Development of a quantitative FI-MS technique for the characterization of high- and nonboiling saturated hydrocarbon mixtures

Summary Using a saturated non-boiling hydrocarbon mixture, the influence of two parameters on the results of field ionization mass spectrometry (FI-MS) measurements was studied: (a) the potential difference between the FI emitter and the counterelectrode; (b) the emitter temperature.Variation of the potential difference had only a minor effect on the average molecular mass measured and had no evident effect on the relative ring number distribution in the sample. In contrast, when the emitter temperature was increased, higher average molecular masses were recorded. Moreover, the average molecular masses shifted to higher ring numbers. In order to control the relationship between the described influences during mixture analysis, measuring instructions have been developed that enable the quantitative analysis of unknown saturated samples. However, average molecular mass of the mixture must be known.

---

Entwicklung einer quantitativen FI-MS-Methode zur Charakterisierung von gesättigten hoch- und nichtsiedenden Kohlenwasserstoffgemischen

     

Bulk and microprobe analysis for trace elements with synchrotron radiation

Blood serum samples were irradiated by monochromatic synchrotron radiation (15 keV) and by 2.4-MeV protons to compare their performance for the detection of trace elements by x-ray fluorescence (XRF) spectrometry. Absolute concentration assignment was based on the addition of an internal standard and on a method which uses the incoherent and coherent radiation as a flux monitor of the incoming beam. Preliminary experiments with a synchrotron XRF microprobe are reported.     

New FIR laser lines and frequency measurements for optically pumped CD3OH

Twenty new cw FIR laser lines in CD₃OH, optically pumped by a CO₂ laser, are reported. The frequencies of 39 of the stronger laser lines were measured relative to stabilized CO₂ lasers with a fractional uncertainty, as determined by the reproducibility of the FIR frequency itself, of 2 parts in 10⁷.Contribution of the U.S. Government, not subject to copyright.     

Low-cost, high-efficiency quasi-planar array of waveguide-fed circularly polarized microstrip antennas

A low-cost quasiplanar Ku-band array of circularly polarized microstrip antennas benefiting from a low-loss waveguide feed network is demonstrated (patent pending). The 32 elements of the array which are arranged in a 2-by-16 configuration are subdivided into four two-by-four subarrays. To maintain feed losses and thus the overall noise temperature at a minimum, the subarrays are excited using a one-by-four corporate feed network of hollow metallic waveguides. This network is composed of E-plane components such as Tee-junctions and bends and is manufactured out of only two metallic pieces that accommodate the feed network in the form of milled grooves. Because of insensitivity of the exploited E-plane components to air gaps or slight misalignments, the pieces are secured together with only four screws without welding, braising, or conducting adhesives. Owing to a low-loss foam substrate, the array elements show high circular polarization gain of 9 dBic and wide relative bandwidth of 4%. To achieve circular polarization, use is made of circular patches with two nearly perpendicular perturbations. Using sequential rotation of the elements along with quadrature phase shifting, the axial ratio of the array is reduced to 1 dB over 4% of bandwidth. The measured circular polarization gain of the array amounts to 23 dBic with an aperture efficiency of 63% in the Ku-band of frequencies. The achieved efficiency, which is higher than the reported efficiency for comparable planar arrays with microstrip feed networks, can be credited to the low losses of only 0.2 dB in its waveguide corporate feed. The paper also presents measurement results for an arrangement of two inclined single arrays mounted in parallel. This configuration which has a measured circular polarization gain of 25.7 dBic with an axial ratio of 1 dB is desirable for mobile low-profile antenna systems.     

Photoconductive Terahertz antenna with radial symmetry

It has been demonstrated recently that it is possible to guide broadband Terahertz pulses utilising a novel coaxial waveguide. This technique is hindered by the difficulty in exciting the radially polarised fundamental mode of the waveguide. To optimise mode matching, a novel radially symmetric photoconductive Terahertz antenna is proposed. Using finite element method simulations and analytical calculations, it is shown that this antenna can generate the desired radial polarisation.     

Tensile behaviour of corroded and hydrogen embrittled 2024 T351 aluminum alloy specimen

The synergetic effect of corrosion and corrosion induced hydrogen embrittlement damage processes which occur at local scale has been found to result in a dramatic macroscopic tensile ductility loss of the 2024 aluminum alloy. In the present work, the tensile behaviour of corroded 2024 T351 specimens has been estimated on the basis of FE analysis by taking into account the local material properties in the damaged areas. A parametric study is involved to account for the effect of thickness in the results. Calculated tensile properties obtained with the analysis agree well with experimental data.     

Investigation of multicomponent fluoride optical materials in the UV spectral region: I. Single crystals of Ca1−x R xF2+x (R = Sc, Y, La, Yb, Lu) solid solutions

Crystalline materials that are transparent in the vacuum UV spectral region and currently used have been reviewed. Transmission of crystals of solid solutions with the fluorite structure Ca_1?x R _xF_2+x (R = Sc, Y, La, Yb, Lu) in the UV and vacuum UV spectral regions has been investigated. It is shown that application of different methods of purification of fluorides from some impurities can significantly improve the optical quality of fluoride multicomponent crystals in the short-wavelength spectral region.     

Minimizing power dissipation in optical interconnects at low voltage using optimal modulator design

A strong motivation for insertion of optical interconnects in short-distance applications such as chip-to-chip or back-plane communication, apart from high bit rates, is their potential to achieve these bit rates at low power compared to the currently prevalent copper based interconnects. Thus, it is imperative to construct design methodologies which minimize the total optical link power dissipation. We present one such methodology, where we optimize the quantum-well modulators to minimize the power dissipation in modulator-based optical interconnects. In the first part of the paper, the focus is on obtaining the optimal modulator metrics [contrast ration (CR) and insertion loss], which yield the lowest total power (receiver and the modulator). The trends are studied as a function of the input laser power and bit rate. Having obtained the desirable modulator metrics and the corresponding power dissipation, in the second part, the focus is on the feasibility of these metrics in the light of voltage swing constraints. The biggest concern with the modulator based optical link is the low CR, especially at low voltage swing. While studying these concerns, we also provide insight into the physical design of the modulator including, its intrinsic region thickness, pre-bias voltage, and the size and the number of quantum-wells. Specifically, we outline the method to obtain the design parameters, which allows minimum power dissipation with the least laser power. This ultimately yields higher aggregate I/O bandwidth for chip to chip communication in power limited chips.     

Algebraic decoding of (103, 52, 19) and (113, 57, 15) quadratic residue codes

In this paper, two algebraic decoders for the (103, 52, 19) and (113, 57, 15) quadratic residue codes, which have lengths greater than 100, are presented. The results have been verified by software simulation that programs in C++ language have been executed to check possible error patterns of both quadratic residue codes.     

The U.S. role in global internet governance

Who should control the Internet? A dozen years after the Internet became a mass medium, this issue has continued to grow in urgency, becoming white hot in fall 2005. At the September 2005 preparatory meeting for the UN World Summit on the Information Society (WSIS), a coalition of countries criticized the United States' unilateral control of the Internet's domain name system (DNS) and proposed the establishment of a multinational Council to supervise it. This proposal emerged from the Final Report of the UN Working Group on Internet Governance. Researchers from the Internet Governance Project, a university-based consortium for policy analysis, have concluded that the United States should internationalize governance of the Internet, but in a way that avoids intrusive, centralized control.