Indirect Control of Donor/Acceptor Interactions for Highly Efficient Space-Confined Thermally Activated Delayed Fluorescence Emitters

Conformational engineering is essential to further reinforce the luminescent properties of thermally activated delayed fluorescence (TADF) materials featuring through-space charge transfer (TSCT) characteristics. Herein, two TSCT-TADF emitters (8MeDM-B and 8FDM-B) with the methyl and fluorine moieties substituted at the C8 site of the rigid spiro-fluorene bridge is reported. Derivation of the C8 site is first proposed to control the molecular configuration with the ability to indirectly tune the intramolecular interaction between donor and acceptor groups. As a result, 8MeDM-B and 8FDM-B both present small singlet-triplet energy gaps, fast reverse intersystem crossing rates, and high photoluminescence quantum yields. Interestingly, the smaller fluorine atom not the bigger methyl group exhibits more evident electrostatic repulsive force onto the central donor and thus rectifies the central spiro structure. Consequently, the high external quantum efficiency values of 28.8% and 31.7% for 8MeDM-B and 8FDM-B-based electroluminescence devices are achieved, respectively. This study offers a measure for enhancing TSCT-TADF emitters without directly modifying the donor or acceptor.     

Fast Ion Transport in Li-Rich Alloy Anode for High-Energy-Density All Solid-State Lithium Metal Batteries

All-solid-state Li batteries (ASSLBs) with solid-polymer electrolytes are considered promising battery systems to achieve improved safety and high energy density. However, Li dendrite formation at the Li anode under high charging current density/capacity has limited their development. To tackle the issue, Li-metal alloying has been proposed as an alternative strategy to suppress Li dendrite growth in ASSLBs. One drawback of alloying is the relatively lower operating cell voltages, which will inevitably lower energy density compared to cells with pure Li anode. Herein, a Li-rich Li₁₃In₃ alloy electrode (LiRLIA) is proposed, where the Li₁₃In₃ alloy scaffold guides Li nucleation and hinders Li dendrite formation. Meanwhile, the free Li can recover Li's potential and facilitate fast charge transfer kinetics to realize high-energy-density ASSLBs. Benefitting from the stronger adsorption energy and lower diffusion energy barrier of Li on a Li₁₃In₃ substrate, Li prefers to deposit in the 3D Li₁₃In₃ scaffold selectively. Therefore, the Li–Li symmetric cell constructed with LiRLIA can operate at a high current density/capacity of 5 mA cm⁻²/5 mAh cm⁻² for almost 1000 h.     

Ultra-Wideband Electrostrictive Mechanical Antenna

Mechanical antennas based on piezoelectric materials can effectively reduce the size of long wave antennas down to 1/1000 of the wavelength (from km scale to mm level). However, the narrow bandwidth and weak field intensity seriously restrict its practical applications in transmission distance and channel capacity. Here, a mechanical antenna-based electrostrictive effect of relaxor ferroelectric ceramic (PMN-PT) is proposed to improve radiation capacity and achieve ultra-wideband characteristics (10 kHz–1 MHz). Due to the ultra-high dielectric constant at working temperature and the relationship between the strain and applied field intensity, the proposed antenna gets rid of the dependence on the poled materials and exhibits excellent communication properties beyond traditional mechanical antennas, which are experimentally demonstrated by a practical wireless communication system. Only using a single proposed mechanical antenna with 8 mm diameter and 3 mm thickness, the effective communication with a transmission distance of 200 m can be realized. This design offers a promising way of constructing mechanical antennas for long-wave communication.     

基于地理坐标系组网雷达目标速度转换方法研究

在组网雷达系统中,进行数据处理前,首先需要进行的是目标观察值的时间、空间同步,即将数据转换到统一坐标系中,同时外推到统一时刻。本文主要讨论了由于地球曲率影响带来的上报速度误差,提出了一种基于坐标转换,利用全微分矩阵进行上报速度的转换,消除该种误差。仿真结果表明,该改进算法较工程中应用的两点外推法,算法的计算量和复杂度得到了有效降低。     

高精度机器视觉对准测量系统设计

设计了用于半导体先进封装光刻设备中的高精度机器视觉对准测量系统,明确了机器视觉对准测量系统工作原理、设计指标及系统设计中需要考虑的关键技术点,同时给出了机器视觉对准测量系统关键零部件的设计,并给出了对准测量系统最终在整机上测得的性能数据。测试结果表明,所设计的机器视觉对准测量系统完全可以满足集成电路先进封装工艺需求。     

不同E_b/N_0条件下误码性能测试

对数字卫星通信系统中Eb/N0与(C0+N0)/N0的关系进行了详细分析,并给出了二者之间的转换公式,在此基础上,将Eb/N0与误码率间的关系转化为(C0+N0)/N0与误码率间的关系。最后给出了(C0+N0)/N0和误码率测试的方法和测试中的注意事项。     

基于核函数的系统模型辨识

本文提出一种基于核函数的系统模型辨识方法。首先通过线性最小二乘确定低维空间中的非线性子空间,并经主分量分析提取与线性子空间基向量近似正交的非线性主分量,再经核密度估计进行聚类,自适应选择多个核将非线性子空间映射到高维空间,从而将任何一个线性和非线性的联合问题最终变成一个高维空间中的线性问题,最后借助线性最小二乘获得一个精确参数的系统模型。经过实验验证,该方法具有较好的效果。     

基于运动矢量分布特征的半像素快速搜索算法

针对MPEG-4视频编码中半像素全搜索方法运算量较大的缺点,提出一种基于运动矢量分布特征的快速半像素运动矢量搜索算法。试验表明最佳半像素运动矢量的分布具有一定的规律,即大多数的运动矢量分布在水平或垂直两个共扼方向上。因此在满足一定条件的前提下水平和垂直方向上的运动矢量被优先搜索,其次搜索其余的点。仿真结果表明本算法可以使半像素平均搜索点数减少71%,而编码质量和码流长度并没有明显降低或增加。     

基于不同醇的醇水法制备纳米CeO2的研究

在四种醇水体系中,以HMT为缓释沉淀剂制备了纳米CeO2粉体。研究了醇的种类、醇水比例及煅烧温度对纳米CeO2颗粒尺寸的影响;并用XRD,BET,TEM,TGA/DSC等表征方法对其影响机理进行了探讨。结果表明:溶剂从甲醇到异丙醇变化时,颗粒逐渐增大;异丙醇到正丁醇时,颗粒尺寸略有降低,且煅烧前颗粒尺寸均介于10~20nm之间。     

军用电台射频性能的三维测试

射频测试是电台性能测试的一项基本内容.本文将已经标准化了的手机与无线局域网的射频测试内容和方法引入军用电台的射频性能测试中,定量地考察了电台的辐射性能.并提出该方法同样适用于我军的高速数据电台.