全文获取类型
收费全文 | 14183篇 |
免费 | 1973篇 |
国内免费 | 1560篇 |
专业分类
化学 | 7708篇 |
晶体学 | 123篇 |
力学 | 696篇 |
综合类 | 69篇 |
数学 | 1316篇 |
物理学 | 3719篇 |
无线电 | 4085篇 |
出版年
2024年 | 69篇 |
2023年 | 414篇 |
2022年 | 470篇 |
2021年 | 567篇 |
2020年 | 569篇 |
2019年 | 570篇 |
2018年 | 482篇 |
2017年 | 483篇 |
2016年 | 606篇 |
2015年 | 667篇 |
2014年 | 775篇 |
2013年 | 1004篇 |
2012年 | 1097篇 |
2011年 | 1183篇 |
2010年 | 880篇 |
2009年 | 843篇 |
2008年 | 947篇 |
2007年 | 784篇 |
2006年 | 728篇 |
2005年 | 551篇 |
2004年 | 458篇 |
2003年 | 386篇 |
2002年 | 402篇 |
2001年 | 291篇 |
2000年 | 306篇 |
1999年 | 357篇 |
1998年 | 275篇 |
1997年 | 207篇 |
1996年 | 226篇 |
1995年 | 191篇 |
1994年 | 144篇 |
1993年 | 146篇 |
1992年 | 128篇 |
1991年 | 106篇 |
1990年 | 89篇 |
1989年 | 66篇 |
1988年 | 49篇 |
1987年 | 37篇 |
1986年 | 31篇 |
1985年 | 40篇 |
1984年 | 25篇 |
1983年 | 17篇 |
1982年 | 13篇 |
1981年 | 6篇 |
1980年 | 4篇 |
1978年 | 5篇 |
1976年 | 3篇 |
1975年 | 4篇 |
1973年 | 3篇 |
1957年 | 3篇 |
排序方式: 共有10000条查询结果,搜索用时 984 毫秒
11.
Jia Tian-Cong Guo Jin-Tao Wang Zhen Zhu Xiao-Shan Zhang Qian-Xin Chen Ping Yao Kun Lv Wen-Ying Liu Guo-Guang 《Journal of Radioanalytical and Nuclear Chemistry》2019,321(3):823-829
Journal of Radioanalytical and Nuclear Chemistry - In the present work the final products of coumarin radiation chemical transformation are investigated by chromatography. During radiolysis of... 相似文献
12.
Ding Q. Yao M. Wu Sh. Zeng M. Xue N. Wu D. Xu J. 《Journal of Applied Spectroscopy》2022,89(4):712-718
Journal of Applied Spectroscopy - Based on partial least squares (PLS) analysis, the effects of different smoothing points and different preprocessing methods on the accuracy and precision of the... 相似文献
13.
We propose a system of time-division multiplexing(TDM) and spatial frequency-division multiplexing(SFDM). Extrinsic Fabry–Perot interferometric sensors are applied to detect weak acoustic signals. The broadband source is employed, the light from it is modulated by a pulse signal sequence and is efficiently amplified by semiconductor optical amplifiers. Experimental results show that the equivalent noise pressure spectrum level is-97.2 d B re 1 rad/√Hz below 1250 Hz, and the cross talk between two sensors in one TDM channel is-32.7 d B with a cavity length difference of 60 μm. The number of sensors in this multiplexing system can theoretically reach 160. 相似文献
14.
Zhang Kailun Wu Hongjuan Wang Tian Yao Meng Xie Jixing Jiao Yunhong 《Journal of Thermal Analysis and Calorimetry》2021,145(6):3067-3075
Journal of Thermal Analysis and Calorimetry - A phosphazene-based flame retardant (PBFA) was synthesized by hexachlorocyclotriphosphazene and N-aminoethylpiperazine. To improve the flame retardancy... 相似文献
15.
基于深度学习的方法,在HL-2A装置上开发出了一套边缘局域模(ELM)实时识别算法。算法使用5200次放电数据(约24.19万数据切片)进行学习,得到一个深度为22层的卷积神经网络。为衡量算法的识别能力,识别了HL-2A装置自2009年实现稳定ELMy H模放电以来所有历史数据(约26000次放电数据),共识别出1665次H模放电,其中误识别35次,误报率为2.10%。在实际的1634次H模放电中,漏识别4次,漏识别率为0.24%。该误报率和漏报率可以满足ELM实时识别的精度要求。识别算法在实时控制环境下,对单个时间点的平均计算时间为0.46ms,可以满足实时控制的计算速度要求。 相似文献
16.
Chunhong Wang Qi Cui Zhixin Zhang Prof. Zhu-Jun Yao Dr. Shaozhong Wang Prof. Zhi-Xiang Yu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(42):9821-9826
1,3-Azaprotio transfer of propargylic α-ketocarboxylate oximes, a new type of alkynyl oximes featuring an ester tether, has been explored by taking advantage of gold catalysis. The incorporation of an oxygen atom to the chain of alkynyl oximes led to the formation of two different oxa-cyclic nitrones. It was found that internal alkynyl oximes with an E-configuration deliver five-membered nitrones, whereas terminal alkynyl oximes with an E-configuration afford six-membered nitrones. DFT calculations on four possible pathways supported a stepwise formation of C−N and C−H bonds, in which a 1,3-acyloxy-migration competes with the 1,3-azaprotio-transfer, especially in the case of internal alkynyl oximes. The relative nucleophilic properties of oxygen in the carbonyl group and the nitrogen in the oxime, the electronic effects of alkynes, and the influence of the ring system have been investigated computationally. 相似文献
17.
Inam Ridha Ali Basiri Sudhakar Godeshala Md Zubair Ebne Rafique Deepanjan Ghosh Jason Williams Nikhilesh Chawla Jung Keun Lee Jacquelyn Kilbourne Yu Yao Kaushal Rege 《Advanced functional materials》2021,31(6):2007811
Poor strength, infection, leakage, long procedure times, and inflammation limit the efficacy of common tissue sealing devices in surgeries and trauma. Light-activated sealing is attractive for tissue sealing and repair, and can be facilitated by the generation of local heat following absorption of nonionizing laser energy by chromophores. Here, the inherent ability of biomaterials is exploited to absorb nonionizing, mid-infrared (midIR) light in order to engender rapid photothermal sealing and repair of soft tissue wounds. In this approach, the biomaterial simultaneously acts as a photothermal convertor as well as a biosealant, which dispenses the need for exogeneous light-absorbing nanoparticles or dyes. Biomechanical recovery, mathematical modeling, histopathology analyses, tissue strain mapping using digital imaging correlation, and visualization of the biosealant-tissue interface using hyperspectral imaging indicate superior performance of midIR sealing in live mice compared to conventional sutures and glue. The midIR-biosealant approach demonstrates rapid sealing of soft tissues, improves cosmesis, lowers potential for scarring, obviates safety concerns because of the nonionizing light used, and allows adoption of a wide diversity of biomaterials. Taken together, the studies demonstrate a novel advance both in biomaterials for surgical sealing along with the use of nonionizing midIR light, with high potential for clinical translation. 相似文献
18.
Ping Chen Yanhong Hao Xinxin Wang Prof. Dr. Dan Yuan Prof. Dr. Yingming Yao Prof. Dr. Lutz Ackermann 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(30):7292-7297
Highly position selective alkylations of N-alkylindoles at C7-positions have been enabled by cationic zirconium complexes. The strategy provides a straightforward access to install alkyl groups at C7-positions of indoles without a complex directing group. Mechanistic studies provided support for the importance of Brønsted acids in the catalytic manifold. 相似文献
19.
Multimodality image registration via pixel migration is a powerful approach. However, it suffers from a serious problem--the global maximum on the sum of squared gradient magnitude (SSG) surface does not correspond to the correct solution of registration. To solve the problem, we partition the search space into feasible and infeasible regions. The genetic algorithm (global optimizer) is used to obtain a good initial estimate of registration parameters and followed by a fast refining with Powell's approach (local optimizer). The experimental results demonstrate that the use of this modified pixel migration algorithm on multisensor image registration is very effective. 相似文献
20.
Lei Zhou Yu-Dong Yao Heffes H. Ruifeng Zhang 《Wireless Communications, IEEE Transactions on》2006,5(4):779-788
A reduced-rate retransmission (RRR) scheme is proposed for improving the throughput performance of spread-spectrum packet radio networks. The scheme takes advantages of the available multi-rate scalable source coding techniques. It assumes that several versions of a data packet with different sizes (number of information bits) are available. The transmission of a packet starts from its full-size version. If the full-size version is not correctly received, its half-size version is used in the retransmission. If further retransmissions are needed, the quarter-size version and so on are used. The shrunk packets are transmitted either in a minislot if the processing gain is kept the same, or occupying a slot duration by increasing the processing gain proportionally. In both cases, the effective signal to interference ratio for a packet is increased. As a result, the system throughput is improved. Theoretical and numerical results are provided in this paper which illustrate the throughput improvement. Another advantage of the proposed RRR scheme is that the packet-size reduction provides finer granules for link adaptation. Therefore, it is especially suitable for multimedia applications for which codes of variable rate for the source data are available and which can tolerate gracefully degraded quality of service. The performance of the proposed scheme in fading channels is also addressed. 相似文献