全文获取类型
收费全文 | 12706篇 |
免费 | 2081篇 |
国内免费 | 1725篇 |
专业分类
化学 | 7387篇 |
晶体学 | 123篇 |
力学 | 508篇 |
综合类 | 109篇 |
数学 | 1039篇 |
物理学 | 3296篇 |
无线电 | 4050篇 |
出版年
2024年 | 57篇 |
2023年 | 312篇 |
2022年 | 471篇 |
2021年 | 530篇 |
2020年 | 545篇 |
2019年 | 590篇 |
2018年 | 465篇 |
2017年 | 424篇 |
2016年 | 615篇 |
2015年 | 681篇 |
2014年 | 783篇 |
2013年 | 980篇 |
2012年 | 1089篇 |
2011年 | 991篇 |
2010年 | 725篇 |
2009年 | 769篇 |
2008年 | 839篇 |
2007年 | 681篇 |
2006年 | 651篇 |
2005年 | 574篇 |
2004年 | 460篇 |
2003年 | 461篇 |
2002年 | 547篇 |
2001年 | 455篇 |
2000年 | 305篇 |
1999年 | 235篇 |
1998年 | 193篇 |
1997年 | 128篇 |
1996年 | 143篇 |
1995年 | 105篇 |
1994年 | 94篇 |
1993年 | 77篇 |
1992年 | 105篇 |
1991年 | 74篇 |
1990年 | 62篇 |
1989年 | 39篇 |
1988年 | 28篇 |
1987年 | 36篇 |
1986年 | 36篇 |
1985年 | 24篇 |
1984年 | 16篇 |
1983年 | 23篇 |
1982年 | 13篇 |
1981年 | 11篇 |
1980年 | 8篇 |
1978年 | 9篇 |
1975年 | 5篇 |
1974年 | 5篇 |
1973年 | 6篇 |
1968年 | 6篇 |
排序方式: 共有10000条查询结果,搜索用时 18 毫秒
171.
Microporous activated carbons prepared from palm shell by thermal activation and their application to sulfur dioxide adsorption 总被引:2,自引:0,他引:2
Textural characterization of activated carbons prepared from palm shell by thermal activation with carbon dioxide (CO(2)) gas is reported in this paper. Palm shell (endocarp) is an abundant agricultural solid waste from palm-oil processing mills in many tropical countries such as Malaysia, Indonesia, and Thailand. The effects of activation temperature on the textural properties of the palm-shell activated carbons, namely specific surface area (BET method), porosity, and microporosity, were investigated. The activated carbons prepared from palm shell possessed well-developed porosity, predominantly microporosity, leading to potential applications in gas-phase adsorption for air pollution control. Static and dynamic adsorption tests for sulfur dioxide (SO(2)), a common gaseous pollutant, were carried out in a thermogravimetric analyzer and a packed column configuration respectively. The effects of adsorption temperature, adsorbate inlet concentration, and adsorbate superficial velocity on the adsorptive performance of the prepared activated carbons were studied. The palm-shell activated carbon was found to have substantial capability for the adsorption of SO(2), comparable to those of some commercial products and an adsorbent derived from another biomass. 相似文献
172.
173.
Adam Bange Jian Tu Xiaoshan Zhu Chong Ahn H. Brian Halsall William R. Heineman 《Electroanalysis》2007,19(21):2202-2207
A microbead based sandwich immunoassay for MS2 bacteriophage was developed using an interdigitated array (IDA) electrode with nanoscale dimensions (220 nm electrode width, 620 nm gap). The IDA was fabricated using an electron beam lithographic lift‐off technique. After an antibody‐assisted capture of MS2 using paramagnetic microbeads, a β‐galactosidase labeled secondary antibody was used to convert p‐aminophenyl‐β‐D ‐galactopyranoside (PAPG) into the redox active p‐aminophenol (PAP). Amperometric detection of PAP with IDA electrodes at +300 and ?200 mV vs. a Ag/AgCl reference electrode was used to measure the result, detecting MS2 concentrations as low as 10 ng/mL. 相似文献
174.
Peng Chen Xiaojun Luo Guanqi Dai Yuchuan Jiang Yue Luo Shuang Peng Hao Wang Penghui Xie Chen Qu Wenyu Lin Jian Hong Xue Ning Aimin Li 《Experimental & molecular medicine》2020,52(7):1062
Dexmedetomidine (DEX) is an anesthetic that is widely used in the clinic, and it has been reported to exhibit paradoxical effects in the progression of multiple solid tumors. In this study, we sought to explore the mechanism by which DEX regulates hepatocellular carcinoma (HCC) progression underlying liver fibrosis. We determined the effects of DEX on tumor progression in an orthotopic HCC mouse model of fibrotic liver. A coculture system and a subcutaneous xenograft model involving coimplantation of mouse hepatoma cells (H22) and primary activated hepatic stellate cells (aHSCs) were used to study the effects of DEX on HCC progression. We found that in the preclinical mouse model of liver fibrosis, DEX treatment significantly shortened median survival time and promoted tumor growth, intrahepatic metastasis and pulmonary metastasis. The DEX receptor (ADRA2A) was mainly expressed in aHSCs but was barely detected in HCC cells. DEX dramatically reinforced HCC malignant behaviors in the presence of aHSCs in both the coculture system and the coimplantation mouse model, but DEX alone exerted no significant effects on the malignancy of HCC. Mechanistically, DEX induced IL-6 secretion from aHSCs and promoted HCC progression via STAT3 activation. Our findings provide evidence that the clinical application of DEX may cause undesirable side effects in HCC patients with liver fibrosis.Subject terms: Cancer microenvironment, Cell growth 相似文献
175.
疏水缔合型增稠剂聚(丙烯酰胺-丙烯酸高级酯)的合成及增稠性能研究 总被引:5,自引:0,他引:5
采用沉淀聚合法合成了聚(丙烯酰胺-丙烯酸十四酯),聚(丙烯酰胺-丙烯酸十六酯)和聚(丙烯酰胺-丙烯酸十八酯),重点讨论了共聚物中疏水基团数量及疏水基团链长对增稠性能的影响。采用凯达尔定氮法和动态热分析(DMTA)测定了共聚物的组成及玻璃化温度。 相似文献
176.
Cheung E Chong KC Jayaraman S Ramamurthy V Scheffer JR Trotter J 《Organic letters》2000,2(18):2801-2804
[reaction: see text] Four methods of asymmetric induction in the cis, trans-photoisomerization of 2beta, 3beta-diphenylcyclopropane-1alpha-carboxylic acid derivatives were studied. Best results (ca. 80% de) were obtained by irradiation of chiral esters, amides, and salts in NaY and LiY zeolites and in the pure crystalline state. 相似文献
177.
trans-RhCl(CO)(TPPTS)2 (TPPTS=tris(m-sulfonatophenyl)phosphine) has been intercalated into Zn-Al layered double hydroxides (LDHs) by the method of ion exchange. The structure, composition and thermal stability of the composite material have been characterized by powder X-ray diffraction, Fourier transform infrared and 31P solid-state magic-angle spinning nuclear magnetic resonance spectroscopy, elemental analysis, thermogravimetry, and differential thermal analysis. The geometry of trans-RhCl(CO)(TPPTS)2 was fully optimized using the PM3 semiempirical molecular orbital method, and a schematic model for the intercalated species has been proposed. The thermal stability of trans-RhCl(CO)(TPPTS)2 is significantly enhanced by intercalation, which suggests that such materials may have prospective application as the basis of a supported catalyst system for the hydroformylation of higher olefins. 相似文献
178.
179.
Ti接枝MCM-41催化剂的结构设计及化学亲和选择性研究 总被引:3,自引:0,他引:3
用二氯化钛茂作为活性物种的来源,利用Si-MCM-41催化剂表面羟基的反应性,得到了Ti接枝MCM-41催化剂的两种结构模型.结构表征结果表明,Ti接枝MCM-41催化剂不仅长程结构好,孔径分布均一,而且催化剂表面活性中心含量高.两种结构模型催化剂上芳烃羟化反应性能表明,Ti接枝MCM-41催化剂表面的亲水/憎水性可以在较宽的范围内调变,从而可实现控制芳烃羟化的化学亲和选择性.另外,研究结果还表明,Ti接枝MCM-41催化剂具有很好的活性稳定性. 相似文献
180.