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951.
Xingying Zhang Chen Song Huijia Nong Kaige Xu Xiaozhuo Wu Wen Zhong Malcolm Xing Leyu Wang 《Advanced functional materials》2023,33(32):2300866
A conductive engineered cardiac patch (ECP) can reconstruct the biomimetic regenerative microenvironment of an infarcted myocardium. Direct ink writing (DIW) and 3D printing can produce an ECP with precisely controlled microarchitectures. However, developing a printed ECP with high conductivity and flexibility for gapless attachment to conform to epicardial geometry remains a challenge. Herein, an asymmetrical DIW hydrophobic/hydrophilic membrane using heat-processed graphene oxide (GO) ink is developed. The “Masked spin coating” method is also developed that leads to a microscale GO (hydrophilic)/reduced GO (rGO, hydrophobic) physiological sensor, as well as a macroscale moisture-driven GO/rGO actuator. Depositing mussel-inspired polydopamine (PDA) coating on the one side of the DIW rGO , the ultrathin (approximately 500 nm) PDA-rGO (hydrophilic)/rGO (hydrophobic) microlattice (DrGOM) ECP is bestowed with the flexibility and moisture-responsive actuation that allows gapless attachment to the curved surface of the epicardium. Conformable DrGOM exhibits a promising therapeutic effect on rats' infarcted hearts through conductive microenvironment reconstruction and improved neovascularization. 相似文献
952.
Zixin Chang Mengsu Zhu Yong Sun Feng He Yang Li Chunhui Ye Yigang Jin Ze Li Wei Xu 《Advanced functional materials》2023,33(32):2301513
Herein, a novel D4 symmetrical redox-active ligand tetrathia[8]circulene-2,3,5,6,8,9,11,12-octaol (8OH-TTC) is designed and synthesized, which coordinates with Ni2+ ions to construct a 2D conductive metal-organic framework (2D c-MOF) named Ni-TTC. Ni-TTC exhibits typical semiconducting properties with electrical conductivity up to ≈1.0 S m−1 at 298 K. Furthermore, magnetism measurements show the paramagnetic property of Ni-TTC with strong antiferromagnetic coupling due to the presence of semiquinone ligand radicals and Ni2+ sites. In virtue of its decent electrical conductivity and good redox activity, the gravimetric capacitance of Ni-TTC is up to 249 F g−1 at a discharge rate of 0.2 A g−1, which demonstrates the potential of tetrathia[8]circulene-based redox-active 2D c-MOFs in energy storage applications. 相似文献
953.
Yu Cheng Xinnan Xu Mengfan Wang Chengwei Deng Yi Sun Chenglin Yan Tao Qian 《Advanced functional materials》2023,33(44):2302332
As a promising energy carrier, ammonia synthesis by electrocatalytic nitrogen reduction reaction (eNRR) is a promising green and low-carbon ammonia synthesis strategy that can replace the traditional Haber–Bosch process. However, the development of eNRR processes is mainly severely constrained by competitive hydrogen evolution reaction (HER), and the corresponding strategies to inhibit this adverse side reaction to obtain high eNRR selectivity are still limited. In addition, for this complex reaction involving gas–liquid–solid three-phase interface and proton/electron transfer, it is great significance to analyze and summarize the existing inhibition HER strategies from the viewpoint of dynamics. In view of this, this work reviews proton supply/filtration regulation strategy in catalytic system, allowing a systematic survey of the literature focusing on interface membrane regulation (inorganic membrane and organic membrane), electrolyte regulation (metal-mediated strategy and electrolyte ion regulation strategy) and system device design (electrode structure design and electrolytic cell device design). Constructive catalytic system design guidance is also suggested to inhibit hydrogen evolution and improve NH3 selectivity, aiming for scalable and economically feasible applications. 相似文献
954.
In this paper, a dual-band and reflective polarization converter based on metasurface is proposed. Its unit cell is composed of two layers of metal plates separated by a dielectric substrate. The simulation results show that the proposed converter is able to convert x- or y-polarized incident waves into cross-polarized waves perfectly in frequency bands of 6.75—10.59 GHz and 17.78—19.61 GHz, and the polarization conversion ratio (PCR) is nearly 100%, which can also convert linearly polarized waves into circularly polarized waves at four frequencies. It can be widely used in applications of radar satellites, antenna design and telecommunication with the function of realizing polarization conversion in two bands and achieving high PCR simultaneously. 相似文献
955.
Lin Xu Taotao Meng Xueying Zheng Tangyuan Li Alexandra H. Brozena Yimin Mao Qian Zhang Bryson Callie Clifford Jiancun Rao Liangbing Hu 《Advanced functional materials》2023,33(27):2302098
Aqueous Zn ion batteries (ZIBs) are one of the most promising battery chemistries for grid-scale renewable energy storage. However, their application is limited by issues such as Zn dendrite formation and undesirable side reactions that can occur in the presence of excess free water molecules and ions. In this study, a nanocellulose-carboxymethylcellulose (CMC) hydrogel electrolyte is demonstrated that features stable cycling performance and high Zn2+ conductivity (26 mS cm−1), which is attributed to the material's strong mechanical strength (≈70 MPa) and water-bonding ability. With this electrolyte, the Zn-metal anode shows exceptional cycling stability at an ultra-high rate, with the ability to sustain a current density as high as 80 mA cm−2 for more than 3500 cycles and a cumulative capacity of 17.6 Ah cm−2 (40 mA cm−2). Additionally, side reactions, such as hydrogen evolution and surface passivation, are substantially reduced due to the strong water-bonding capacity of the CMC. Full Zn||MnO2 batteries fabricated with this electrolyte demonstrate excellent high-rate performance and long-term cycling stability (>500 cycles at 8C). These results suggest the cellulose-CMC electrolyte as a promising low-cost, easy-to-fabricate, and sustainable aqueous-based electrolyte for ZIBs with excellent electrochemical performance that can help pave the way toward grid-scale energy storage for renewable energy sources. 相似文献
956.
Bohan Chen Wenxuan Zhu Tian Wang Bin Peng Yiwei Xu Guohua Dong Yunting Guo Haixia Liu Houbing Huang Ming Liu 《Advanced functional materials》2023,33(36):2302683
Inorganic/organic dielectric composites are very attractive for high energy density electrostatic capacitors. Usually, linear dielectric and ferroelectric materials are chosen as inorganic fillers to improve energy storage performance. Antiferroelectric (AFE) materials, especially single-crystalline AFE oxides, have relatively high efficiency and higher density than linear dielectrics or ferroelectrics. However, adding single-crystalline AFE oxides into polymers to construct composite with improved energy storage performance remains elusive. In this study, high-quality freestanding single-crystalline PbZrO3 membranes are obtained by a water-soluble sacrificial layer method. They exhibit classic AFE behavior and then 2D–2D type PbZrO3/PVDF composites with the different film thicknesses of PbZrO3 (0.1-0.4 µm) is constructed. Their dielectric properties and polarization response improve significantly as compared to pure PVDF and are optimized in the PbZrO3(0.3 µm)/PVDF composite. Consequently, a record-high energy density of 43.3 J cm−3 is achieved at a large breakdown strength of 750 MV m−1. Phase-field simulation indicates that inserting PbZrO3 membranes effectively reduces the breakdown path. Single-crystalline AFE oxide membranes will be useful fillers for composite-based high-power capacitors. 相似文献
957.
Chunliu Xu Weibo Hua Qinghua Zhang Yuan Liu Rongbin Dang Ruijuan Xiao Jin Wang Zhao Chen Feixiang Ding Xiaodong Guo Chao Yang Liangrong Yang Junmei Zhao Yong-Sheng Hu 《Advanced functional materials》2023,33(33):2302810
Na superionic conductor of Na3MnTi(PO4)3 only containing high earth-abundance elements is regarded as one of the most promising cathodes for the applicable Na-ion batteries due to its desirable cycling stability and high safety. However, the voltage hysteresis caused by Mn2+ ions resided in Na+ vacancies has led to significant capacity loss associated with Mn reaction centers between 2.5–4.2 V. Herein, the sodium excess strategy based on charge compensation is applied to suppress the undesirable voltage hysteresis, thereby achieving sufficient utilization of the Mn2+/Mn3+ and Mn3+/Mn4+ redox couples. These findings indicate that the sodium excess Na3.5MnTi0.5Ti0.5(PO4)3 cathode with Ti4+ reduction has a lowest Mn2+ occupation on the Na+ vacancies in its initial composition, which can improve the kinetics properties, finally contributing to a suppressed voltage hysteresis. Based on these findings, it is further applied the sodium excess route on a Mn-richer phosphate cathode, which enables the suppressed voltage hysteresis and more reversible capacity. Consequently, this developed Na3.6Mn1.15Ti0.85(PO4)3 cathode achieved a high energy density over 380 Wh kg−1 (based on active substance mass of cathode) in full-cell configurations, which is not only superior to most of the phosphate cathodes, but also delivers more application potential than the typical oxides cathodes for Na-ion batteries. 相似文献
958.
Yinhua Bao Haojie Liu Zeang Zhao Xu Ma Xing-Yu Zhang Guanzhong Liu Wei-Li Song 《Advanced functional materials》2023,33(37):2301581
High performance flexible batteries are essential ingredients for flexible devices. However, general isolated flexible batteries face critical challenges in developing multifunctional embodied energy systems, owing to the lack of integrative design. Herein, inspired by scales in creatures, overlapping flexible lithium-ion batteries (FLIBs) consisting of energy storage scales and connections using LiNi0.5Co0.2Mn0.3O2 (NCM523) and graphite electrodes are presented. The scale-dermis structure ensures a high energy density of 374.4 Wh L−1 as well as a high capacity retention of 93.2% after 200 charge/discharge cycles and 40 000 bending times. A variable stiffness property is revealed that can be controlled by battery configurations and deformation modes. Furthermore, the overlapping FLIBs can be housed directly into the architecture of several flexible devices, such as robots and grippers, allowing to create multifunctionalities that go far beyond energy storage and include load-bearing and variable flexibility. This study broadens the versatility of FLIBs toward energy storage structure engineering of flexible devices. 相似文献
959.
Bowen Jin Yuanhui Liu Junya Cui Shimeng Zhang Yu Wu Annan Xu Ming Xu Mingfei Shao 《Advanced functional materials》2023,33(31):2301909
Regarding the complex properties of various cations, the design of aqueous batteries that can simultaneously store multi-ions with high capacity and satisfactory rate performance is a great challenge. Here an amorphization strategy to boost cation-ion storage capacities of anode materials is reported. In monovalent (H+, Li+, K+), divalent (Mg2+, Ca2+, Zn2+) and even trivalent (Al3+) aqueous electrolytes, the capacity of the resulting amorphous MoOx is more than quadruple than that of crystalline MoOx and exceeds those of other reported multiple-ion storage materials. Both experimental and theoretical calculations reveal the generation of ample active sites and isotropic ions in the amorphous phase, which accelerates cation migration within the electrode bulk. Amorphous MoOx can be coupled with multi-ion storage cathodes to realize electrochemical energy storage devices with different carriers, promising high energy and power densities. The power density exceeded 15000 W kg−1, demonstrating the great potential of amorphous MoOx in advanced aqueous batteries. 相似文献
960.
Zhao-Yang Yin Yang Chen Yang-Yang Zhang Yu Yuan Qian Yang Ya-Nan Zhong Xu Gao Jing Xiao Zhao-Kui Wang Jian-Long Xu Sui-Dong Wang 《Advanced functional materials》2023,33(33):2302199
Minimizing reverse bias dark current density (Jdark) while retaining high external quantum efficiency is crucial for promising applications of perovskite photodiodes, and it remains challenging to elucidate the ultimate origin of Jdark. It is demonstrated in this study that the surface defects induced by iodine vacancies are the main cause of Jdark in perovskite photodiodes. In a targeted way, the surface defects are thoroughly passivated through a simple treatment with butylamine hydroiodide to form ultrathin 2D perovskite on its 3D bulk. In the passivated perovskite photodiodes, Jdark as low as 3.78 × 10-10 A cm-2 at -0.1 V is achieved, and the photoresponse is also enhanced, especially at low light intensities. A combination of the two improvements realizes high specific detectivity up to 1.46 × 1012 Jones in the devices. It is clarified that the trap states induced by the surface defects can not only raise the generation-recombination current density associated with the Shockley–Read–Hall mechanisms in the dark (increasing Jdark), but also provide additional carrier recombination paths under light illumination (decreasing photocurrent). The critical role of surface defects on Jdark of perovskite photodiodes suggests that making trap-free perovskite thin films, for example, by fine preparation and/or surface engineering, is a top priority for high-performance perovskite photodiodes. 相似文献