A Large Conformational Change of a Bridged b-Cyclodextrin Dimer in Aqueous Solution

As artificial enzymes, the binding constants of cyclodextrins (CDs) and their substrates are expected to be high1. For this purpose, many kinds of bridged cyclodextrin dimers2 whose two cyclodextrins are linked by various spacers have been constructed. It was of interest to make the dimers, whose binding constants would exceed 108dm3/mol3. Up to date, the bridged cyclodextrin dimers have been extensively studied as enzyme models and as molecular receptors4-6. Recently, we synthesized a brid…     

Performance of various activators in ethylene polymerization based on an iron(II) catalyst system

Ethylisobutylaluminoxane (EBAO) and its analogues were synthesized by a reaction between an triethylaluminum (Et₃Al)/triisobutylaluminum (i‐Bu₃Al) mixture and 4‐fluorobenzeneboronic acid, phenylboronic acid, or n‐butaneboronic acid and subsequent hydrolysis with water. They were used as cocatalysts in ethylene polymerization catalyzed by an iron complex {[(ArN?C(Me))₂C₅H₃N]FeCl₂, where Ar is 2,6‐diisopropylphenyl}. Polyethylene with a high molecular weight and a narrow molecular weight distribution was prepared with modified EBAOs, and the performance of the iron complex at high polymerization temperatures was greatly improved. The activators for the iron complex also affected the polymerization activity and the molecular weight of the resultant polyethylene. It was suggested that the stereo and electronic effects of the substitute groups of aluminoxane contributed to the improved performance of the new activators. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 1093–1099, 2004     

NMR investigation of concentrated alumina and silica slurries

The longitudinal relaxation times (T₁) of water in concentrated silica and alumina slurries were measured as a function of solids content. It was shown that the results could be fit very well with a two-phase fast-exchange model between free and surface-bound water. As expected, values of T₁ for bound water were in the order of 20–2000 times lower than that for free water, indicating a higher effective viscosity of the surface-bound water. The strength of the interaction depended on the particular surface, and all of the aluminas examined interacted more strongly with water than the two silicas studied, which themselves differed considerably. The chemical mechanical polishing (CMP) removal rate of tantalum by silica slurries was shown to be directly correlated with the interaction parameters, derived from the NMR relation times rather than with total surface hydroxyl group concentration.     

微波谐振腔Q值对磁激子振幅不稳定态阈值的影响

基于Safonov和Yamazaki所发展的激励自旋波非线性辐射衰减的理论［J. MMM. 161 (1996 ) 275］, 考虑磁激子与磁激子以及磁激子与光子的两种非线性相互作用过程，计算了微波谐振腔Q值对磁激子振幅不稳定态阈值的影响，结果与实验数据基本一致. 关键词： 磁激子 谐振器 铁磁体     

带限信号高频重建的一种新的正则外推算法

本文提出生种新的带限信号的外推方法，该方法能够很好地抑制噪声干扰，且计算复杂性较低，本文给出算法，证明了收敛性，最后给出了误差计算机实验结果。     

开关DC—DC变换器并联运行问题的研究

开关直流电源并联运行在许多场合应用。每一路电源输出阻抗的不一致性使每一路输出电流难以均衡，影响了系统的可靠性。本文提出了一种双回路ＤＣ—ＤＣ变换器的控制方案。由于采用电压环（外环）和电流环（内环）两环结构的双回路控制模式，变换器输出电流得到了有效控制，便于多个ＤＣ—ＤＣ变换器输出直接并联，从而实现了模块化，具有一定的实用性     

用于非均匀介质重建的选代算法收敛性的研究

研究轴对称二维非均匀介质重建迭代算法的收敛性问题。首先借助于玻恩近似将非线性积分方程线性化，然后，利用玻恩迭代法和变形玻恩迭代法，由散射场数据对轴对称二维非均匀介质进行重建。通过几个例子研究了影响迭代算法收敛性的几种因素，如送代算法本身、积分离散化后的网格划分、正则化方法中的正则化参数选取等。     

一种多径环境下基于四阶累积量的阵列扩展测向方法

本文分析了基于四阶累积量的测向方法不能正确测量多径信号方向的原因，提出了一种多径环境下的基于四阶累积量的新型测向方法。该方法利用零点领处理方法抑制多径信号，然后采用四阶累积量进行阵列扩展测向。计算机模拟结果表明该方法在多径环境下具有良好的性能并且可能实现对足够多的信号进行测向。     

帧中继交换技术

本文论述了帧中继交换的概念、标准，结构、特点网络式样及在互连网中的应用。     

单麦克风和双麦克风语音增强系统的研究

本文对采用减谱法和箱关法的语音增强系统进行了研究，系统的噪声为白噪声和普通机房噪声。减谱法采用单麦克风输入，试验中发现语音的分帧方法对消噪影响很大，通过比较得到了一种具有明显消噪效果的分帧方法，在相关法中采用双麦克风输入，对两个输入信号之间的时延差进行了补偿，在求维纳滤波器系数时，对信号谱进行统计平均，从而使消噪后的语音信号具有较好的自然度。在研究以上两种方法的基础上，我们提出了一种混合消噪系统，