全文获取类型
收费全文 | 198444篇 |
免费 | 18873篇 |
国内免费 | 12730篇 |
专业分类
化学 | 83503篇 |
晶体学 | 1631篇 |
力学 | 11999篇 |
综合类 | 512篇 |
数学 | 41108篇 |
物理学 | 51312篇 |
无线电 | 39982篇 |
出版年
2024年 | 503篇 |
2023年 | 3057篇 |
2022年 | 3683篇 |
2021年 | 4786篇 |
2020年 | 4759篇 |
2019年 | 4180篇 |
2018年 | 14729篇 |
2017年 | 14231篇 |
2016年 | 11624篇 |
2015年 | 6310篇 |
2014年 | 6847篇 |
2013年 | 8600篇 |
2012年 | 13863篇 |
2011年 | 20976篇 |
2010年 | 13404篇 |
2009年 | 13364篇 |
2008年 | 14286篇 |
2007年 | 15832篇 |
2006年 | 6599篇 |
2005年 | 6816篇 |
2004年 | 5404篇 |
2003年 | 5190篇 |
2002年 | 3883篇 |
2001年 | 2702篇 |
2000年 | 2596篇 |
1999年 | 2797篇 |
1998年 | 2487篇 |
1997年 | 2267篇 |
1996年 | 2269篇 |
1995年 | 1877篇 |
1994年 | 1636篇 |
1993年 | 1385篇 |
1992年 | 1218篇 |
1991年 | 1038篇 |
1990年 | 805篇 |
1989年 | 628篇 |
1988年 | 504篇 |
1987年 | 409篇 |
1986年 | 411篇 |
1985年 | 336篇 |
1984年 | 223篇 |
1983年 | 166篇 |
1982年 | 153篇 |
1981年 | 104篇 |
1980年 | 95篇 |
1979年 | 65篇 |
1914年 | 45篇 |
1912年 | 40篇 |
1909年 | 41篇 |
1908年 | 40篇 |
排序方式: 共有10000条查询结果,搜索用时 46 毫秒
111.
112.
快速启动微型J—T制冷器 总被引:1,自引:1,他引:0
在一些特殊应用中,要求把红外探测器必须在几秒钟或更短的时间内冷却到工作状态。微型J-T式制冷是常用致冷方式。本文介绍了快速启动冷却红外探测器的J-T制冷器的设计及达到快速冷却的方法以及测试结果。 相似文献
113.
添加尖晶石对氧化锌压敏电阻性能的影响 总被引:1,自引:0,他引:1
通过添加尖晶石(Zn7Sb2O(12))改性研制出电位梯度为100V/mm左右,压敏电压在82~150V,通流容量可达1600A/cm2,漏电流<2μA系列压敏电阻器,从而满足了国内电话交换机行业对82V、100V、120V、150V压敏电阻器的电性能要求。从工艺的角度解释了尖晶石对氧化锌瓷晶粒的作用原理,并分析了尖晶石的微观结构及粒度对瓷片电性能的影响。 相似文献
114.
The article referenced above was first published online on 7 August 2007 with incorrect pagination; the pagination has now been corrected online and in print. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
115.
Zhigang Zhang Jianping Deng Weiguo Zhao Jianmin Wang Wantai Yang 《Journal of polymer science. Part A, Polymer chemistry》2007,45(3):500-508
A novel chiral N‐propargylsulfamide monomer ( 1a ) and its enantiomer ( 1b ) were synthesized and polymerized with (nbd)Rh+B?(C6H5)4 as a catalyst providing poly(1) (poly( 1a ) and poly( 1b )) in high yields (≥99%). Poly(1) could take stable helices in less polar solvents (chloroform and THF), demonstrated by strong circular dichroism signals and UV–vis absorption peaks at about 415 nm and the large specific rotations; but in more polar solvents including DMF and DMSO, poly(1) failed to form helix. Quantitative evaluation with anisotropy factor showed that the helical screw sense had a relatively high thermal stability. These results together with the IR spectra measured in solvents showed that hydrogen bonding between the neighboring sulfamide groups is one of the main driving forces for poly(1) to adopt stable helices. In addition, copolymerization of monomer 1a and monomer 2 was conducted, the solubility of poly(1) was improved drastically. However, the copolymerization had adverse effects on the formation of stable helices in the copolymers. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 500–508, 2007 相似文献
116.
标题化合物二乙胺合三(5-甲基-2-苯并噻唑基)硼烷(C28H29BN4S3(Mr=527.57)的晶体属于三斜晶系,空间群为P1,晶胞参数a=0.397(8)nm,b=1.1742(6)nm,c=1.3100(2)nm,α=104.29(2)°,β=92.99(3)°,γ=98.58(5)°,V=1.3790nm3,Z=2,Dc=1.270g/cm3,μ(MoKα)=2.804cm-1.结构的偏离因子R=0.0648,Rw=0.0737.结构测定表明,甲基取代基的电子效应导致硼碳键键长的平均化,预示杂环对硼原子的π-电子反馈与胺基氮原子对硼原子的反馈有彼消此长的关系. 相似文献
117.
Zhishen Mo Lixiao Wang Hongfang Zhang Ping Han Baotong Huang 《Journal of Polymer Science.Polymer Physics》1987,25(9):1829-1837
Wide-angle X-ray scattering from presumed block copolymers of polypropylene (PP) and ethylene-propylene copolymer (EPR), i.e., PP-EPR and PP-EPR-PP, synthesized by sequential polymerization with δ-TiCl3? Et2AlCl, was examined and compared with WAXS of mechanical blends and chain-transfer mixtures of PP and EPR with comparable compositions. The peak at 2θ = 20° for both the copolymers and the mixtures was attributed to the γ modification of PP in EPR. A strong variation in the ratio of diffraction intensities I040/I110 of PP in block copolymers and mixtures was explained in terms of crystallite growth in different directions. Analysis of the patterns and calculation of crystallinity, crystallite size, and lattice parameters led to the conclusion that block structure existed in the prepared copolymers. 相似文献
118.
Binyuan Liu Yang Li Boo‐Gyo Shin Do Yeung Yoon IL Kim Li Zhang Weidong Yan 《Journal of polymer science. Part A, Polymer chemistry》2007,45(15):3391-3399
Three novel functionalized polynorbornenes (PNB) with pendant dimethyl carboxylate group (carboxylates—acetate, propionate, and butyrate) are synthesized as a vinyl‐type with a palladium (II) catalyst in high yield. The effects of size of substitutents, molar ratio of monomer to catalyst, solvent polarity, reaction time, and temperature on the polymerization of exo‐norbornene dimethyl propionate were systematically investigated. The low molar ratio and temperature, as well as high polarity of solvent, and long reaction time, are favorable for the enhancement of the monomer conversion, especially, the solvent have an obvious effect on the catalyst activity. The resulting poly(cis‐norbornene‐exo‐2,3‐dimethyl carboxylates) (PNB‐dimethyl carboxylates) show good solubility in common organic solvent and high thermal stability up to 360 °C. The glass transition temperature was detected by DMA at 331, 324, and 318 °C for acetate, propionate, and butyrate, respectively. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3391–3399, 2007 相似文献
119.
120.
Dongheng Zhang Wen-Hua Sun Junxian Hou Suyun Jie Fei Chang 《Journal of polymer science. Part A, Polymer chemistry》2006,44(1):264-272
The polymerization of cyclopentadiene (CPD) was effectively initiated by methylaluminoxane (MAO) to generate poly(cyclopentadiene) (polyCPD). The effects on the polymerization of some reaction parameters such as the monomer concentration, the initiator concentration, and solvents were investigated. The conversion of CPD was monitored with gas chromatography to investigate the reaction kinetics. The polymerization rate was proportional to the concentrations of MAO in the first order and of the CPD monomer in the second order, and a reasonable cationic polymerization mechanism was suggested on the basis of the kinetic study. PolyCPD obtained at a low temperature could be dissolved in toluene or chloroform, and this indicated lower cross‐coupling during the polymerization reaction. 1H NMR and IR analysis of the polymer indicated that there were almost equal amounts of 1,2‐enchainment and 1,4‐enchainment in the polymer chain. The measurement of polyCPD showed its unique properties as a potential candidate for stable wrappings or electronic packaging materials. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 264–272, 2006 相似文献