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111.
A new chromogenic reagent tribromocarboxyarsenazo has been synthesized and the chromogenic reaction of this reagent with zirconium studied. In the medium of 0.5 mol/1 HCl, a blue complex is formed by the reaction of zirconium with tribromocarboxyarsenazo. The maximum absorption of the complex is at 633 nm, and the apparent molar absorptivity is 4.8 x 10(4) 1/mol/cm. Beer's law is obeyed over the zirconium concentration range 0-18, mug/25 ml. The method has been applied to the determination of zirconium in aluminum, copper and magnesium alloys with satisfactory results. 相似文献
112.
Nitration of 2-bromo or 2-chlorotropone gave a new compound, 2,7-dinitrotropone: The halegen atom on the 2-position was displaced by the nitro group through an electrophilic substitution reaction. Nitration of 3,5,7-tribromotropolone gave 3,7-dibromo-5-nitropolone: the nitro group again displaced the bromine atom at position 5. 相似文献
113.
Stopped-flow was used to evaluate the methylation and reduction kinetics of the isolated alpha subunit of acetyl-Coenzyme A synthase from Moorella thermoacetica. This catalytically active subunit contains a novel Ni-X-Fe4S4 cluster and a putative unidentified n = 2 redox site called D. The D-site must be reduced for a methyl group to transfer from a corrinoid-iron-sulfur protein, a key step in the catalytic synthesis of acetyl-CoA. The Fe4S4 component of this cluster is also redox active, raising the possibility that it is the D-site or a portion thereof. Results presented demonstrate that the D-site reduces far faster than the Fe4S4 component, effectively eliminating this possibility. Rather, this component may alter catalytically important properties of the Ni center. The D-site is reduced through a pathway that probably does not involve the Fe4S4 component of this active-site cluster. 相似文献
114.
巯基葡聚糖凝胶分离富集光度法测定镉的研究 总被引:2,自引:0,他引:2
研究了在TritonX-100存在下,新显色剂邻羧基苯基重氮氨基偶氮苯(CDAA)与镉的显色体系,在pH10.6的Na2B4O7-NaOH体系中,显色反应灵敏度很高。络合物的最大吸收位于545nm处,其摩尔吸光系数为2.22×10^5L·mol^-1·cm^-1。镉含量在0 ̄12μg/25mL符合比耳定律。将该体系用于巯基葡聚糖凝胶分离富集-光度法测水样中微量镉,结果令人满意。 相似文献
115.
A new short synthesis of 3-substituted 5-amino-1-(chloromethyl)-1,2-dihydro-3H-benzo[e]indoles from Martius Yellow is disclosed. The key steps of the synthesis were three efficient regioselective reactions (iodination, 5-exo-trig aryl radical-alkene cyclization and carboxylation). 相似文献
116.
The UV and visible spectra of six model compounds were studied. These compounds can be considered as models of polyaniline in the reduced, cation radical, partially oxidized and oxidized forms. After treatment of a mixture of equal molar quantities of the reduced form (DPPD) and the oxidized form (QDIM) with acid, the following reaction was observed: DPPD(I)+QDIM(III)+2H+=2DPPD+(II) After similar treatment of the partially oxidized form (V) with acid, the radical cation salt formed. The UV and visible spectra of polyaniline in the reduced form, oxidized form and conductive form are similar to the spectra of DPPD, QDIM and DPPD+ or radical cation salt of V respectively. We propose that the polyaniline synthesized by chemical oxidation of aniline consists of oxidized and reduced repeat units. Upon protonation a redox reaction (or electron rearrangement) occurs and forms delocalized radical cations (polarons) in the polymer chain which are highly conductive. 相似文献
117.
对1993年6月至1996年6月因体弱多病,生长发育矮小等来诊的351例儿童作了血铅测查和临床全征分析,以期引起儿科临床医师重视。 相似文献
118.
Nitropyridines reacted with an excess of vinyl Grignard reagent to produce 4- or 6-azaindoles. Improved yields were obtained when a halogen atom was present at the position alpha to the nitrogen atom in the pyridine ring. 相似文献
119.
Odile Burlet Chao-Yuh Yang Simon J. Gaskell 《Journal of the American Society for Mass Spectrometry》1992,3(4):337-344
Oxidation of cysteine residues to cysteic acids in C-terminal arginine-eontaining peptides (such as those derived by tryptic digestion of proteins) strongly promotes the formation of multiple members of the Y? series of fragment ions following low energy collision-activated decomposition (CAD) of the protonated peptides, Removal of the arginine residue abolishes the effect, which is also attenuated by conversion of the arginine to dimethylpyrim-idylornithine. The data indicate the importance of an intraionic interaction between the cysteic acid and arginine side-chains. Low energy CAD of peptides which include cysteic acid and histidine residues, also provides evidence for intraionic interactions. It is proposed that these findings are consistent with the general hypothesis that an increased heterogeneity (with respect to location of charge) of the protonated peptide precursor ion population is beneficial to the generation of a high yield of product ions via several charge-directed, low energy fragmentation pathways. Furthermore, these data emphasize the significance of gas-phase conformations of protonated peptides in determining fragmentation pathways. 相似文献
120.
Since hydration forces become very strong at short range and are particularly important for determining the magnitude of the adhesion between two surfaces or interaction energy, the influences of the hydration force and elastic strain energy due to hydration-induced layering of liquid molecules close to a solid film surface on the stability of a solid film in a solid-on-liquid (SOL) nanostructure are studied in this paper. The liquid of this thin SOL structure is a kind of water solution. Since the surface forces play an important role in the structure, the total free energy change of SOL structures consists of the changes in the bulk elastic energy within the solid film, the surface energy at the solid-liquid interface and the solid-air interface, and highly nonlinear volumetric component associated with interfacial forces. The critical wavelength of one-dimensional undulation, the critical thickness of the solid film, and the critical thickness of the liquid layer are studied, and the stability regions of the solid film have been determined. Emphasis is placed on calculation of critical values, which are the basis of analyzing the stability of the very thin solid film. 相似文献