Optical and atomic force microscopic study on step bunching in BaB2O4 crystal growth

The formation of macrostep during high-temperature phase of barium meta-borate (α-BaB 2 O 4) single crystal growth has been investigated by both optical in-situ observation system and atomic force microscopy (AFM).The insitu observation results demonstrate that the critical linear size of growing facet exceeding the size that the macrostep generates is significantly anisotropic.The critical linear sizes are around 280 μm and 620 μm for {1010} and {1010} planes,respectively.AFM study illustrates that macrostep train with a height of 150 nm～200 nm is one typical morphological feature of the as-grown crystal surface.The riser of each macrostep consists of several straight and parallel sub-steps,indicating the occurrence of step bunching.Additionally,triangular sub-steps with heights of several nanometers on the treads of the macrosteps are found to be another typical feature of surface morphology,which implies a microscopically competitive bunching of sub-steps between various crystallographic orientations.     

Investigation on densification of Al2O3/B4C ceramic by ab initio calculation and experiment

Compared to experiment, the adsorption energies, bonding properties, and electronic structure of two different Al₂O₃/B₄C bridge sites with seven different Al₂O₃ surfaces are investigated by ab initio periodic density functional theory. The Al₂O₃/B₄C ceramic sintered in Ar is synthesized and measured by XRD and TEM. The calculated results reveal that the densification of O_bridge site of Al₂O₃/B₄C surface is better than that of Al_bridge. The Al₂O₃ (1 1 3)/B₄C with O_bridge is the most favorable and stable. The electronic structure shows that the electron hybridization exists between Al, O atoms and C, B atoms. The results indicate that the calculated results are in good agreement with the experiment.     

功能化单壁碳纳米管的热导率

采用基于BrennerⅡ势的非平衡态分子动力学方法,模拟研究了300K温度下经氢化学修饰的(10,0)单壁碳纳米管的热导率.研究显示功能化后碳管的热导率有明显减小,当有一列碳原子被氢化后（功能化程度为5%）,碳管的热导率减小了大约1/3,为了进一步解释这种功能化对碳纳米管热导率的影响,计算了不同功能化程度下碳纳米管的声子谱.     

可见/近红外光谱分析技术快速鉴别航天育种番茄

提出了利用可见/近红外光谱技术快速无损鉴别航天育种番茄品种的方法,采用偏最小二乘法对光谱特征信息进行提取,与神经网络结合建立番茄品种的鉴别模型.该模型将提取后的主成分作为神经网络的输入,加速了神经网络的训练速度.同时采用小波变换对大量光谱数据进行压缩,并结合神经网络建立番茄品种鉴别模型,该模型将压缩后的数据作为神经网络...     

量子纠缠消相干对确定型远程制备的影响

研究了两种典型的量子纠缠消相干现象对确定型量子态远程制备方案的影响.首先对该确定型远程制备方案进行了分析,得到该方案确定性和比特消耗情况; 然后通过分析制备过程中纠缠消相干现象对系统的影响得出: 在极化消相干过程中,该系统保真度与目标量子比特在Bloch球上的经度选择无关,仅与目标比特的纬度和消相干的大小有关;在相位消相干中,该系统的保真度不会受到消相干的影响,仅与目标量子态的纬度相关. 关键词： 远程制备 纠缠消相干 通信消耗 保真度     

基于M2因子测量的大气湍流参数的确定方法

基于广义惠更斯-菲涅尔原理以及大气湍流理论,推导出部分相干光束在大气湍流中传输的光束传输M ^{2因子的解析表达式.定量分析了表征大气湍流参数的折射率结构常数 C2_n}和涡旋内尺度 l _{0对 M ^{2因子的影响,并由此提出了一种通过实验测量大气湍流中光束的 M 2因子,进而确定出大气湍流参数的新方法.研究结果表明,由于大气湍流对相干性好的光束影响更为明显,在测量中可采用具有高相干性的基模高斯光束作为测量光源,而测量装 关键词： 2因子')" href="#">光束传输 M 2因子 大气湍流参数 湍流折射率结构常数 湍流涡旋内尺度}}     

Fe离子注入ZnO生成超顺磁纳米颗粒

过渡族元素掺杂ZnO生成稀磁半导体, 成为近期国际材料科学研究的热点. 在本文中, 研究Fe离子注入ZnO单晶的结构和磁性变化, 目标是建立磁性和结构的对应关系, 澄清铁磁性的来源. 采用卢瑟福背散射/沟道技术 (RBS/Channelling)、同步辐射X射线衍射 (SR-XRD)和超导量子干涉仪 (SQUID), 研究注入温度和退火对样品的晶格损伤、结构及磁性的影响. 研究表明: 样品注入区损伤随注入温度升高而降低; 低温253 K注入样品中, SR-XRD未检测到新相, Fe离子分布于Zn位, ZnO (0002) 峰右侧肩峰可能属于Zn_1-xFe_xO, 5 K下测试样品不具有铁磁性; 623 K注入和823 K真空退火 (253 K注入) 样品中形成α和γ相金属Fe, 5 K下样品具有明显的剩磁和矫顽力, 零场冷却和场冷却 (ZFC/FC) 曲线和300 K下的磁滞回线显示纳米Fe颗粒具有超顺磁性. Fe离子注入ZnO的磁性源于第二相α-Fe和γ-Fe. 关键词： 离子注入 ZnO 同步辐射X射线衍射 超顺磁性     

中子探测晶体Li6Gd(BO3)3:Ce的光谱特性研究

文章用提拉法生长出Li₆Gd(BO₃)₃:Ce晶体,并对其光谱性能与发光过程进行了探索. 借助于真空紫外-紫外透过光谱测试,发现晶体的透过光谱中存在Ce³⁺离子和Gd³⁺的特征吸收峰,同时还存在与Ce⁴⁺离子相关的电荷迁移带. 对晶体的真空紫外-紫外激发发射光谱进行研究发现,在晶体存在着Ce³⁺离子的5d→4f辐射跃迁发光与Gd³⁺离子的4f→4f辐射跃迁发光,而且存在着Gd³⁺→Ce³⁺之间的能量传递. 对Li₆Gd(BO₃)₃:Ce晶体的X射线与γ射线激发发射光谱研究可知,晶体在高能射线激发下的闪烁光主要是Ce³⁺离子的发光. 关键词： 6Gd(BO₃)₃:Ce晶体')" href="#">Li₆Gd(BO₃)₃:Ce晶体 真空紫外-紫外透过光谱 真空紫外-紫外激发发射光谱 能量传递     

CuS纳米粒子在太赫兹波段的光电性质研究

关键词： 太赫兹 CuS纳米粒子 Lorentz理论 Drude-Smith模型     

The magnetism for NN AFM ground state in Fe-based superconductor: Sr1−xKxFe2As2

The crystal structure, magnetism properties, and density of states for FeAs layered compound SrFe₂As₂ have been investigated by using the density functional theory (DFT) method. The magnetism under a checkerboard nearest neighbor anti-ferromagnetic (NN AFM) and ferromagnetic (FM) order ground-state have been analyzed with substitution for Sr with K ion in Sr_1−xK_xFe₂As₂. The results indicate that the distortion of FeAs tetrahedrons is sensitive to the electron doping concentration. The system magnetism was suppressed by K doping in NN-AFM ground state instead of FM. The density of states at Fermi level N(E_F) under NN AFM ground state would be regarded as a driving force for the increased T_c of Sr_1−xK_xFe₂As₂ system as observed experimentally. Our calculation reflects that NN AFM type spin fluctuation may still exist in the Sr_1−xK_xFe₂As₂ system and it may be an origin of strong spin fluctuation in this system besides the spin density wave (SDW) states.