氧化镧作为直接硼氢化物燃料电池阴极催化剂的研究

通过采用线性电势扫描(LSV)和恒电流计时电势扫描方法对氧化镧作为直接硼氢化物燃料电池阴极催化剂的电化学性能进行了研究.实验结果表明:在单室燃料电池体系中,氧化镧对氧还原具有良好的活性,同时在强碱溶液中对硼氢根离子具有很强的稳定性且对硼氢根的水解没有任何促进作用.以镍基储氢合金作为电池的阳极催化剂组装成简单的单室燃料电池,电池的开路电压达到1.052 V,在常温下(21℃),电池于0.491 V获得最高功率密度65.25 mW·cm-2,电池运行稳定.     

NdFeB材料微波吸收特性的研究

采用高能球磨和晶化热处理方法制备钕铁硼吸波粉体,研究制备工艺对钕铁硼粉体吸波性能的影响。结果发现:高能球磨和适当晶化热处理可改善NdFeB粉体的组织结构、复介电常数和复磁导率;NdFeB粉体的反射率最小值为-15.5 dB,高能球磨48 h后粉体的反射率最小值降到-23 dB,高能球磨粉体经600℃晶化热处理后反射率最小值为-19 dB;高能球磨和晶化热处理可降低NdFeB粉体的吸收峰频率;高能球磨会使NdFeB粉体的吸波带宽变窄,经600℃晶化热处理后吸波带宽变宽,并且随着晶化热处理的温度升高,吸波带宽变得更宽。     

尿素在ZnO(1010)表面的吸附

运用VASP(Vienna ab-initio simulation package),采用基于密度泛函理论(DFT)的第一原理计算,研究了尿素在ZnO(101軈0)表面的吸附行为.计算结果表明:尿素分子在ZnO(101軈0)表面主要发生分子吸附,稳定的吸附产物通过尿素分子中的氮原子或氧原子与表面锌原子之间的键合作用而形成,吸附能分别为-1.48和-1.41eV;表面吸附的尿素分子也可以发生解离,生成表面吸附的异氰酸根、氨气和一个表面羟基,吸附能为-1.66eV.     

Cu(L-His)2溶液配位结构的X射线吸收精细结构分析

采用X射线吸收精细结构分析(XAFS)方法分析Cu(His)₂复合物的配位模式,通过测定不同pH值下的铜的K边XAFS吸收谱,研究Cu(His)₂第一配位壳层的结构．为了更准确地验证Cu(His)₂配位结构,对组氨酸的羧基和咪唑分别进行了化学修饰．研究结果明确了在不同pH环境下组氨酸的羧基、氨基和咪唑的配位情况．对于争议最大的在生理pH值下组氨酸的配位方式,其结果更支持六配位模式,同时可能有少量的五配位模式配合物平衡存在.     

Long-term quantitative phase-contrast imaging of living cells by digital holographic microscopy

The dynamic analysis of biological living samples is one of the particular interests in life sciences. An improved digital holographic microscope for long-term quantitative phase-contrast imaging of living cells is presented in this paper. The optical configuration is optimized in the form of a free-space-fiber hybrid system which promotes the flexibility of imaging in complex or semi-enclosed experimental environment. Aberrations compensation is implemented taking into account the additional phase aberration induced by liquid culture medium in long-term observation. The proposed approach is applied to investigate living samples of MC3T3-E1 and MLO-Y4 cells. The experimental results demonstrate its availability in the analysis of cellular changes.     

In-band pumped Er:YAG ceramic laser with 11 W of output power at 1645 nm

We report on a high power polycrystalline Er:YAG ceramic laser in-band pumped by a cladding-pumped Er, Yb fiber laser wavelength locked at 1532 nm with a volume Bragg grating. Using 1.0 at % Er³⁺-doped ceramic as the gain medium and an output coupler of 10% transmission, the laser had a threshold pump power of ∼1.5 W and generated 11 W of continuous-wave output at 1645 nm for 23.3 W of incident pump power at 1532 nm, corresponding to a slope efficiency with respect to incident pump power of 51%.     

Long-lasting near-infrared persistent luminescence from β-Ga2O3:Cr nanowire assemblies

Near-infrared (NIR) persistent luminescent β-Ga₂O₃:Cr³⁺ nanowire assemblies were synthesized by a hydrothermal process followed by calcination. The phosphor exhibits more than 4 h afterglow in the wavelength range of 650-850 nm after ceasing the ultraviolet light (280-360 nm) irradiation. The trap structure and persistent luminescence mechanism were revealed by thermoluminescence measurement. The β-Ga₂O₃:Cr³⁺ nanowire assemblies may find applications as identification taggants in security and optical probes in bio-imaging.     

Tuning visible light generation based on multi-channel quasi-periodically poled LiTaO3

We demonstrate broadband tuning visible light generation based on a multi-channel quasi-periodically poled LiTaO₃ crystal, in which a quasi-phase matched optical parametric generation process and a quasi-phase matched sum-frequency mixing process were achieved simultaneously. The conversion characters on spectrum and energy were studied by using a nanosecond pulse laser at 1.064 μm as pump light. We could tune the visible light over ~ 26 nm by means of changing the crystal's channel and temperature. The ratio of the output wavelength variation to that of temperature was ~ 0.07 nm/°C. The single-pass slope efficiency was 6.3% with the maximum output energy of 25 μJ.     

细线径螺旋线长脉冲产生技术

 提出了双路输出的螺旋脉冲形成线(PFL)结构,该结构内置用于充电的高耦合变压器,在螺旋PFL的两端各自输出一个脉冲,副路匹配输出时主路输出脉冲波形具有良好的平顶品质,主路输出脉冲能量占储能的大部分,解决了Korovin提出的螺旋PFL充电问题。对比分析双路输出的螺旋 PFL与SINUS-700/130两种技术路线,结果发现双路输出的螺旋 PFL改善了输出脉冲的平顶质量,输出功率提高29%,但是副路输出占用11%的储能,不易充分利用。     

热管冰蓄冷结构设计

从技术角度研究和探讨了热管做为冰蓄冷装置的适用性;对各种热管用金属管材与工质的特性进行了科学比较;从而最终确定了适宜冰蓄冷工作的热管管材、热管工质及其基本尺寸;为热管冰蓄冷装置的深入研究及推广应用,提供了强有力的理论依据。