Grafted MXenes Based Electrolytes for 5V-Class Solid-State Batteries

Polymer blends based solid polymer electrolytes (SPEs), combining the advantages of multiple polymers, are promising for the utilization of 5 V-class cathodes (e.g., LiCoMnO₄ (LCMO)) with enhanced safety. However, severe macro-phase separation with defects and voids in polymer blends restrict the electrochemical stability and ionic migration of SPEs. Herein, inorganic compatibilizer polyacrylonitrile grafted MXene (MXene-g-PAN) is exploited to improve the miscibility of the poly(vinylidene fluoride-co-hexafluoropropylene) (PVHF)/PAN blends and suppress the consolidation of phase particles. The resulting SPE exhibits a high anodic stability with an ionic conductivity of 2.17 × 10⁻⁴ S cm⁻¹, enabling a stable and reversible Li platting/stripping (over 2500 h). The fabricated solid Li‖LCMO cell delivers a 5.1 V discharge voltage with a decent capacity (131 mAh g⁻¹) and cycling performance. Subsequently, the solid all-in-one graphite‖LCMO battery is also constructed to extend the application of MXene based SPEs in flexible batteries. Benefiting from the interface-less design, outstanding mechanical flexibility and stability is achieved in the battery, which can endure various deformations with a low-capacity loss (< ≈10%). This study signifies a significant development on solid flexible lithium ion batteries with enhanced performance, stability, and reliability by investigating the miscibility of polymer blends, benefiting for the design of high-performance SPEs.     

Glycyrrhetinic Acid Liposomes Encapsulated Microcapsules from Microfluidic Electrospray for Inflammatory Wound Healing

In diabetic wound healing, M1 macrophage accumulation and elevated inflammation are prevalent issues. Intelligent delivery systems that can sustainably release antioxidizing and anti-inflammatory ingredients are expected for effective wound healing. Herein, a novel glycyrrhetinic acid (GA) liposomes encapsulated microcapsules delivery system that has desired features for inflammatory wound repair is presented. As the bacteria could break down the alginate shells, the GA liposomes could be controllably released from the microcapsules, which promotes M2 macrophage polarization and regulate their responses in the inflammatory wound microenvironment. Based on these, it is demonstrated that the GA liposomes encapsulated microcapsules delivery system exhibits an anti-inflammatory and immunomodulatory effect for diabetic wound healing in a full-thickness defect model in diabetic rats. These results indicate that the immunomodulatory capabilities of the microcapsules can be unitized for efficient wound repair, and such a delivery system is valuable for clinical wound healing applications.     

光电导太赫兹源回路电感对其辐射特性的影响

光电导太赫兹源（Photo-Conductive Antenna,PCA）已广泛用于太赫兹时域光谱系统（THz-TDS）。在THz-TDS系统中,处于偏置状态的PCA被飞秒激光触发因光生载流子,在偏置电场下的加速运动而向自由空间辐射太赫兹波,同时在PCA偏置回路中形成脉冲电流。通常给PCA加载偏置电压的回路有不同结构的电路设计,导致PCA装架的基板回路不可避免地存在一定电感,由此引起的电磁惯性会显著影响回路中脉冲电流的脉宽,电流脉冲的脉宽会随回路电感的增大而展宽。那么PCA回路电感是否会影响PCA向自由空间辐射THz波的特性,这是设计PCA基板电路面临的问题所在。本文尝试在PCA回路中加入不同电感值的电感元件,通过实验测试了PCA辐射THz波的时域波形和频谱,结果表明,PCA回路电感的数值对PCA辐射THz波没有明显影响,从而对不同场合应用的PCA基板结构和电路设计提供了实验基础。     

Pattern synthesis for uniform linear array using genetic algorithm and artificial neural network

Multidimensional Systems and Signal Processing - In this paper, we propose a new amplitude-only method for pattern synthesis of uniform linear array (ULA) based on genetic algorithm (GA) and...     

激光退火硅晶圆温度场分布的数值模拟研究

目前,激光退火技术被广泛应用于半导体加工领域,但对如何选择激光条件进行相应的退火并没有系统清晰的准则可以参考,尤其是在硅的深注入杂质激活方面。本文通过对激光照射在硅晶圆上形成的温度场分布进行数值模拟研究,分析了激光波长和脉冲宽度对加热深度以及晶圆背面温度的影响。结果表明,延长激光波长或脉冲宽度,都有助于增加激光退火的加热深度。而对于特定的激活深度需求,存在着最优的激光波长和脉冲宽度组合,可以使退火所需要的激光脉冲能量最低,硅晶圆背面的温升最小。本文通过模拟仿真给出了激活深度在1～10μm范围内的最优波长和脉宽值,可为实现高效的深硅注入激光激活工艺提供重要的条件参考。     

Synthesis and structure characterization of a novel series of N-alkylphthalimidylaminocarbonylmethoxylcalix [4] arenes

A novel series of N-alkylphthalimidylaminocarbonylmethoxylcalix[4]arenes with the reaction between 4-(N-bromoacetyla- mino)-phthalimide derivatives and calix[4]arene has been synthesized and structurally characterized by IR,~1HNMR and MS.From their analysis data,it was found that compounds 7a-7d adopted a cone conformation.     

硼酸溶液中氯柱硼镁石的溶解及相转化动力学

对氯柱硼镁石（2MgO•2B2O3•MgCl2•14H2O）在4.5％H3BO3水溶液40 ℃的溶解及相转化过程进行了动力学研究.对不同时间取出的液相的化学分析及不同阶段分离固相的鉴定结果表明,该复盐在溶解阶段出现与前所报导不同的同步溶解，最终产物是库水硼镁石（2MgO•3B2O3•15H2O）.提出了库水硼镁石的形成条件和溶解及相转化动力学机理，利用单纯形优化法配合Runge-Kutta微分方程组数值解法对实验数据进行处理，给出了转化结晶动力学方程.     

阿利新蓝的合成

阿利新蓝 (ＡｌｃｉａｎＢｌｕｅ)是一种从植物中提取出的天然物。于 1 944年由Ｈａｄｄｏｃｋ和Ｗｏｏｄ在实验室通过多次实验后所发现。它的水溶液呈天蓝色 ,着色性好而且吸光系数很大。又因它较好的水溶性。所以可以作为高效的生物染色剂[1,2 ] ,用于粘蛋白染色、细菌染色及聚酯、纤维素等人造和天然纤维的染料[3 ] 。基于它的重大应用前景和较高的商业价值 ,探索出一条合理的工业化合成路线就非常重要了。有关阿利新蓝的应用虽然有很多 ,但始终未见合成阿利新蓝的文献报道。在设计它的有机合成时必然涉及酞菁铜 (ＰｃＣｕ)的氯甲基化反…     

A New Dimeric Phthalide from Angelica sinensis

Angelica sinensis (Oliv.) Diels (Umbelliferae), known as Danggui in Chinese, one of the most important traditional Chinese medicines, is used for tonifying blood and treating female irregular menstruation and amenorrhoea. It is also used for treatment of …     

2-取代亚肼基-1,3-二硫杂环戊烷类化合物的合成及其生物活性研究

以取代苯甲醛、取代吡啶和取代苯甲酸酯等为原料合成了 10种含硫杂环化合物 (其中 2a～ 2g化合物为国内外未见报道 ) .在合成过程中采用了超声波技术 ,极大地缩短了反应时间 ,提高了收率 .所得化合物的结构经IR ,1 HNMR ,MS和元素分析证实 .对其生物活性进行了初步测试 ,结果证明一些化合物具有良好的抑菌或杀菌作用 ,其中 2b ,2c ,2e ,2h ,2i和2j对大肠杆菌 ( 10 40 7号 )的抗菌效果与CET和SMZ相当 ;2b ,2c ,2f对草绿色链球菌 ( 112 3号 )的抗菌效果与CET和SMZ相当 .