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871.
872.
离子色谱荧光检测法测定废水中痕量2-氨基联苯和4-氨基联苯 总被引:2,自引:0,他引:2
采用离子色谱荧光检测法测定废水中的2-氨基联苯(2-ADP)和4-氨基联苯(4-ADP),流动相为1.0mL/min的0.06mol/L NaCl,0.08mol/L HCl,40%(V/V)ACN,分离柱为Dinoex OmniPac PCX-500,该法具有良好的重现性和线性关系,2-ADP和4-ADP的回收率分别为98.5%-101.4%和102.2%-104.0%,检测限分别为0.006mg/L和0.10mg/L。 相似文献
873.
Jin-Hua Cai Jin-Wang Huang Ping Zhao Yuan-Jian Ye Han-Cheng Yu Liang-Nian Ji 《Journal of Sol-Gel Science and Technology》2009,50(3):430-436
Three types of novel silica-metalloporphyrins hybrid materials, Si-S-APTCPPFe, Si-S-APTCPPMn and Si-S-APTCPPCo, were prepared
at room temperature by sol–gel method involving a thiol-ene polymerization reaction of 5-(4-allyloxy)phenyl-10,15,20-tri(4-chlorophenyl)porphyrin
(APTCPP) with 3-mercaptopropyltrimethoxysilane (MPS). The hybrid materials were characterized by XRD, SEM, FT–IR, UV–Vis and
TG, and were investigated as catalysts for the aerobic oxidation of cyclohexane. It is found that these hybrid materials are
more efficient catalysts than the analogous non-supported metalloporphyrins for cyclohexane hydroxylation in metalloporphyrin–O2–ascrobate system and the metal ion in the porphyrins significantly affected the catalytic efficiencies of these hybrid materials. 相似文献
874.
Ultrathin Co3S4 Nanosheets that Synergistically Engineer Spin States and Exposed Polyhedra that Promote Water Oxidation under Neutral Conditions 下载免费PDF全文
Youwen Liu Dr. Chong Xiao Mengjie Lyu Dr. Yue Lin Weizheng Cai Pengcheng Huang Prof. Wei Tong Prof. Youming Zou Prof. Yi Xie 《Angewandte Chemie (International ed. in English)》2015,54(38):11231-11235
Development of efficient and affordable electrocatalysts in neutral solutions is paramount importance for the renewable energy. Herein, we report that the oxygen evolution reaction (OER) performance of Co3S4 under neutral conditions can be enhanced by exposed octahedral planes and self‐adapted spin states in atomically thin nanosheets. A HAADF image clearly confirmed that the active octahedra with Jahn–Teller distortions were exposed exclusively. Most importantly, in the atomically thin nanosheets, the spin states of Co3+ in the octahedral self‐adapt from low‐spin to high‐spin states. As a result, the synergistic effect endow the Co3S4 nanosheets with superior OER performance, with exceptional low onset overpotentials of circa 0.31 V in neutral solutions, which is state‐of‐the‐art among inorganic non‐noble metal compounds. 相似文献
875.
基于YNS层合板理论,通过对混合能变分原理的修正,建立了层合板问题的Hamilton正则方程。在辛几何数学框架下,采用共轭辛正交归一关系给出精确解。并与经典层板理论进行了比较。 相似文献
876.
关于陀螺信号处理中小波基选取的研究 总被引:9,自引:1,他引:9
在建立陀螺漂移的数学模型的基础上,使用不同的小波基对陀螺输出信号进行多尺度小波分解,去除由噪声产生的小波系数,从而达到消除噪声的目的。从不同小波基的滤波效果来看,双正交样条小波Biorl.5具有较好的去噪效果,从而也验证了小波对称性在陀螺信号去噪中的重要性。 相似文献
877.
Li-Wei Wang Songwei Jiang Ying-Hui Yuan Jilong Duan Nian-Dong Mao Zi Hui Renren Bai Tian Xie Xiang-Yang Ye 《Molecules (Basel, Switzerland)》2022,27(8)
As one of the key phosphatidylinositol 3-kinase-related kinases (PIKKs) family members, ataxia telangiectasia and RAD3-related protein kinase (ATR) is crucial in maintaining mammalian cell genomic integrity in DNA damage response (DDR) and repair pathways. Dysregulation of ATR has been found across different cancer types. In recent years, the inhibition of ATR has been proven to be effective in cancer therapy in preclinical and clinical studies. Importantly, tumor-specific alterations such as ATM loss and Cyclin E1 (CCNE1) amplification are more sensitive to ATR inhibition and are being exploited in synthetic lethality (SL) strategy. Besides SL, synergistic anticancer effects involving ATRi have been reported in an increasing number in recent years. This review focuses on the recent advances in different forms of synergistic antitumor effects, summarizes the pharmacological benefits and ongoing clinical trials behind the biological mechanism, and provides perspectives for future challenges and opportunities. The hope is to draw awareness to the community that targeting ATR should have great potential in developing effective anticancer medicines. 相似文献
878.
近江牡蛎受精细胞学研究 总被引:5,自引:0,他引:5
用醋酸──地衣红染色的方法对近江牡蛎人工授精的卵子减数分裂和受精过程进行了详细的细胞学观察.精子入卵前,卵子处于第一次减数分裂的前期(胚泡期),精子入卵后,胚泡消失,然后进行两次减数分裂,在海水温度为28.8℃的情况下,授精后33min和45min,绝大部分受精卵已排出第一极体和第二极体,雄原核可在第一极体排出后及第二极体排出前任何时期内形成,雌雄原核以联合的方式将两组染色体合并,授精后1h,大部分卵子完成第一次卵裂.在25℃和26℃授精的情况下,观察到了较多的多精入卵的现象.卵子发育的非同步性现象非常明显. 相似文献
879.
Considered is a system of delay differential equations modeling a time-delayed connecting network of three neurons without self-feedback. Discussing the change of the number of eigenvalues with zero real part, we locate the boundary of the stability region and finally determine the largest stability region of trivial solution. We investigate the existence of bifurcation phenomena of codimension one/two of the trivial equilibrium by considering the intersections of some parameter curves, which, in the aτ-half parameter plane, correspond to zero root or pure imaginary roots. In particular, the equivariant bifurcation is studied because of the equivariance of the system. We also present numerical simulations to demonstrate the rich dynamical behavior near the equivariant Pitchfork-Hopf bifurcation points, Hopf-Hopf bifurcation points, and some higher codimension bifurcation points. 相似文献
880.
Zhi CHENG Yu YE 《数学学报(英文版)》2007,23(6):965-972
We introduce the category of t-fold modules which is a full subcategory of graded modules over a graded algebra. We show that this subcategory and hence the subcategory of t-Koszul modules are both closed under extensions and cokernels of monomorphisms. We study the one-point extension algebras, and a necessary and sufficient condition for such an algebra to be t-Koszul is given. We also consider the conditions such that the category of t-Koszul modules and the category of quadratic modules coincide. 相似文献