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91.
Qin Yang Bingqing Ge Pei Yuan Shuting Luo Hongwei Zhang Zhengyu Zhao Jiujun Zhang Shidong Wang Xiaojun Bao Xiangdong Yao 《Advanced functional materials》2023,33(25):2214588
Electrocatalytic hydrogenation (ECH) is a burgeoning strategy for the sustainable utilization of hydrogen. However, how to effectively suppress the competitive hydrogen evolution reaction (HER) is a big challenge to ECH catalysis. In this study, amine (NH2 R)-coordinated Pd nanoparticles loaded on carbon felt (Pd@CF) as a catalyst is successfully synthesized by a one-step solvothermal reduction method using oleylamine as the reducing agent. An exceptional ECH reactivity on benzaldehyde is achieved on the optimal Pd@CF catalyst in terms of a high conversion (89.7%) and selectivity toward benzyl alcohol (89.8%) at −0.4 V in 60 min. Notably, the Faradaic efficiency for producing benzyl alcohol is up to 90.2%, much higher than that catalyzed by Pd@CF-without N-group (41.1%) and thecommercial Pd/C (20.9%). The excellent ECH performance of Pd@CF can be attributed to the enriched electrons on Pd surface resulted from the introduction of NH2 R groups, which strengthens both the adsorption of benzaldehyde and the adsorbed hydrogen (Hads) on Pd, preventing the combination of Hads to form H2, that is, inhibiting the HER. This study gives a new insight into design principles of highly efficient electrocatalysts for the hydrogenation of unsaturated aldehydes molecules. 相似文献
92.
Yuan Deng Yihai Yang Yuanhang Xiao He-Lou Xie Ruochen Lan Lanying Zhang Huai Yang 《Advanced functional materials》2023,33(35):2301319
Switchable passive radiative cooling (PRC) smart windows can modulate sunlight transmission and spontaneously emit heat to outer space through atmospheric transparent window, presenting great potential in building energy conservation. However, realizing stable and on-demand control of the cooling efficiency for PRC materials is still challenging. Herein, an electro-controlled polymer-dispersed liquid crystal (PDLC) smart window showing PRC property is designed and prepared by adding mid-infrared emitting reactive monomers into the conventional PDLC matrix. It is found that not only the electro-optical properties but also the PRC efficiency of PRC PDLC film are tunable by regulating the content of the mid-infrared emitting components, film thickness, and micromorphology. This advanced PRC PDLC material achieves a near/sub-ambient temperature when the solar irradiance is below 400 W m−2 and can dynamically manage daytime cooling efficiency. Importantly, its PRC efficiency is capable of being tuned in an on-demand and ultrafast millisecond-scale way, whose controllable transparency enables multistage heat regulation. This study is hoped to provide new inspiration in the preparation of advanced optical devices and energy-efficient equipment. 相似文献
93.
Hui Zhang Yinkun Sun Junjie Yang Zhiyu Sun Yanxin Zhao Xin Li Wei Wang Dongwei Lu Jun Ma 《Advanced functional materials》2023,33(40):2302816
Precise adjustment of the pore size, damage repair, and efficient cleaning is all challenges for the wider application of inorganic membranes. This study reports a simple strategy of combining dry-wet spinning and electrosynthesis to fabricate stainless-steel metal–organic framework composite membranes characterized by customizable pore sizes, targeted reparability, and high catalytic activity for membrane cleaning. The membrane pore size can be precisely customized in the range of 14–212 nm at nanoscale, and damaged membranes can be repaired by targeted treatment in 120 s. In addition, advanced oxidation processes can be used to quickly clean the membrane and achieve 98% flux recovery. The synergistic actions of the membrane matrix and the selective layer increase the adsorption energy of active sites to oxidant, shorten the electron transfer cycle, and enhance the overall catalytic performance. This study can provide a new direction for the development of advanced membranes for water purification and high-efficiency membrane cleaning methods. 相似文献
94.
Jine Zhang Xiaobing Chen Mengqin Wang Qinghua Zhang Wenxiao Shi Xiaozhi Zhan Meng Zhao Zhe Li Jie Zheng Hui Zhang Furong Han Huaiwen Yang Tao Zhu Banggui Liu Fengxia Hu Baogen Shen Yuansha Chen Yue Zhang Yunzhong Chen Weisheng Zhao Jirong Sun 《Advanced functional materials》2023,33(41):2306434
Ferromagnetic materials with a strong spin-orbit coupling (SOC) have attracted much attention in recent years because of their exotic properties and potential applications in energy-efficient spintronics. However, such materials are scarce in nature. Here, a proximity-induced paramagnetic to ferromagnetic transition for the heavy transition metal oxide CaRuO3 in (001)-(LaMnO3/CaRuO3) superlattices is reported. Anomalous Hall effect is observed in the temperature range up to 180 K. Maximal anomalous Hall conductivity and anomalous Hall angle are as large as ∼15 Ω−1 cm−1 and ∼0.93%, respectively, by one to two orders of magnitude larger than those of the typical 3d ferromagnetic oxides such as La0.67Sr0.33MnO3. Density functional theory calculations indicate the existence of avoid band crossings in the electronic band structure of the ferromagnetic CRO layer, which enhances Berry curvature thus strong anomalous Hall effects. Further evidences from polarized neutron reflectometry show that the CaRuO3 layers are in a fully ferromagnetic state (∼0.8 μB/Ru), in sharp contrast to the proximity-induced canted antiferromagnetic state in 5d oxides SrIrO3 and CaIrO3 (∼0.1 μB/Ir). More than that, the magnetic anisotropy of the (001)-(LaMnO3/CaRuO3) superlattices is eightfold symmetric, showing potential applications in the technology of multistate data storage. 相似文献
95.
Wireless Personal Communications - With the rapid development of information technology, issues such as network security and privacy protection have attracted more and more attention. The... 相似文献
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