全文获取类型
收费全文 | 30467篇 |
免费 | 5313篇 |
国内免费 | 4444篇 |
专业分类
化学 | 14870篇 |
晶体学 | 362篇 |
力学 | 1303篇 |
综合类 | 314篇 |
数学 | 2338篇 |
物理学 | 8853篇 |
无线电 | 12184篇 |
出版年
2024年 | 176篇 |
2023年 | 765篇 |
2022年 | 1214篇 |
2021年 | 1275篇 |
2020年 | 1268篇 |
2019年 | 1219篇 |
2018年 | 1093篇 |
2017年 | 1191篇 |
2016年 | 1312篇 |
2015年 | 1593篇 |
2014年 | 1834篇 |
2013年 | 2268篇 |
2012年 | 2689篇 |
2011年 | 2605篇 |
2010年 | 2072篇 |
2009年 | 2250篇 |
2008年 | 2300篇 |
2007年 | 2120篇 |
2006年 | 2021篇 |
2005年 | 1686篇 |
2004年 | 1183篇 |
2003年 | 893篇 |
2002年 | 837篇 |
2001年 | 744篇 |
2000年 | 641篇 |
1999年 | 494篇 |
1998年 | 327篇 |
1997年 | 307篇 |
1996年 | 278篇 |
1995年 | 260篇 |
1994年 | 211篇 |
1993年 | 202篇 |
1992年 | 173篇 |
1991年 | 121篇 |
1990年 | 113篇 |
1989年 | 77篇 |
1988年 | 71篇 |
1987年 | 65篇 |
1986年 | 59篇 |
1985年 | 44篇 |
1984年 | 34篇 |
1983年 | 36篇 |
1982年 | 14篇 |
1981年 | 16篇 |
1980年 | 13篇 |
1979年 | 11篇 |
1978年 | 8篇 |
1975年 | 5篇 |
1971年 | 4篇 |
1965年 | 8篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
11.
12.
The article referenced above was first published online on 7 August 2007 with incorrect pagination; the pagination has now been corrected online and in print. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
13.
Kan‐Yi Pu Yi Chen Xiao‐Ying Qi Chun‐Yang Qin Qing‐Quan Chen Hong‐Yu Wang Yun Deng Qu‐Li Fan Yan‐Qin Huang Shu‐Juan Liu Wei Wei Bo Peng Wei Huang 《Journal of polymer science. Part A, Polymer chemistry》2007,45(16):3776-3787
In this contribution, we demonstrate a new effective methodology for constructing highly efficient and durable poly(p‐phenyleneethynylene) (PPE) containing emissive material with nonaggregating and hole‐facilitating properties through the introduction of hole‐transporting blocks into the PPE system as the grafting coils as well as building the energy donor–acceptor architecture between the grafting coils and the PPE backbone. Poly(2‐(carbazol‐9‐yl)ethyl methacrylate) (PCzEMA), herein, is chosen as the hole‐transporting blocks, and incorporated into the PPE system as the grafting coils via atom transfer radical polymerization. The chemical structure of the resultant copolymer, PPE‐g‐PCzEMA, was characterized by NMR and gel permeation chromatography, showing that the desirable copolymer was obtained with the narrow polydispersity. The increased thermal stability of PPE‐g‐PCzEMA was confirmed by thermogravimetric analysis and differential scanning calorimetry along with its macroinitiator. The optoelectronic properties of this copolymer were studied in detail by ultraviolet‐visible absorption, photoluminescence emission and excitation spectra, and cyclic voltammogram (CV). The results indicate that PPE‐g‐PCzEMA exhibits the solid‐state luminescent property dominated by individual lumophores, and also the energy transfer process from the PCzEMA blocks to the PPE backbone with a relatively higher energy transfer efficiency in the solid‐state compared to that of the solution state. Additionally, the hole‐injection property is greatly facilitated due to the presence of PCzEMA, as confirmed by CV profiles. All these data indicate that PPE‐g‐PCzEMA is a good candidate for use in optoelectronic devices. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3776–3787, 2007 相似文献
14.
15.
Peng Xu Haitao Wang Rui Lv Qiangguo Du Wei Zhong Yuliang Yang 《Journal of polymer science. Part A, Polymer chemistry》2006,44(12):3911-3920
A novel microphase‐inversion method was proposed for the preparation of TiO2–SiO2/poly(methyl methacrylate) core–shell nanocomposite particles. The inorganic–polymer nanocomposites were first synthesized via a free‐radical copolymerization in a tetrahydrofuran solution, and the poor solvent was added slowly to induce the microphase separation of the nanocomposite and result in the formation of nanoparticles. The average particle sizes of the microspheres ranged from 70 to 1000 nm, depending on the reaction conditions. Transmission electron microscopy and scanning electron microscopy indicated a core–shell morphology for the obtained microspheres. Thermogravimetric analysis and X‐ray photoelectron spectroscopy measurements confirmed that the surface of the nanocomposite microspheres was polymer‐rich, and this was consistent with the core–shell morphology. The influence of the synthetic conditions, such as the inorganic composition and the content of the crosslinking monomer, on the particle properties was studied in detail. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 3911–3920, 2006 相似文献
16.
Peng Chen Jun Chen Baoqing Zhang Jun Zhang Jiasong He 《Journal of Polymer Science.Polymer Physics》2006,44(6):1020-1030
Polycarbonate (PC) was melt blended with small amount of liquid‐crystalline polymer (LCP) and various contents of glass beads (GB) having different diameters. The rheological measurements indicated that the GB addition increased the viscosity ratio and seemed unfavorable to the LCP fibrillation. However, the morphological observation showed that the LCP fibrillation was promoted by the GB addition and varied with the GB packing. With the increased GB packing by increasing the GB content and/or decreasing the GB diameter, LCP deformed from spheres and ellipsoids into stretched ellipsoids at lower shear rates and into long fibrils at higher shear rates. Although higher content of smaller GB jammed into the larger LCP droplets and inhibited the LCP fibrillation, very long LCP fibrils formed at higher shear rates at a high enough packing of GB. The relationship between GB packing and LCP fibrillation revealed two kinds of hydrodynamic effects of GB promoting the LCP fibrillation: at lower GB packing, the shear flow was enhanced by the high local shear between GB, in quantity; and for a high enough GB packing, the shear flow was changed, in quality, into elongational flow, which was more effective for the LCP fibrillation. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 1020–1030, 2006 相似文献
17.
18.
We consider the problem of reconstructing tomographic imagery from fan-beam projections using the direct Fourier method (DFM). Previous DFM reconstructions from parallel-beam projections produced images of quality comparable to that of filtered convolution back-projection. Moreover, the number of operations using DFM in the parallel-beam case is proportional to N2 log N versus N3 for back projection [3]. The fan-beam case is more complicated because additional interpolation of the nonuniformly spaced rebinned data is required. We derive bounds on the detector spacing in fan-beam CT that enable direct Fourier reconstruction and describe the full algorithm necessary for processing the fan-beam data. The feasibility of the method is demonstrated with an example. A key result of this paper is that high-quality imagery can be reconstructed from fan-beam data using the DFM in 0 (N2 log N) operations. 相似文献
19.
FFC-1离子交换纤维对酸碱有害气体吸附性能的研究 总被引:8,自引:0,他引:8
系统考察了不同直径及反离子形式的FFC-1聚羧酸离子交换纤维对酸碱有害气体的穿透吸附,各种温、湿度条件下的吸水率,以及作为有害气体吸附滤除材料的重复使用与再生性能。研究表明:FFC-1纤维直径的减小有利于提高对有害气体的动态吸附容量。在体系温度、相对湿度分别为15℃、50%时,以3D腈纶为起始原料的钠型FFC-1离子交换纤维的吸水率≥350mg/g.纤维;对SO2的穿透吸附容量可达200mg/g.纤维。FFC-1离子交换纤维具有良好的重复使用与再生能力,经20次再生循环使用后,纤维交换容量未见明显变化。 相似文献
20.
A new method based on hollow fiber-protected liquid-phase microextraction (LPME) was developed for the simultaneous determination
of atrazine, desethyl atrazine and desisopropyl atrazine in environmental water samples. In LPME, analytes were extracted
into 1-octanol immobilized in the micropores of a poly(vinylidene fluoride) porous hollow fiber membrane, and back extracted
into the acceptor (4 M HCl) filled in the lumen of the hollow fiber. After LPME, the analytes trapped in the acceptor were
analyzed with high-performance liquid chromatography after neutralization. The effect of extraction factors such as sample
pH, acceptor pH, salinity, extraction time, stirring rate, and humic acid were studied. Under the optimized conditions, the
limits of detection and relative standard deviations were respectively in the range of 0.5–1.0 μg L−1 and 3.9–4.7% (n = 5). The proposed method was applied to determine atrazine, desethyl atrazine and desisopropyl atrazine in wastewater and
groundwater samples. The three analytes were below the limits of detection, but good relative spiked recoveries over 90.1
± 5.9% at 5 μg L−1 spiked level were obtained. 相似文献