Organic Light‐Emitting Diode Sensing Platform: Challenges and Solutions

The organic light‐emitting diode (OLED)‐based sensing platform is gaining momentum due to unique attributes of the compact OLEDs that are used as excitation sources. This paper, however, points to issues related to this sensing platform that will affect many (bio)chemical sensing applications, in particular in photoluminescence (PL)‐based sensors operated in the advantageous time domain, where pulsed OLEDs are utilized. The issues are related to the post‐pulse electroluminescence (EL) profile, i.e., transient EL, which depends on the OLED materials and structure, and to the long‐wavelength tail of the typically broad‐band EL spectrum. Depending on materials and device structure, the transient EL may exhibit spikes peaking at ～100–200 ns and μs‐long tails. As shown, these interfere with the determination of PL decay times (that are related to analyte concentrations) of sensing elements. The results also indicate that the long‐wavelength tail of the EL spectrum contributes to the interfering post‐pulse μs‐long EL tail. Hence, it is shown that the choice of OLED materials, the use of microcavity (μC) OLEDs with tunable, narrower EL bands, and the use of UV OLEDs alleviate these issues, resulting in more reliable data analysis. Furthermore, a 2‐D uniform 2 μm‐pitch microlens array that was previously used for improving light extraction from the OLEDs (J.‐M. Park et al., Optics Express 2011 , 19, A786) is used for directional PL scattering toward the photodetector, which leads to a ～2.1–3.8 fold enhancement of the PL signal. This behavior is shown for oxygen sensing, which is the basis for sensing of bioanalytes such as glucose, lactate, ethanol, cholesterol, and uric acid.     

光学活体成像技术进展

光学活体成像技术是近年来生物医学检测中发展最快的前沿科学之一,能够在微创或无创的条件下对活体组织或动物体内的生理生物活动进行成像跟踪,其中某些技术可以达到动态实时监测.总结了目前常用和最新的光学活体成像技术,并对其在生物医学领域的应用做了介绍与展望.     

Composite coating of 58S bioglass and hydroxyapatite on a poly (ethylene terepthalate) artificial ligament graft for the graft osseointegration in a bone tunnel

The purpose of this study was to determine the effect of the combination of hydroxyapatite (HA) and bioglass (BG) on polyethylene terephthalate (PET) artificial ligament graft osseointegration within the bone tunnel. The results of in vitro culturing of MC3T3-E1 mouse osteoblastic cells proved that this HA/BG composite coating can promote the cell compatibility of grafts. A rabbit extraarticular tendon-to-bone healing model was used to evaluate the effect of this composite coating on PET artificial ligaments in vivo. The final results demonstrated that HA/BG coating improved new bone formation at the graft-bone interface and increased the load-to-failure property of graft in bone tunnel compared to the control group at early time. The study has shown that HA/BG composite coating on the PET artificial ligament surface has a positive effect in the induction of artificial ligament osseointegration within the bone tunnel.     

A Selective RhI‐Catalyzed Substrate‐Controlled C−C Bond Activation of Benzyl Sulfonamide/Alcohol‐Tethered Alkylidenecyclopropanes

Benzyl sulfonamide/alcohol‐tethered alkylidenecyclopropanes undergo a rhodium‐catalyzed and substrate‐controlled selective C?C bond activation, producing three types of common organic structural units: benzo[c]azepine/oxepines, dihydronaphthalen‐1‐amines, and conjugated dienes. Epoxidation and aromatization of these products to construct two useful compounds have also been achieved.     

Modeling and analysis of multiple access channel capacity based on hybrid energy storage and energy harvesting

Energy harvesting (EH) has been considered as a promising technology to solve the constrained energy problem in the devices of IoT with its advantages of flexible deployment and sustainable energy supply.For multiple access channel with energy harvesting,a hybrid energy storage structure model composed by super capacitor and battery was proposed for the devices of IoT.According to the peculiarities of medium access channel and energy harvesting system,an optimized energy allocation strategy with exponential-type decline (ETD) was presented,the upper and lower bounds of the average throughput were deduced,in particular,the gap of two bounds was derived to be a constant.The channel capacity was further obtained by utilizing the relationship between the average throughput and the channel capacity.In the simulations,the effect of harvested energy,storage capacity and the number of nodes on the channel capacity were analyzed respectively.Experiment results show that compared with the conventional wireless node with single battery storage,the proposed hybrid energy storage structure can improve the harvested energy value and increase the multiple access channel capacity by using adaptive modulation scheme when transmitting the signals.     

Electromagnetic field of a horizontal electric dipole buried in a medium covering one-dimensionally anisotropic medium

The electromagnetic fields of a horizontal electric dipole buried in a medium covering one-dimensionally anisotropic medium are studied. There are three media, one-dimensionally anisotropic medium covered with a dielectric under the air. The electromagnetic field components are complex because of the multiple reflections from the up and down boundaries. The electromagnetic field components between air and one-dimensionally anisotropic medium are given, the trapped surface waves and lateral waves along the dielectric-anisotropic medium boundary are computed. The results have some practical applications in the communication in sea or lake above one-dimensionally anisotropic earth or sediments.     

Application of EDXRF Method in Measurement of Fe Content in Aqueous Fe Sample

介绍了能量色散X荧光分析方法在含水Fe样品测量中的应用.用ANTG -2000型海底X荧光探测系统对含Fe为10％～60％的Fe样进行测量,建立水分对Fe元素特征K α射线影响的校正模型.结果表明,通过该模型校正,对含饱和水情况下Fe样品的分析相对误差小于4％,具有良好的分析效果.