Synthesis,structure, and photophysical property of series of Ln(III) coordination polymers with different carboxylato ligands (Ln = Sm,Eu)

Four Ln(III) coordination polymers, {[Ln₂(1,3-bdc)₃(H₂O)₄]·DMF·H₂O} _n (Ln = Sm 1, Eu 2) and [Ln₂(mal)₃(H₂O)₆] _n (Ln = Sm 3, Eu 4) (1,3-H₂bdc = isophthalate acid, H₂mal = malonate acid), were hydrothermally synthesized and characterized by single-crystal X-ray diffraction, elemental analysis, IR spectra, UV–Vis–NIR absorption spectra, and fluorescence spectra. The structural analyses reveal that polymer 1 is a 3D coordination polymer. Its asymmetry unit contains two crystallographically independent Sm(III) ions, both are eight-coordinated. The 1,3-bdc^2? anions show three different coordination modes. The structure of polymer 2 is isomorphous with that of 1. Polymer 3 is also a 3D coordination polymer, its asymmetry unit contains one Sm(III) ion, which is nine-coordinate. The mal^2? anions have two different coordination modes. The structure of polymer 4 is isomorphous with that of 3. The luminescent study shows that polymers 1, 2, and 4 exhibit characteristic emission bands in the visible region, corresponding to the transitions of the Ln(III) ions. By comparison and analysis of luminescence, it is found that the incidence of the same ligand on the corresponding spectra of different Ln(III) ions is different, and the influence of different ligands on luminescence of the same Ln(III) ion is also very different.

     

Impact of environmental conditions on the sorption behavior of UO<Subscript>2</Subscript><Superscript>2+</Superscript> onto attapulgite studied by batch experiments

The sorption of UO₂ ²⁺ from aqueous solution on attapulgite was investigated as a function of contact time, solid content, pH, ionic strength, foreign ions, humic acid (HA), and fulvic acid (FA) under ambient conditions by using batch technique. The attapulgite sample was characterized by XRD and FTIR in detail. The results indicated that the sorption of UO₂ ²⁺ was strongly dependent on pH and ionic strength. The sorption of UO₂ ²⁺ on attapulgite increased quickly with rising pH at pH < 6.5, and decreased with increasing pH at pH > 6.5. The presence of HA or FA enhanced the sorption of UO₂ ²⁺ on attapulgite obviously at low pH because of the strong complexation of surface adsorbed HA/FA with UO₂ ²⁺ on attapulgite surface. Sorption of UO₂ ²⁺ on attapulgite was mainly dominated by ion-exchange or outer-sphere surface complexation at low pH values, but by inner-sphere surface complexation at high pH values. The results indicate that attapulgite is a very suitable adsorbent for the preconcentration and solidification of UO₂ ²⁺ from large volumes of aqueous solutions because of its negative surface charge and large surface areas.     

Organic Thin Film Transistors Based on 2,3‐Dimethylpentacene and 2,3‐Dimethyltetracene

2,3‐Dimethylpentacene (DMP) and 2,3‐dimethyltetracene (DMT) were synthesized, characterized and employed as the channel material in the fabrication of thin‐film transistors. The two methyl groups increase the chemical stability of the compounds versus the pristine acene analogues. The crystals maintain herringbone‐like molecular packing, whereas the weak dipole associated with the unsymmetrical molecule induces an anti‐parallel alignment among the neighbors. This structural motif favors layered film growth on SiO₂/Si surface. Thin film transistors prepared on SiO₂/Si and n‐nonyltrichlorosilane‐modified SiO₂/Si at different substrate temperatures were compared. DMP‐based transistors prepared on rubbed n‐nonyltrichlorosilane‐modified SiO₂/Si substrate gave the highest field‐effect mobility of 0.46 cm²/Vs, whereas DMT‐based transistor gave a mobility of 0.028 cm²/Vs.     

A new cyclopentanone derivative from <Emphasis Type="Italic">Euphorbia hirta</Emphasis>

A new cyclopentanone derivative, (1'R,5'R)-5-(5'-carboxymethyl-2'-oxocyclopentyl)-3Z-pentenyl acetate (1), was isolated from Euphorbia hirta. Its structure was elucidated on the basis of spectroscopic analysis including 1D and 2D NMR techniques. The EtOAc extract of Euphorbia hirta was evaluated against K562 and A549 cancer cell lines.     

Algorithms of common solutions to quasi variational inclusion and fixed point problems

The purpose of this paper is to present an iterative scheme for finding a common element of the set of solutions to the variational inclusion problem with multivalued maximal monotone mapping and inverse-strongly monotone mappings and the set of fixed points of nonexpansive mappings in Hilbert space.Under suitable conditions, some strong convergence theorems for approximating this common elements are proved. The results presented in the paper not only improve and extend the main results in Korpelevich（Ekonomika i Matematicheskie Metody,1976,12（4）：747-756）,but also extend and replenish the corresponding results obtained by Iiduka and Takahashi（Nonlinear Anal TMA,2005,61（3）：341-350）,Takahashi and Toyoda（J Optim Theory Appl,2003, 118（2）：417-428）,Nadezhkina and Takahashi（J Optim Theory Appl,2006,128（1）：191- 201）,and Zeng and Yao（Taiwanese Journal of Mathematics,2006,10（5）：1293-1303）.     

考虑回转性能的三维结构拓扑优化设计

以考虑运动学性能的回转运动体材料最优分布问题为背景,提出并求解了转动惯量约束下的三维结构拓扑优化问题.常规的结构拓扑优化通常构造为给定材料体积约束下的结构最小柔顺性问题.本文指出,引入结构转动惯量约束对于回转结构的拓扑优化具有重要意义.本文将重量约束下的优化准则法计算格式拓广到单个转动惯量约束下的最小柔顺性问题,而对于包含转动惯量约束的多约束问题采用数学规划法求解.本文给出的数值算例验证了所提出算法的正确性,并且表明引入转动惯量约束后可得到与常规拓扑优化问题不同的结构布局形式.     

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通过对套铣筒这种特殊结构钻柱的分析,在现有钻柱力学模型研究的基础上,针对 套铣筒结构特点(大筒径、薄壁筒型钻柱),建立套铣筒与井壁接触力学模型,通过分析套铣 管柱在井下屈曲状态以及与井壁接触压力的计算,对套铣筒进行力学分析以及摩阻力计算.     

The First Principle Formula of the Relativistic Heat Conductivity of Coulomb Electronic Plasmas

Making use of the relativistic BBGKY technique,the relativistic generalization of Landau collision integral is botained.Furthermore,we calculate the relativistic hydrodynamic modes up to the second order in the hydrodynamic wave number.Combining Resibois‘ method,we present the first principle formula of the relativistic heat conductivity of Coulumb electronic plasmas for low-order corrections.     

用统一耦合模理论分析含布拉格光栅的对称光纤耦合器的传输特性

利用由麦克斯韦方程组直接导出的统一耦合模理论分析各类型的含布拉格光栅的对称光纤耦合器的传输特性。与以前发表的分析方法不同,对于含布拉格光栅的耦合区域,统一耦合模型理论同时考虑了布拉格光栅和耦合的耦合作用。模拟结果证明它能精确地模拟和解释各种类型的含布拉格光栅的对称光纤耦合器的有关实验现象。     

Construction of stationary self-similar generalized fields by random wavelet expansion

Random wavelet expansion is introduced in the study of stationary self-similar generalized random fields. It is motivated by a model of natural images, in which 2D views of objects are randomly scaled and translated because the objects are randomly distributed in the 3D space. It is demonstrated that any stationary self-similar random field defined on the dual space of a Schwartz space of smooth rapidly decreasing functions has a random wavelet expansion representation. To explicitly construct stationary self-similar random fields, random wavelet expansion representations incorporating random functionals of the following three types are considered: (1) a multiple stochastic integral over the product domain of scale and translate, (2) an iterated one, first integrating over the scale domain, and (3) an iterated one, first integrating over the translate domain. We show that random wavelet expansion gives rise to a variety of stationary self-similar random fields, including such well-known processes as the linear fractional stable motions. Received: 11 December 1998 / Revised version: 31 January 2001 / Published online: 23 August 2001