双酚A聚砜链对对苯二酚聚砜链结晶性能的影响

本文报导了双酚A聚砜(B)与对苯二酚聚砜(H)两组份含量不同的嵌段共聚物的X射线衍射结果,B链的加入,使共聚物的结晶性能被破坏,B/H为0.48(摩尔比)时,所得共聚物已呈现出完全非晶相结构的特征.由IGC及DSC实验测定,表明这两种聚砜链是相容的.     

重金属铊在环境介质中的分布及其迁移行为

铊是剧毒重金属元素,它在自然界中是典型的稀有分散金属。环境介质中铊的自然本底值较低,但随着铊矿床的开发和铊资源的广泛应用,岩矿石中的铊在自然力或人为作用下向环境介质中迁移。综述了铊在岩（矿）石、土壤、水体、动植物和人体中的分布,以及在上述环境介质及大气中的迁移行为。研究表明,人类活动是导致环境介质中铊含量增加的主要原因。铊在环境介质中的迁移是反复循环的复杂过程,通过风化、溶解、淋滤、吸收、沉降、固结等方式在环境介质中循环往复,从而危害环境生态和人体健康。铊污染应引起人们的普遍重视。     

Integrated Routing Algorithms for Provisioning “Sub-Wavelength” Connections in IP-Over-WDM Networks

This work focuses on developing and implementing comprehensive unified constraint-based routing algorithms within the generalized multi-protocol label switching framework (GMPLS) to provision sub-wavelength circuits (low-rate traffic streams). Constraint-based routing is further augmented in this work by dynamically routing both an active and another alternate link/node-disjoint backup path at the same time in order to provision a given connection request. This new integrated approach combines both IP routing and optical resource allocation to setup end-to-end connections.     

激光对固体推进剂点火形成的二次燃烧现象

利用反应性光声技术检测了Ｎｄ３＋：ＹＡＧ脉冲激光对固体推进剂点火的全过程。检测结果表明除激光作用时形成的一次燃烧外还存在非光支持的二次燃烧。     

Numerical calculation of electromigration under pulse current withJoule heating

Electromigration behavior under pulsed directional current (PDC) was investigated theoretically and experimentally. A vacancy diffusion equation under current stress was derived, and the relationship between vacancy concentration and time to failure was calculated numerically. The results show that if Joule heating is considered, the ratio of lifetime under PDC to that under DC is less than what was reported by other authors. In addition, the dependence of the lifetime on duty ratios and frequencies of PDC is not the same in different regimes of PDC frequencies. The analytical equation describing the relation between MTF_PDC and MTF_DC in the entire regime of frequencies, including Joule heating, is given. All calculated results are compared to experimental results     

Ce掺杂K_2La_2Ti_3O_(10)催化剂的可见光高效催化制氢的研究

采用高温固相法合成了铈掺杂的K2La2Ti3O10催化剂,利用X射线衍射(XRD)、紫外-可见漫反射(UV-visDRS)、透射电镜(TEM)和X射线光电子能谱(XPS)对催化剂进行了表征.考察了催化剂的可见光催化分解甲醇水溶液制氢的活性,并对可见光催化机理进行了分析.研究表明,铈的掺杂没有改变K2La2Ti3O10的微晶结构,并使催化剂粒径有所减小.紫外可见漫反射分析表明禁带宽度为2.3eV左右,对可见光具有较高吸收.XPS表明La和Ti为+3和+4价,而Ce则是+3和+4的混合价态.担载2wt%Pt后,在可见光下光催化活性大大提高,当铈的掺杂量为0.5mol%(即Ce取代La的摩尔百分量)时,光催化活性达到最大,产氢速率为0.05mmol/h;光照5h后产氢量为0.22mmol,而纯K2La2Ti3O10的产氢量只有0.037mmol.     

Concise synthesis of the oxapentacyclic core of cortistatin A

A concise synthetic approach for constructing the oxapentacyclic framework of cortistatin A is described. The synthesis features a furan-oxyallyl [4 + 3] cycloaddition and double-intramolecular aldol reactions. In addition, an interesting core structure was obtained in 11 steps from furan by using our method.     

电子电路实验中心EDA室的建设与应用

从建设适合现代实验教学的ＥＤＡ机房出发，介绍了ＥＤＡ实验室的硬件环境和软件配置及其所取得的教学效果。     

Novel chiral thiazoline‐containing N―O ligands in the asymmetric addition of diethylzinc to aldehydes: substituent effect on the enantioselectivity

Several novel chiral thiazoline primary and tertiary alcohols were easily synthesized from commercially available l ‐cysteine in three steps and with high yield. These ligands were subsequently applied to the asymmetric addition of diethylzinc (Et₂Zn) to various aldehydes. Products with S configuration were obtained when thiazoline‐containing tertiary alcohol ligands were used as catalysts. The primary alcohol induced corresponding products with R configuration in 68% enantiomeric excess, which was a higher value relative to other N―O ligands possessing a primary alcohol unit in the literature. Furthermore, a plausible transition state model was proposed to explain the observed enantioselectivities. Copyright © 2012 John Wiley & Sons, Ltd.     

Fair queueing with service envelopes (FQSE): a cousin-fair hierarchical scheduler for subscriber access networks

In this paper, we propose and investigate the characteristics of a fair queueing with service envelopes (FQSE) algorithm-a hierarchical fair-share scheduling algorithm for access networks based on a remote scheduling system such as Ethernet passive optical networks (EPON) or cable TV network. FQSE is designed to overcome the limiting factors of a typical remote scheduling system such as large control-plane delay, limited control-plane bandwidth, and significant queue switch-over overhead. The algorithm is based on a concept of service envelope-a function representing the fair allocation of resources based on a global network condition called satisfiability parameter (SP). We define properties of cousin-fairness and sibling-fairness and show the FQSE to be cousin-fair. FQSE is unique in that it is the only hierarchical algorithm that is simultaneously cousin-fair. Furthermore, we show the necessary techniques to adapt FQSE to variable-sized packet-based networks. We analyze FQSE performance in EPON serving 1024 independent queues and demonstrate FQSE's ability to provide guaranteed bandwidth to each queue and to share the excess bandwidth fairly.