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241.
242.
Two-dimensional van der Waals magnetic materials are intriguing for applications in the future spintronics devices, so it is crucial to explore strategy to control the magnetic properties. Here, we carried out first-principles calculations and Monte Carlo simulations to investigate the effect of biaxial strain and hydrostatic pressure on the magnetic properties of the bilayer CrI3. We found that the magnetic anisotropy, intralayer and interlayer exchange interactions, and Curie temperature can be tuned by biaxial strain and hydrostatic pressure. Large compressive biaxial strain may induce a ferromagneticto-antiferromagnetic transition of both CrI3 layers. The hydrostatic pressure could enhance the intralayer exchange interaction significantly and hence largely boost the Curie temperature. The effect of the biaxial strain and hydrostatic pressure revealed in the bilayer CrI3 may be generalized to other two-dimensional magnetic materials. 相似文献
243.
空间太阳电池槽式聚光热电联供系统特性分析 总被引:3,自引:1,他引:3
建立了空间太阳电池的热电联供系统在槽式聚光条件下的热电性能模型, 并与实验进行了对比.理论计算与实验结果吻合较好, 最大误差在5.1%以内, 证明了该数学模型的正确性.通过此数学模型, 从聚光镜面的光学效率与焦线宽度、导热胶的导热系数、金属平板光照面的吸收率等内部特性参数及风速、太阳直辐射等外部特性参数出发, 对所设计制造的空间太阳电池槽式聚光热电联供系统进行分析.较为全面而系统地分析了这些参数的改变对其系统的热电效率、总效率及火用效率等性能指标的影响, 其中聚光镜面的光学效率影响最大, 光学效率从0.5增加至0.95, 系统的总效率和火用效率分别增加0.9倍和0.5倍, 其余参数对性能也有较强影响.研究结果为新一轮系统装置的制作提供了优化设计基础. 相似文献
244.
Hui Ma Lulu Xiao Dongchen Xu Yingrui Geng Xuesong Liu Yong Chen Yongjiang Wu 《Molecules (Basel, Switzerland)》2022,27(9)
Quality control methods of current traditional Chinese medicine (TCM) preparation is time-consuming and difficult to assess in terms of overall efficiency of the drug. A non-destructive rapid near-infrared spectroscopy detection system for key chemical components and biological activity of Lanqin oral solution (LOS), one of the best-selling TCM formulations, was established for comprehensive quality evaluation. Near infrared spectral scanning was carried out on 101 batches of commercial LOS under the penetrated vial state and traditional state. RAW 264.7 cells were cultured to detect the anti-inflammatory ability of LOS, and the reference concentrations of epigoitrin, geniposide, and baicalin were obtained by HPLC. The quantitative models were optimized by three kinds of variable selection methods. The correlation coefficients of prediction value of the models were greater than 0.94. The system also passed the external validation. The performance of the non-invasive models was similar to the traditional models. The established non-destructive system can be applied to the rapid quality inspection of LOS to avoid unqualified drugs from entering the market and ensure drug effectiveness. The biological activity index of LOS was introduced and predicted by NIRs for the first time, which provides a new idea about the quality control of TCM formulations. 相似文献
245.
Suxia Li Kang Lin Huaiyu Pang Yixin Wu Jianhe Xu 《Applied biochemistry and biotechnology》2013,169(2):612-623
An organic solvent-tolerant lipase from Serratia marcescens ECU1010 (rSML) was overproduced in Escherichia coli in an insoluble form. High concentrations of both biomass (50 g cell wet weight/L culture broth) and inclusion bodies (10.5 g/L) were obtained by applying a high-cell-density cultivation procedure. Activity assays indicated that the enzymatic activity of rSML reached 600 U/L. After treatment with isopropyl ether for 12 h, the maximum lipase activity reached 6,000 U/L. Scanning electron microscopy and Fourier transform infrared microspectroscopy revealed the activation mechanism of rSML in the presence of organic solvents. rSML was stable in broad ranges of temperatures and pH values, as well as in a series of organic solvents. Besides, rSML showed the best enantioselectivity for the kinetic resolution of (±)-trans-3-(4-methoxyphenyl)glycidic acid methyl ester. These features render the S. marcescens ECU1010 lipase attractive for biotechnological applications in the field of organic synthesis and pharmaceutical industry. 相似文献
246.
Molecular Dynamics (MD) is employed to investigate nonthermal melting triggered by coherent phonon excitation in bismuth telluride, which has Peierls distortion in the lattice structure. Results showed that the structural distortion caused by coherent phonons appears as early as 80 fs, while it takes several picoseconds for the whole phonon-excited area to evolve into a liquid state. It was also found that the temperature in the phonon-excited area rises quickly within tens of femtoseconds, while the rest of the lattice remains at the initial temperature even after several picoseconds, which is separated from the high temperature region across a thin transition area. This phenomenon is analogous to the heat transfer across a solid–liquid interface, even though in our case there is no abrupt solid-liquid interface between the cold lattice and the quasiliquid. 相似文献
247.
248.
249.
Commercial CaO was modified simply with benzyl bromide. The modified CaO had good water resistance, and characterization by FTIR and TG revealed the modifier was chemically bonded to the CaO surface. Commercial CaO and CaO modified with benzyl bromide were investigated as catalysts for the Henry reaction between benzaldehyde and nitromethane. It was found that the catalytic activity of the modified CaO was greatly improved, with high conversion of benzaldehyde to the (E)-phenyl nitroolefin and 1-phenyl-2-nitroethanol, and with different selectivity from commercial CaO. The effect of modification and reaction conditions on yield, selectivity, and mechanism were studied thoroughly. 相似文献
250.
Yi-Bin Zhao Quan-Shui Fan Gui-Li Xu Zi-Liang Feng Xiao-Jiang Hao 《Journal of carbohydrate chemistry》2013,32(7):401-410
Three new carbohydrates were isolated from the acidic hydrolysis part of the ethyl acetate extract of Cynanchum otophyllum Schneid (Asclepiadaceae) and one new carbohydrate from the ethyl acetate extract of Cynanchum paniculatum Kitagawa. Their structures were determined as methyl 2,6-dideoxy-3-O-methyl-α-D-arabino-hexopyranosyl-(1 → 4)-2,6-deoxy-3-O-methyl-β-D-arabino-hexopyranosyl-(1 → 4)-2,6-dideoxy-3-O-methyl-α-D-arabino-hexopyranoside (1), ethyl 2,6-dideoxy-3-O-methyl-β-D-ribo-hexopyranosyl-(1 → 4)-2,6-dideoxy-3-O-methyl-α-l-lyxo-hexopyranoside (2), met hyl 2,6-dideoxy-3-O-methyl-α-l-ribo-hexopyranosyl-(1 → 4)-2,6-dideoxy-3-O-methyl-β-D-lyxo-hexopyranosyl-(1 → 4)-2,6-dideoxy-3-O-methyl-α-D-arabino-hexopyranoside (3), and 2,6-dideoxy-3-O-methyl-β-D-ribo-hexopyranosyl-(1 → 4)-2,6-dideoxy-3-O-methyl-α-d-arabino-hexopyranosyl-(1 → 4)-2,6-dideoxy-3-O-methyl-α -d-arabino-hexopyranose (4), respectively, by spectral methods. 相似文献