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Mg-based hydrogen storage alloys Mg0.9Ti0.1-xZrxNi (x=0.02, 0.04, 0.06) were successfully prepared by means of mechanical alloying (MA). The effects of Zr addition on the discharge capacity and the cycle performance of the Mg-based electrodes were also studied. It was found that the discharge capacities were improved with addition of a small amount of Zr and the cycle performances of the alloy were stabilized with the addition of Ti. The effects of surface modification or coating on the properties of Mg0.9Ti0.06Zr0.04Ni were also studied. The results indicated that coating with graphite improved both the discharge capacity and cycle life of the amorphous Mg0.9Ti0.06Zr0.04Ni electrode. 相似文献
184.
A new ion selective electrode for salicylate based on N,N'-(aminoethyl)ethylenediamide bis(2-salicylideneimine) binuclear copper(Ⅱ) complex [Cu(Ⅱ)2-AEBS] as an ionophore was developed. The electrode has a linear range from 1.0 × 10^-1 to 5.0 ×10^-7 mol·L^- 1 with a near-Nemstian slope of ( - 55 ±1 ) mV/decade and a detection limit of 2.0 × 10-7 mol·L^-1 in phosphorate buffer solution of pH 5.0 at 25 ℃. It shows good selectivity for Sal^- and displays anti-Hofmeister selectivity sequence: Sal^-〉SCN^-〉 ClO4^- 〉I^-〉 NO2^- 〉Br^-〉 NO3^- 〉Cl^-〉 SO3^2- 〉 SO4^2- The proposed sensor based on binuclear copper(Ⅱ)complex has a fast response time of 5-10 s and can be used for at least 2 months without any major deviation. The response mechanism is discussed in view of the alternating current (AC) impedance technique and the UV-vis spectroscopy technique. The effect of the electrode membrane compositions and the experimental conditions were studied. The electrode has been successfully used for the determination of salicylate ion in drug pharmaceutical preparations. 相似文献
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The properties of immobilized glucose oxidase (GOD) by the complexes of diethylaminoethyl cellulose(DEAEC) with different polymers, such as polymethylacrylic acid (PMAA), polyacrylic acid (PAA), polystyrene sulfonic acid (PSSA), polyvinylaleohol (PVA), polyethylene oxide (PEO) and styrene-maleic acid copolymer (PSMA) were investigated. The activity of immobilized GOD was obviously influenced by the component of the DEAEC complexes. The relative activity of the immobilized GOD reached to maximum and over 90% of the native GOD. when the DEAEC-PMAA DEAEC-PAA complexes were used as a carrier with the molar ratio of DEAEC and polyacid of about one. Michaelis constants (Km) of the immobilized enzymes of DEAEC-GOD-PMAA and DEAEC-GOD-PAA were determined to be 1.25 and 1.00, respectively. Moreover, the immobilized GOD has a good storage stability and cyclic life. 相似文献
187.
Thermochemical Properties and Decomposition Kinetics of Ammonium Magnesium Phosphate Monohydrate 总被引:1,自引:0,他引:1
Ammonium magnesium phosphate monohydrate NH4MgPO4·H2O was prepared via solid state reaction at room temperature and characterized by XRD, FT-IR and SEM. Thermochemical study was performed by an isoperibol solution calorimeter, non-isothermal measurement was used in a multivariate non-linear regression analysis to determine the kinetic reaction parameters. The results show that the molar enthalpy of reaction above is (28.795 ± 0.182) kJ/mol (298.15 K), and the standard molar enthalpy of formation of the title complex is (-2185.43 ± 13.80) kJ/mol (298.15 K). Kinetics analysis shows that the second decomposition of NH4MgPO4·H2O acts as a double-step reaction: an nth-order reaction (Fn) with n=4.28, E1=147.35 kJ/mol, A1=3.63×10^13 s^-1 is followed by a second-order reaction (F2) with E2=212.71 kJ/mol, A2= 1.82 × 10^18 s^-1. 相似文献
188.
蛋白质的硫巯化是一种重要的氧化翻译后修饰,在细胞衰老、内质网应激、血管舒张、细胞凋亡等过程中扮演重要角色。利用蛋白质组学技术表征硫巯化修饰具有十分重要的意义。该文发展了一种基于碘乙酸功能化的聚酰胺-胺树枝状聚合物(PAMAM-INS),并结合滤膜辅助的样品预处理技术用于硫巯化肽段的富集(简称FADE策略),利用FADE策略能从100倍质量干扰的牛血清白蛋白酶解产物中选择性地富集出硫巯化标准肽段。将细胞培养稳定同位素标记技术引入到FADE策略中,并将其应用于不同浓度梯度硫氢化钠刺激的SHSY5Y细胞硫巯化蛋白质组分析,共鉴定到163条硫巯化肽段。生物信息学的结果表明,硫巯化修饰可能在中枢神经系统中扮演着重要角色。 相似文献
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190.
葡聚糖为载体的双亲型LDL吸附剂吸附动力学研究 总被引:3,自引:0,他引:3
合成了以葡聚为载体,同时具有亲水性磺酸基和疏水性胆固醇两类配基的新型低密度脂蛋白(LDL)吸附剂。通过对LDL纯溶液中吸附等温线的测试,比较了以Dextran G-75为载体的双亲型LDL吸附剂与单一亲水型磺酸基配基,单一疏水型胆固醇基吸附剂吸附量和亲和吸附系数的关系。对双亲型LDL吸附剂的吸附动力学进行了初步研究,在LDL溶液中,亲水型磺酸基,疏水型胆固醇配基,双亲型LDL吸附剂对LDL的吸附曲线基本上符合Langmuir吸附方程,另外通过高离子强度NaCl洗脱实验,测定了双亲型LDL吸附剂上具有的磺酸基与胆固醇两类基在对低密脂蛋白吸附过程中所起的配合效果,为下一步作用力机制研究提供了参考依据。 相似文献