Facile solvent-free synthesis of pure-phased AlN nanowhiskers at a low temperature

Pure hexagonal aluminum nitride (AlN) nanowhiskers have been successfully synthesized by directly reacting AlCl₃ with NaN₃ in non-solvent system at the low temperature of 450 °C for 24 h. The obtained products are characterized by X-ray diffraction, field emission scanning electron microscopy, transmission electron microscopy, high-resolution transmission electron microscopy and selected area electron diffraction, which show that the obtained products are hexagonal phase AlN nanowhiskers with width from 10 to 80 nm and length up to several micrometers. The influencing factors of the formation of AlN nanowhiskers were discussed and a possible growth mechanism for AlN nanowhiskers was proposed. Additionally, the study on the corresponding optical properties and catalytic properties is also carried out.     

抗卟啉抗体与卟啉的协同作用

meso -四 (α ,α ,α ,α - 0 -苯乙酰苯 )卟啉诱导的单抗 (MAb)导致meso -四 (α,α ,α ,α - 0 -苯乙酰苯 )卟啉Soret带来巨大红移 ,并且在meso -四 (α ,α ,α ,α - 0 -苯乙酰苯 )卟啉上产生巨大的诱导Cotton效应 (ICD) .借用ICD定量分析meso -四 (α ,α ,α ,α - 0 -苯乙酰苯 )卟啉同抗体的结合 ,表明在抗体超过meso -四 (α ,α ,α ,α - 0 -苯乙酰苯 )卟啉的情况下 ,既有 1∶1结合 ,又有 2∶1结合〔结合位点 :meso -四 (α ,α ,α ,α - 0 -苯乙酰苯 )卟啉〕     

Solar-Driven Artificial Carbon Cycle

Constituting the artificial carbon cycle,for example,through recycling CO₂ and converting CH₄ to value-added fuels and chemicals with solar energy,offers a sustainable future for humankind to tackle the global environmental issues and energy crisis.However,significant bottlenecks remain in such photocatalytic conversion,mainly related to the reaction activity and product selectivity.Herein,we share our efforts and systematic research progress on addressing the double bottlenecks for achieving solar-driven artificial carbon cycle,with specifically focusing on the photocatalytic CO₂ and CH₄ conversion.We further elucidate the common fundamentals behind various designed photocatalytic materials systems.Toward future development,we highlight the opportunities and challenges in the research field.     

Effect of Ce<Superscript>3+</Superscript> on spectral characteristic of D1/D2/Cytb559 complex from spinach

It was studied by spectroscopy that PSII reaction center complex consisting of three polypeptides, D₁, D₂ and Cytb559, were purified from PSII particle of CeCl₃ treated spinach. The results of the experiment show that Ce³⁺ could improve the growth of spinach, and accelerate electron transport of PSII particles. Of chl-a of UV-Vis spectrum of D1/D2/Cytb559 complex, Soret band was blue-shifted by 3 nm and Q band by 2 nm, respectively, and the fluorescence emission peak was blue-shifted by 5 nm in CeCl₃-treated spinach compared with the one in control. By the extended X-ray absorption fine structure (EXAFS) spectroscopy methods, it has been found that Ce³⁺ is coordinated with 8 nitrogen atoms in the first coordination shell with Ce-N bond length of 0.253 nm, and Ce³⁺ with 6 oxygen atoms in the second coordination shell with Ce-O bond length of 0.32 nm. However, the secondary structure of D1/D2/Cytb559 complex by circular dichroism (CD) spectroscopy has no significant change after CeCl₃ treated. It might be that Ce³⁺ binds to porphyrin rings of chlorophyll and oxygen of amino acid residue of polypeptide in D1/D2/Cytb559 complex, and then accelerates the primary reaction of PSII, intensifies function of P680⁺ primary electron donor of D1/D2/Cytb559, but there is little change in conformation of PSII reaction center complex.     

基于点云空间分布特征的多级索引结构北大核心CSCD

为解决点云数据分布不规则、非均匀产生的查询效率低下的问题,提出了一种基于三维点云数据空间分布特征的多级索引结构。将点云空间信息引入传统八叉树,形成一种新的数据结构——方向八叉树,用于点云空间的全局划分。在每次划分空间之前,先对点云数据进行主成分分析,形成节点的方向包围盒,再进一步将空间划分为八个子空间。为了实现数据的快速调度与查询,在局部,使用KD树对方向八叉树的叶子节点进行二次组织构建。实验结果表明,方向八叉树能有效减少节点总数和冗余节点数量;方向八叉树和KD树的组合嵌套结构可以有效划分海量点云数据,实现点云数据的高效检索,对点云数据进行有效管理。     

双层伞状开孔的微测辐射热计红外吸收分析

建立了具有伞状吸收层结构的微测辐射热计探测单元的红外吸收模型。基于光学导纳矩阵法和阻抗匹配理论,采用三维电磁仿真软件CST,对伞状结构不同开孔尺寸和形状下模型的红外吸收特性进行了分析。结果表明,双层伞状开孔微测辐射热计光学性能与伞状结构开孔大小有密切的关系。该伞状微测辐射热计中引入开孔后,在保持较高的红外吸收特性的基础上,减少了探测单元热容,从而提升了器件响应速度。最终所得探测单元在8~14μm红外波段内的平均吸收率为85%,满足超大规模小像元非致冷红外焦平面探测器的设计要求。     

基于新型掺钪氮化铝的级联马赫-曾德尔结构(解)复用器

在新型掺钪(Sc)氮化铝(Al1-xScxN)集成光学平台上设计了插入损耗低、传输通道谱线平坦的O波段四通道波分(解)复用器,并提出了优化方法。所设计的器件结构基于级联马赫-曾德尔干涉仪(MZI)滤波器,结合弯曲波导结构的定向耦合器改善波长敏感度。针对粗波分复用(CWDM)应用的特性,文章使用粒子群算法(PSO)提升器件性能优化的效率,通过调整器件结构的设计参数对四路通道的传输谱线质量进行优化。针对0%,9%,23%的掺Sc浓度,设计的解复用器表现出宽达约15.6nm的1-dB带宽和小于0.1dB的插入损耗,传输谱线呈“盒状”响应,各通道间串扰均优于-30.6dB。     

FMQL45T900平台千兆以太网三层交换功能实现

随着以太网通信技术的发展,局域网子网间的通信业务增长迅速,而适用于子网间数据通信的传统路由器因为其转发速度慢、用户配置复杂等缺点,难以满足当前大量跨子网以及虚拟局域网之间通信数据量的需求。基于片上系统(System-on-Chip, SoC)平台FMQL45T900型号的FPGA芯片,采用VHDL硬件描述语言,自主研发了12端口的千兆以太网三层交换功能,并已在相应的硬件平台上进行了功能验证和性能测试。实验结果表明,基于固定长度链表的哈希查找方式实现简单、查找高效、复杂度低,该研究成果可在某些需要进行数据灵活交换的特殊的场景下进行应用。