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61.
In this paper, the transformation processes of two types of bis(8-hydroxyquinoline)zinc: Znq2 dihydrate and anhydrous (Znq2)4 were investigated by X-ray diffraction (XRD), infrared spectra (IR), scanning electron microscope (SEM), differential scanning calorimetry (DSC) and thermogravimetry (TG). The effects of crystal structure on optical properties of bis(8-hydroxyquinoiline)zinc were analyzed. Znq2 dihydrate can be transformed into anhydrous (Znq2)4 during heating under vacuum. Reversal transformation occurs by the interaction between chloroform and (Znq2)4. But (Znq2)4 was partially transformed into Znq2 dihydrate by the interaction between ethanol and (Znq2)4. The different molecular structure results in different crystal stacking and electronic structure, thereby affect its optical properties. 相似文献
62.
The traditional chemical industry has become a largely mature industry with many commodity products based on established technologies. Therefore, new product and market opportunities will more likely come from speciality chemicals, and from new functionalities obtained from new processing technologies as well as new microstructure control methodologies. It is a well-known fact that in addition to its molecular structure, the microstructure of a material is key to determining its properties. Controlling structures at the micro- and nano-levels is therefore essential to new discoveries. For this article, we define nanotechnology as the controlled manipulation of nanomaterials with at least one dimension less than 100nm. Nanotechnology is emerging as one of the principal areas of investigation that is integrating chemistry and materials science, and in some cases integrating these with biology to create new and yet undiscovered properties that can be exploited to gain new market opportunities. In this article market opportunities for nanotechnology will be presented from an industrial perspective covering electronic, biomedical, performance materials, and consumer products. Manufacturing technology challenges will be identified, including operations ranging from particle formation, coating, dispersion, to characterization, modeling, and simulation. Finally, a nanotechnology innovation roadmap is proposed wherein the interplay between the development of nanoscale building blocks, product design, process design, and value chain integration is identified. A suggestion is made for an R&D model combining market pull and technology push as a way to quickly exploit the advantages in nanotechnology and translate these into customer benefits. 相似文献
63.
物理模型教学与创新能力的培养 总被引:1,自引:0,他引:1
现代教学以能力培养为重点.学生获得研究问题、探索问题的能力是十分重要的,物理模型的教学过程对培养学生研究问题、探索问题、发展创造思维、培养辩证唯物主义思想方法都极为有利,因此,必须重视物理模型教学. 相似文献
64.
A new family of photonucleases, naphthalimide-thiazoles was synthesized and evaluated. These compounds intercalated into DNA efficiently and damaged DNA photochemically at concentrations as low as 5 μM. Mechanistic experiment suggests that a novel naphthalimide-thiazole radical produced via an excited triple state might be involved in the DNA photodamage. Different activity may arise from the impact of substituents at 2-phenyl ring of thiazole on the electron population of excited triple state according to AM1 semi-empirical calculation. 相似文献
65.
本文介绍了HSDPA的发展背景,针对HSDPA的主要技术特点,依据市场发展规划、用户需求等方面对HSDPA部署进行探讨,并对HSDPA的覆盖与容量方面进行规划分析. 相似文献
66.
This paper presents an investigation on a single-mode-multimode-single-mode fiber structure. A one-way guided-mode propagation analysis for the circular symmetry waveguide is employed to model the light propagation and the approximated formulations are derived and evaluated concerning the accuracy. Phase conjunction of the multimode interference within the fiber structure is revealed. A simple way to predict and analyze the spectral response of the structure is presented through the space to wavelength mapping with the derived approximated formulations. The prediction of spectral response is verified numerically and experimentally. 相似文献
67.
H.L. Xu A. Persson S. Svanberg 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2003,23(2):233-236
New radiative lifetime measurements based on time-resolved laser-induced fluorescence techniques are reported for 18 even-parity
levels belonging to the 4f5d26p and 4f
25d
2 configurations of Ce I and 6 even-parity levels belonging to the 5d26s, 4f5d6p, and 4f6s6p configurations of Ce II. Free neutral and singly ionized cerium atoms were produced by laser ablation. The Ce I and Ce II
levels range in energy from 26 545 to 29 102 cm-1, and 42 573 to 48 152 cm-1, respectively.
Received 25 September 2002 Published online 4 March 2003 相似文献
68.
一种小波域音频信息隐藏方法 总被引:1,自引:0,他引:1
提出了一种基于量化的小波域音频隐藏算法,将保密语音隐藏到载体音频中.为提高隐藏重和保密语音传输的安全性,对保密语音进行了小波域压缩编码和m序列的扩频调制,生成待隐藏的比特序列;通过量化方法,将编码和调制后的保密语音隐藏到载体音频的小波系数中;保密语音的恢复过程不需要使用原始音频、仿真结果表明,隐藏有保密语音的载体音频听觉质量没有明显下降,提取的保密语音感知质量较好;该算法对重量化、加噪、低通滤波等攻击均有良好的鲁棒性. 相似文献
69.
Zhiping Lin Xu L. Bose N.K. 《IEEE transactions on circuits and systems. I, Regular papers》2008,55(1):445-461
70.
Haitao Qian Edith Mathiowitz 《Journal of polymer science. Part A, Polymer chemistry》2007,45(24):5899-5915
We succeeded in developing the acyl chloride‐facilitated condensation polymerization method for the synthesis of new poly(anhydride‐ester)s with aromatic side groups, which cannot be polymerized by the classic melt condensation polymerization method. Using chlorinated and acylated carboxylic acids as the intermediates, the polymerization was carried out at low temperatures of 120 or 135 °C to yield pure poly(anhydride‐ester)s of molecular weights as high as 1.55 × 105 with minimal side‐reactions. A homogeneous route of preparation was developed and optimized, using butyric anhydride as the acylating reagent and oxalyl chloride as the chlorinating reagent. A comparison of the mechanisms of the classic method and the new method indicates that the effects of transacylation—cyclization and oligomer formation—were greatly reduced due to the high reactivity of carboxylic acid chloride and the steric effect of bulky acyl groups. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5899–5915, 2007 相似文献