石墨-六角氮化硼微晶混合物与水高压反应产物分析

 利用球磨法制备石墨-六角氮化硼微晶混合物，并在6.1 GPa、800~1 500 ℃条件下与水进行高压反应，以便研究用水作触媒合成B-C-N三元化合物的可能性。通过对反应产物的XRD、XPS谱分析发现：高压下随着温度的升高，反应产物中出现再结晶石墨，其晶化程度逐渐提高；但没有出现再结晶六角氮化硼，也未出现立方氮化硼。在球磨不充分条件下，石墨-六角氮化硼混合物的XRD谱没有完全弥散，它们与水高压反应时，能观察到石墨与立方氮化硼分别结晶的现象，但都没有形成B-C-N晶化结构。     

Density functional theory study on antiferromagnetic interactions in a silver (I) complex of nitronyl nitroxide

A one-dimensional (1D) silver (I) complex of nitronyl nitroxide with fairly strong antiferromagnetic interaction, in which the metal ions are diamagnetic, is investigated by means of the ab initio crystal orbital method based on the density functional theory. The calculated values of the magnetic coupling constant (J) are close to the experimental measured J value in the periodic system. The magneto-structural correlation reveals that the existence of an antiferromagnetic coupling pathway along nitronyl nitroxide units via silver (I) ion in this system. The spin population distribution also shows the existence of spin delocalization along the ONCNO–Ag–ONCNO, which affords a rational interpretation for the antiferromagnetic interaction mechanism.     

串列加速器头部电极改进方案

通过改变头部电极的局部形状来改善头部电场, 运用Poisson程序计算几种可能形状下表面电场的分布, 并以此给出最佳的改进方案.     

Extension of Isometries Between the Unit Spheres of Normed Space E and C（Ω）

In this paper, we study the extension of isometries between the unit spheres of normed space E and C（Ω）. We obtain that any surjective isometry between the unit spheres of normed space E and C（Ω） can be extended to be a linear isometry on the whole space E and give an affirmative answer to the corresponding Tingley＇s problem （where Ω be a compact metric space）.     

On a micro‐macro model for polymeric fluids near equilibrium

In this paper, we study a micro‐macro model for polymeric fluid. The system involves coupling between the macroscopic momentum equation and a microscopic evolution equation describing the combined effects of the microscopic potential and thermofluctuation. We employ an energetic variation procedure to explore the relation between the macroscopic transport of the particles and the induced elastic stress due to the microscopic structure. For the initial data not far from the equilibrium, we prove the global existence and uniqueness of classical solutions to the system. © 2006 Wiley Periodicals, Inc.     

Determination of gold in ore by flame atomic absorption spectrometry with flow-injection on-line sorbent extraction preconcentration

Gold in ores was determined by flame atomic absorption spectrometry following on-line preconcentration by sorbent extraction in a flow-injection system. The medium polarity adsorption resin Amberlite XAD-8 packed in a 220-μl micro-column was used to collect gold(III) from hydrochloric acid sample solutions for 40 s at 7.6 ml/min. Ethanol was used to elute the adsorbed analytes into the nebulizer. Optimization studies were made on sample loading rate, elution rate and sample acidity. Some possible interferences on the determination are discussed. A 35-fold enrichment was achieved at a sampling frequency of 60 h^?1 and with an RSD of 1.4%. The detection limit (3σ) and 2 μg l^?1. Results for gold in ore samples showed good agreement with those obtained using activated carbon adsorption preconcentration. The recoveries were 97–108%.     

电控发动机喷油脉宽的分析

本文介绍了利用喷油脉宽大小的变化来分析电控发动机电控系统、燃油供给等系统故障的一种方法,在汽车故障检测与诊断中有着广泛的应用。     

Features of the total disintegration events of heavyemulsion targets caused by 4.5A GeV/c16O

Total disintegration events produced by 4.5\,A GeV/c $^{16}$O--AgBr interactions are analysed to investigate the characteristics of secondary charged particles produced in such collisions. The multiplicity distributions of grey, black, and relativistic charged particles can be well represented by Gaussian distribution. The average multiplicity of grey particles is found to increase with the mass of projectile increasing, while that of black particles is found to decrease with the mass of projectile increasing. This result is in good agreement with the prediction of fireball model. Finally, the linear dependence between grey and black particles is observed, but there is no distinct dependence between the production of relativistic charged particles and the target excitation.     

含有五边形—七边形缺陷的单壁纳米碳管的输运性质研究

运用第一性原理的密度泛函理论结合非平衡格林函数研究了含有五边形—七边形拓扑缺陷的纳米碳管异质结的输运性质.结果发现：拓扑缺陷对碳管的输运性质有很大影响；另外，不同类型的碳管形成的异质结的输运性质也有明显的差异. 关键词： 纳米碳管 输运性质 异质结 透射系数     

火工品可靠性试验数据的综合分析方法

升降法试验数据和固定刺激量下的成败型试验数据,是两种最常见的火工品可靠性试验数据．我们应用Markov链,研究了升降法试验数据下,感度分布参数的极大似然估计的特性．在此基础上,应用Bootstrap方法和Bayes方法,给出了综合分析两种试验数据的方法．最后,将该方法应用于520底火的可靠性鉴定,得出了有益的结论．