quantization (CIQ) is presented in this paper. In CIQ, the colour palette used has a great influence on the reconstructed image quality. Typically, a higher image quality and a larger storage cost are obtained when a larger-sized palette is used in CIQ. To cut down the storage cost while preserving quality of the reconstructed images, the threshold control policy for quadtree segmentation is used in this paper. Experimental results show that the proposed method adaptively provides desired bit rates while having better image qualities comparing to CIQ with the usage of multiple palettes of different sizes.     

二维正弦离散映射的分岔和吸引子

由一个正弦映射和一个三次方映射通过非线性耦合,构成一个新的二维正弦离散映射. 基于此二维正弦离散映射得到系统的不动点以及相应的特征值,分析了系统的稳定性,研究了系统的复杂非线性动力学行为及其吸引子的演变过程. 研究结果表明：此二维正弦离散映射中存在复杂的对称性破缺分岔、Hopf分岔、倍周期分岔和周期振荡快慢效应等非线性物理现象. 进一步根据控制变量变化时系统的分岔图、Lyapunov指数图和相轨迹图分析了系统的分岔模式共存、快慢周期振荡及其吸引子的演变过程,通过数值仿真验证了理论分析的正确性. 关键词： 正弦离散映射 对称性破缺分岔 Hopf分岔 吸引子     

Volume polarization holographic recording in thick phenanthrenequinone-doped poly(methyl methacrylate) photopolymer

Volume polarization holographic recording in phenanthrenequinone-doped poly (methyl methacrylate) photopolymer is obtained. Photoinduced birefringence in a 2 mm thick sample is measured by a phase-modulated ellipsometry. The birefringence induced in this material by linearly polarized beam at 514 nm reaches 1.2×10(-5). In addition, ability for recording volume polarization grating using two different polarization configurations is demonstrated and compared. The experimental results show that the diffraction efficiency of the hologram reaches to ～40% by using two orthogonal circularly polarized beams.     

Atomistic simulation of slow grain boundary motion

Existing atomistic simulation techniques to study grain boundary motion are usually limited to either high velocities or temperatures and are difficult to compare to realistic experimental conditions. Here we introduce an adapted simulation method that can access boundary velocities in the experimental range and extract mobilities in the zero driving force limit at temperatures as low as ～0.2T(m) (T(m) is the melting point). The method reveals three mechanistic regimes of boundary mobility at zero net velocity depending on the system temperature.     

SnS Nanosheets for 105th Harmonic Soliton Molecule Generation

As a member of the 2D group IV monochalcogenides (MX; M = Sn, Ge; X = S, Se), SnS has attracted great interest due to its outstanding optical, electrical, and optoelectronic properties. Especially, SnS nanosheets material have a large absorption coefficient and high photoelectric conversion efficiency, it can be potentially used in optical modulators, saturable absorbers, solar cells, supercapacitors, and other optical devices. However, the nonlinear optical properties of SnS nanosheets and their applications in ultrafast photonics are seldom studied. In this paper, the nonlinear optical properties of SnS nanosheets have been characterized through a dual‐balance detection system, whose modulation depth is 5.8%. More importantly, 105th harmonic soliton molecule based on SnS saturable absorbers has been realized for the first time to the authors’ knowledge. A compact mode‐locked fiber laser with a pulse duration of 1.02 ps and a repetition rate of 459 MHz is realized near 1.5 µm. It is demonstrated that SnS nanosheets have outstanding nonlinear properties and play an extremely important role in the field of ultrafast photonics.     

基于跳距修正L-M优化的WSN定位算法

针对DV-Hop定位算法在节点随机分布的网络拓扑环境下存在误差较大的问题,文中通过分析平均跳距估计、未知节点坐标估计区域求解对定位精度的影响,提出了一种基于跳距修正L-M优化的WSN定位算法CLDV-Hop(Correct L-M DV-Hop)。仿真结果表明,在不增加额外开销且仿真环境相同的条件下,CLDV-Hop算法比现有改进的算法具有更高的定位精度,与DV-Hop算法相比精度提高了约33%——41%。     

Boson peak in Sm-Al-Co ternary metallic glasses and its possible structural origin

The low temperature specific heat of Sm-Al-Co ternary metallic glasses is investigated and a clear anomaly associated with the Boson peak is identified. While this anomaly depends slightly on the chemical composition, it has no dependence on external magnetic field. To figure out the mechanism of the Boson peak, we interpret the data within various model frameworks. Unlike earlier work, our study shows that this Boson peak is mainly ascribed to an additional T² term of the specific heat, which may originate from the quasi-two-dimensional and short-range ordered structure units possibly existing in the metallic glasses.     

遮光罩内壁蜂窝结构单元的双向反射特性

内壁蜂窝结构是决定遮光罩杂散光抑制性能的主要因素,掌握其各向异性辐射传输特性对遮光罩的杂散光分析和优化设计具有重要意义.针对蜂窝结构单元,建立辐射传输模型,导出了表面双向反射分布函数的离散表达式;通过蒙特卡罗法模拟蜂窝结构单元的辐射传输过程,分析了几何参量和涂层反射率对等效面反射特性的影响;根据模拟所得双向反射分布函数数据库,建立了用于遮光罩杂散光分析的蜂窝结构等效面的反射特性概率模型.分析结果表明,蜂窝结构对杂散光呈现很强的后向散射特征,等效面的反射特性概率模型与直接模拟结果符合很好,可用于遮光罩杂散光分析和设计.