首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   38005篇
  免费   6655篇
  国内免费   4809篇
化学   16064篇
晶体学   611篇
力学   1690篇
综合类   824篇
数学   2822篇
物理学   10191篇
无线电   17267篇
  2025年   226篇
  2024年   776篇
  2023年   983篇
  2022年   1346篇
  2021年   1413篇
  2020年   1423篇
  2019年   1412篇
  2018年   1241篇
  2017年   1341篇
  2016年   1373篇
  2015年   1852篇
  2014年   2156篇
  2013年   2727篇
  2012年   2959篇
  2011年   2907篇
  2010年   2735篇
  2009年   2727篇
  2008年   2918篇
  2007年   2712篇
  2006年   2551篇
  2005年   2205篇
  2004年   1679篇
  2003年   1193篇
  2002年   1158篇
  2001年   1080篇
  2000年   1037篇
  1999年   620篇
  1998年   318篇
  1997年   267篇
  1996年   250篇
  1995年   224篇
  1994年   204篇
  1993年   196篇
  1992年   156篇
  1991年   117篇
  1990年   129篇
  1989年   109篇
  1988年   122篇
  1987年   77篇
  1986年   76篇
  1985年   46篇
  1984年   43篇
  1983年   50篇
  1982年   33篇
  1981年   23篇
  1980年   26篇
  1979年   36篇
  1978年   27篇
  1971年   15篇
  1965年   20篇
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
61.
Cheng CY  Wu CM  Liao GB  Cheng WY 《Optics letters》2007,32(5):563-565
A cesium 6S(1/2) --> 8S(1/2) two-photon-transition (TPT)-stabilized 822.5 nm diode laser is reported for the first time to our knowledge. Allan deviation of 4.4 x 10(-13) (60 s) was achieved, and the possible systematic errors were evaluated as smaller than 2 kHz. We demonstrate that the cesium TPT-stabilized diode laser could be a reliable frequency reference at 822.5 nm wavelength.  相似文献   
62.
Nitric oxide (NO) is one of the most important intercellular signaling molecules, and plays important roles in various biological systems. In this work, a unique RuII complex, tris[(5-(4-methylamino-3-aminobenzylamino)-1,10-phenanthroline)] ruthenium(II) hexafluorophosphate [Ru(MAA-phen)3][PF6]2, has been designed and synthesized as a luminescent probe for the detection of NO in aqueous media. The complex itself is almost non-luminescent, but can specifically react with NO under the aerobic conditions to afford its highly luminescent triazole derivative in aqueous media, [Ru(MTA-phen)3]2+ (MTA-phen: methyl-trazolebenzylamino-1,10-phenanthroline), accompanied by a 302-fold increase in luminescence intensity at 598 nm with a 130 nm Stokes shift. The luminescence response of [Ru(MAA-phen)3]2+ to NO is rapid, highly specific without interferences of other reactive oxygen/nitrogen species, and highly stable against the pH changes in the range of pH 4.5–9.5. These features enable [Ru(MAA-phen)3]2+ to be used as a probe for the highly selective and sensitive luminescence detection of NO in weakly acidic, neutral, and weakly basic media.  相似文献   
63.
The effect of delay, nonlinearity and noise on oscillatory motion is of permanent interest for theoretical and experimental research. Here we explore a negative feedback loop between p53 and Mdm2 with a time delay, which is a key circuit in the response of cells to damage. This circuit shows noisy sustained oscillations in individual human cells following DNA damage, and damped oscillations at the cell population level. We demonstrate the effect of delay on the oscillation, and the correlation in time course. In a multi-species system, the events at different time points which span a time delay are coupled even when the delay is large compared with the other characteristic times of the system. We also clarify that the dynamics at the single-cell level appears to be coherent resonance, and the origin of the damped oscillation at the macroscopic level out of the sustained ones at the single-cell level can be ascribed to the dephasing process which is induced by the interplay between nonlinearity and noise. The findings are consistent with experimental observations and advance our understanding of the dynamics of the p53 network.  相似文献   
64.
65.
高温超导线圈在大电流下稳定性的数值仿真   总被引:2,自引:0,他引:2  
在电力应用中,超导磁体可能会因为线圈工作于过流状态而失超,也可能会因为交流损耗而导致失超.为此,我们模拟了一个磁体在大电流过载下的稳定性情况.我们使用了一个建立在热传导方程和麦克斯韦方程基础上的差分数值计算方法来得出磁体内部的温度分布.我们对各种不同的电流冲击情况进行了考察,我们的模型可以使磁体设计者在实际制作之前能够估计一个比较安全的操作电流水平,有着广泛的实用价值.  相似文献   
66.
A novel phosphor, Mn4+ doped La2LiTaO6, was developed by solid-state reaction method. The luminescent spectra and emission efficiencies of La2LiTaO6:Mn x 4+ (x = 0.001, 0.003, 0.005 and 0.01) were discussed. The effects of co-doped charge compensation ions, M = Mg2+, Ca2+, Na+, were investigated, respectively. The excitation spectra indicated that La2LiTaO6:Mn4+ could be effectively excited by both NUV light and blue light. The emission spectra of the phosphor exhibit a broadband ranging from 670 to 720 nm with the maximum at about 709 nm in deep red region. The co-doping of Mg2+ could significantly improve the luminescent properties of La2LiTaO6:Mn4+. Thus, phosphor La2LiTaO6:Mn4+, Mg2+ can serve as a key component to improve color rendering of blue-chip white-LEDs.  相似文献   
67.
Luminescent probes/chemosensors based on lanthanide complexes have shown great potentials in various bioassays due to their unique long-lived luminescence property for eliminating short-lived autofluorescence with time-resolved detection mode. In this work, we designed and synthesized a new dual-chelating ligand {4′-[N,N-bis(2-picolyl)amino]methylene-2,2′:6′,2′-terpyridine-6,6′-diyl} bis(methylenenitrilo) tetrakis(acetic acid) (BPTTA), and investigated the performance of its Tb3+ complex (BPTTA-Tb3+) for the time-resolved luminescence sensing of Zn2+ ions in aqueous media. Weakly luminescent BPTTA-Tb3+ can rapidly react with Zn2+ ions to display remarkable luminescence enhancement with high sensitivity and selectivity, and such luminescence response can be realized repeatedly. Laudably, the dose-dependent luminescence enhancement shows a good linear response to the concentration of Zn2+ ions with a detection limit of 4.1 nM. To examine the utility of the new probe for detecting intracellular Zn2+ ions, the performance of BPTTA-Tb3+ in the time-resolved luminescence imaging of Zn2+ ions in living HeLa cells was investigated. The results demonstrated the applicability of BPTTA-Tb3+ as a probe for the time-resolved luminescence sensing of intracellular Zn2+ ions.  相似文献   
68.
We explore the phases of supersymmetric U(N) gauge theories with fundamental matter that arise as deformations of SQCD by the addition of a superpotential for the adjoint chiral multiplet. As the parameters in the superpotential are varied, the vacua of this theory sweep out various branches, which in some cases have multiple semiclassical limits. In such limits, we recover the vacua of various product gauge group theories, with flavors charged under some group factors. We describe in detail the structure of the vacua in both classical and quantum regimes, and develop general techniques such as an addition and a multiplication map which relate vacua of different gauge theories. We also consider possible indices characterizing different branches and potential relationships with matrix models.  相似文献   
69.
Three-dimensional (3D) architecture of TiO2 hollow sphere has many excellent and interesting performances that attract significant attention nowadays. In this paper, a simple surface erosion approach to the fabrication of TiO2 hollow spheres via the hydrothermal process has been developed. The morphologies and the phase were characterized by scanning electron microscopy (SEM) and X-ray diffractometer (XRD). The results indicate that the anatase-type TiO2 hollow spheres with a diameter of ∼1 μm are successfully synthesized. The shell thickness of TiO2 hollow spheres is ∼150 nm and the size of hollow cavity is ∼600 nm. By the control experiments, the influence of ammonium fluoride and hydrogen peroxide on the hollow spherical structures was studied. Hydrogen peroxide acts as both the oxidant and the bubble generator, ammonium fluoride is crucial for the erosion and dissolution of titanium, the detailed dissolution-crystallization mechanism for the formation of TiO2 hollow spheres was also proposed.  相似文献   
70.
在对人本主义学习理论做简要阐述的基础上,结合物理学的学科性质,就人本主义学习观如何应用到物理教学上做了些尝试.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号