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111.
The optical nonlinearities of Cu(mpo)2 [formula = C10H8N2CuO2S2] complex have firstly been investigated by using the Z-scan technique with a nanosecond-pulsed Nd:YAG laser at its second harmonic (532 nm) radiation. The nonlinear optical absorption and refraction coefficients of Cu(mpo)2 have been measured with the different on-axial peak irradiances I
0 at the waist ranging from 0.48 to 5.66 GW/cm2. The nonlinear transmittance characteristics exhibit the near resonant two-photon absorption (TPA) at 532 nm and are explained by a population redistribution model. The nonlinear absorption originates from the near resonant TPA while the mechanism of the nonlinear refraction is the near resonant TPA transition enhancement. The linear increasing dependences of the optical nonlinearities on the incident irradiance arise from the population redistribution due to the near resonant TPA. 相似文献
112.
Ha Yong Lee Se Hun Jung Soo Yong Lee Young Ho You Kyung Hyun Ko 《Applied Surface Science》2005,252(5):1891-1898
Al-Al2O3 composite coatings with different Al2O3 particle shapes were prepared on Si and Al substrate by cold spray. The powder compositions of metal (Al) and ceramic (Al2O3) having different sizes and agglomerations were varied into ratios of 10:1 wt% and 1:1 wt%. Al2O3 particles were successfully incorporated into the soft metal matrix of Al. It was found that crater formation between the coatings and substrate, which is typical characteristic signature of cold spray could be affected by initial starting Al2O3 particles. In addition, when the large hard particles of fused Al2O3 were employed, the deep and big craters were generated at the interface between coatings and hard substrates. In the case of pure soft metal coating such as Al on hard substrate, it is very hard to get proper adhesion due to lack of crater formation. Therefore, the composite coating would have certain advantages. 相似文献
113.
A novel and cost-effective sol-gel process for preparation of MgAl2O4 spinel nanometer powders has been developed in this study. A solution of magnesium and aluminum nitrates in stoichiometric proportion was successfully embraced in the biology polysaccharide gel network, formed by the synergistic interaction between xanthan gum (XG) and locust bean gum (LBG) utilizing their broad-spectrum stability of salt tolerance and character of transformation from sol to gel on the condition of proper temperature and relative proportion of polymeric components. Dry gel could be obtained by vacuum dehydration of aqueous gel at low temperatures. Monolithic MgAl2O4 spinel nanometer powders were produced by calcining the dry gel above 800°C, with average crystallite size of 20 nanometers. 相似文献
115.
An exfoliated poly(4,4′-oxybis(benzene)disulfide) (POBDS)/vermiculite (VMT) nanocomposite was prepared by using cyclo(4,4′-oxybis(benzene)disulfide) (COBDS) oligomers and cetyltrimethyl ammonium bromide exchanged VMT. The POBDS/VMT nanocomposites were fabricated in two steps. First, the COBDS oligomers were used to swell and exfoliate organo VMT to afford COBDS-VMT nanocomposite precursor. Subsequently, the exfoliated POBDS-VMT nanocomposite can be made via in situ and instant melt ring-opening polymerization of the COBDS-VMT nanocomposite precursor. High molecular weight POBDS polymer can be formed in a few minutes. The nano scale dispersion of VMT layers within POBDS polymer was confirmed by both the X-ray diffraction patterns and TEM examinations. This methodology provides a potential approach to synthesize high performance polymer nanocomposite. 相似文献
116.
QiaoHongYAO FuYouLI LuSHAN ChunHuiHUANG DongDongYIN 《中国化学快报》2003,14(11):1185-1188
A new photoresponsive D-π-A dye, mPS, has been designed and synthesized.Compared to the parent dye PS, IPCE values in the region from 400 nm to 560 nm was greatly improved upon changing the attaching group from the p- position to the o- position of the π-conjugation bridge. A solar cell based on mPS generated a remarkably high overall yield η of 5.4% under irradiation of 80.0 mW cm^-2 white light from a Xe lamp, Compared with PS, the overall yield η increased by 64%. 相似文献
117.
X. Y. You 《Heat and Mass Transfer》2003,40(1-2):75-81
Active feedback control for the onset of Rayleigh-Bénard Convection in temperature-dependent-viscosity liquids is investigated.
In this paper, three major problems are addressed: (1) The results of Tang-Bau control are improved by considering the effects
of temperature-dependent viscosity; (2) A more efficient two-plate control strategy is presented. A phenomenon of coalescence
of the unstable modes is observed as the controller gain is large enough; (3) A simple way to estimate the critical Rayleigh
number under the effects of temperature-dependent viscosity is described. Numerical results show that the effects of temperature-dependent
viscosity on the critical Rayleigh number should be taken into account in some cases and the onset of Rayleigh-Bénard convection
can be effectively delayed or advanced by the active feedback control strategies studied here. 相似文献
118.
用溶胶-凝胶法制备了在可见光照射下具有光催化活性的掺杂P(t Ⅳ)离子的非晶态微孔TiO2,表面积为160~200 m2/g;含3.0%Pt(Ⅳ)的AMM-Ti具有最大的光催化活性. X射线精细结构分析(EXAFS)表明,单个的PtCl4分子均匀地分布在非晶态二氧化钛表面;用这种光催化剂降解2,4-二氯苯氧基乙酸时,2,4-二氯苯酚是主要的中间物,通过Langmuir-Hinshelwood 方程的线性形式估算了反应速率常数k 和吸附平衡常数K,研究了光催化起始反应速率和反应物起始浓度之间的关系,同时,提 相似文献
119.
120.
高功率激光系统通过空间滤波和中继成像抑制自聚焦 总被引:3,自引:1,他引:2
孟昭贤 《激光与光电子学进展》1998,35(9):8-12
讨论了由光束自聚焦引起的细丝形成和光束分裂,为了克服聚焦造成的破坏要求在光束传播中采用中继成像和空间滤波。 相似文献