首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   62586篇
  免费   9917篇
  国内免费   7693篇
化学   33655篇
晶体学   653篇
力学   2980篇
综合类   487篇
数学   5688篇
物理学   18738篇
无线电   17995篇
  2024年   259篇
  2023年   1330篇
  2022年   1718篇
  2021年   2105篇
  2020年   2204篇
  2019年   2127篇
  2018年   1838篇
  2017年   1808篇
  2016年   2540篇
  2015年   2843篇
  2014年   3417篇
  2013年   4246篇
  2012年   5085篇
  2011年   5274篇
  2010年   3989篇
  2009年   4080篇
  2008年   4342篇
  2007年   4063篇
  2006年   3933篇
  2005年   3077篇
  2004年   2439篇
  2003年   2166篇
  2002年   1994篇
  2001年   1693篇
  2000年   1536篇
  1999年   1390篇
  1998年   1229篇
  1997年   1049篇
  1996年   1046篇
  1995年   925篇
  1994年   804篇
  1993年   619篇
  1992年   625篇
  1991年   478篇
  1990年   392篇
  1989年   306篇
  1988年   263篇
  1987年   212篇
  1986年   195篇
  1985年   180篇
  1984年   118篇
  1983年   88篇
  1982年   70篇
  1981年   41篇
  1980年   19篇
  1979年   11篇
  1977年   7篇
  1970年   3篇
  1959年   3篇
  1957年   3篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
31.
32.
Unreliable mobility values, and particularly greatly overestimated values and severely distorted temperature dependences, have recently hampered the development of the organic transistor field. Given that organic field‐effect transistors (OFETs) have been routinely used to evaluate mobility, precise parameter extraction using the electrical properties of OFETs is thus of primary importance. This review examines the origins of the various mobilities that must be determined for OFET applications, the relevant extraction methods, and the data selection limitations, which help in avoiding conceptual errors during mobility extraction. For increased precision, the review also discusses device fabrication considerations, calibration of both the specific gate‐dielectric capacitance and the threshold voltage, the contact effects, and the bias and temperature dependences, which must actually be handled with great care but have mostly been overlooked to date. This review serves as a systematic overview of the OFET mobility extraction process to ensure high precision and will also aid in improving future research.  相似文献   
33.
Three‐dimensional (3D) nanometal films serving as current collectors have attracted much interest recently owing to their promising application in high‐performance supercapacitors. In the process of the electrochemical reaction, the 3D structure can provide a short diffusion path for fast ion transport, and the highly conductive nanometal may serve as a backbone for facile electron transfer. In this work, a novel polypyrrole (PPy) shell@3D‐Ni‐core composite is developed to enhance the electrochemical performance of conventional PPy. With the introduction of a Ni metal core, the as‐prepared material exhibits a high specific capacitance (726 F g?1 at a charge/discharge rate of 1 A g?1), good rate capability (a decay of 33 % in Csp with charge/discharge rates increasing from 1 to 20 A g?1), and high cycle stability (only a small decrease of 4.2 % in Csp after 1000 cycles at a scan rate of 100 mV s?1). Furthermore, an aqueous symmetric supercapacitor device is fabricated by using the as‐prepared composite as electrodes; the device demonstrates a high energy density (≈21.2 Wh kg?1) and superior long‐term cycle ability (only 4.4 % and 18.6 % loss in Csp after 2000 and 5000 cycles, respectively).  相似文献   
34.
35.
36.
The satisfiability (SAT) problem is a core problem in computer science. Existing studies have shown that most industrial SAT instances can be effectively solved by modern SAT solvers while random SAT instances cannot. It is believed that the structural characteristics of different SAT formula classes are the reasons behind this difference. In this paper, we study the structural properties of propositional formulas in conjunctive normal form (CNF) by the principle of structural entropy of formulas. First, we used structural entropy to measure the complex structure of a formula and found that the difficulty solving the formula is related to the structural entropy of the formula. The smaller the compressing information of a formula, the more difficult it is to solve the formula. Secondly, we proposed a λ-approximation strategy to approximate the structural entropy of large formulas. The experimental results showed that the proposed strategy can effectively approximate the structural entropy of the original formula and that the approximation ratio is more than 92%. Finally, we analyzed the structural properties of a formula in the solution process and found that a local search solver tends to select variables in different communities to perform the next round of searches during a search and that the structural entropy of a variable affects the probability of the variable being flipped. By using these conclusions, we also proposed an initial candidate solution generation strategy for a local search for SAT, and the experimental results showed that this strategy effectively improves the performance of the solvers CCAsat and Sparrow2011 when incorporated into these two solvers.  相似文献   
37.
Bromine-based flow batteries (Br-FBs) are considered one of the most promising energy storage systems due to their features of high energy density and low cost. However, they generally suffer from uncontrolled diffusion of corrosive bromine particularly at high temperatures. That is because the interaction between polybromide anions and the commonly used complexing agent (N–methyl–N–ethyl–pyrrolidinium bromide [MEP]) decreases with increasing temperatures, which causes serious self-discharge and capacity fade. Herein, a novel bromine complexing agent, 1–ethyl–2–methyl–pyridinium bromide (BCA), is introduced in Br-FBs to solve the above problems. It is proven that BCA can combine with polybromide anions very well even at a high temperature of 60 °C. Moreover, the BCA contributes to decreasing the electrochemical polarization of Br/Br2 couple, which in turn improves their power density. As a result, a zinc–bromine flow battery with BCA as the complexing agent can achieve a high energy efficiency of 84% at 40 mA cm−2, even at high temperature of 60 °C and it can stably run for more than 400 cycles without obvious performance decay. This paper provides an effective complexing agent to enable a wide temperature range Br-FB.  相似文献   
38.
Journal of Radioanalytical and Nuclear Chemistry - In the present work the final products of coumarin radiation chemical transformation are investigated by chromatography. During radiolysis of...  相似文献   
39.
Ding  Q.  Yao  M.  Wu  Sh.  Zeng  M.  Xue  N.  Wu  D.  Xu  J. 《Journal of Applied Spectroscopy》2022,89(4):712-718
Journal of Applied Spectroscopy - Based on partial least squares (PLS) analysis, the effects of different smoothing points and different preprocessing methods on the accuracy and precision of the...  相似文献   
40.
Xu  H. J.  Zhang  Q. G.  Debenest  G. 《Transport in Porous Media》2021,140(3):625-627
Transport in Porous Media - The theme of coupling problems for adsorption, absorption and thermochemical transport in porous media is very important for engineering applications. Based on the...  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号