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11.
Metabolic profiles of dioscin in rats revealed by ultra‐performance liquid chromatography quadrupole time‐of‐flight mass spectrometry 下载免费PDF全文
He Zhu Jin‐Di Xu Qian Mao Hong Shen Ming Kong Jian‐Ping Chen Song‐Lin Li 《Biomedical chromatography : BMC》2015,29(9):1415-1421
Dioscin (DIS), one of the most abundant bioactive steroidal saponins in Dioscorea sp., is used as a complementary medicine to treat coronary disease and angina pectoris in China. Although the pharmacological activities and pharmacokinetics of DIS have been well demonstrated, information regarding the final metabolic fates is very limited. This study investigated the in vivo metabolic profiles of DIS after oral administration by ultra‐performance liquid chromatography quadrupole time‐of‐flight mass spectrometry method. The structures of the metabolites were identified and tentatively characterized by means of comparing the molecular mass, retention time and fragmentation pattern of the analytes with those of the parent compound. A total of eight metabolites, including seven phase I and one phase II metabolites, were detected and tentatively identified for the first time. Oxidation, deglycosylation and glucuronidation were found to be the major metabolic processes of the compound in rats. In addition, a possible metabolic pathway on the biotransformation of DIS in vivo was proposed. This study provides valuable and new information on the metabolism of DIS, which will be helpful for further understanding its mechanism of action. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
12.
Kai He Tsegaye TadesseTsega Xi Liu Jiantao Zai Xin‐Hao Li Xuejiao Liu Wenhao Li Nazakat Ali Xuefeng Qian 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(34):12029-12035
The modulation of electron density is an effective option for efficient alternative electrocatalysts. Here, p‐n junctions are constructed in 3D free‐standing FeNi‐LDH/CoP/carbon cloth (CC) electrode (LDH=layered double hydroxide). The positively charged FeNi‐LDH in the space‐charge region can significantly boost oxygen evolution reaction. Therefore, the j at 1.485 V (vs. RHE) of FeNi‐LDH/CoP/CC achieves ca. 10‐fold and ca. 100‐fold increases compared to those of FeNi‐LDH/CC and CoP/CC, respectively. Density functional theory calculation reveals OH? has a stronger trend to adsorb on the surface of FeNi‐LDH side in the p‐n junction compared to individual FeNi‐LDH further verifying the synergistic effect in the p‐n junction. Additionally, it represents excellent activity toward water splitting. The utilization of heterojunctions would open up an entirely new possibility to purposefully regulate the electronic structure of active sites and promote their catalytic activities. 相似文献
13.
Uplink scheduling in wireless systems is gaining importance due to arising uplink intensive data services (ftp, image uploads
etc.), which could be hampered by the currently in-built asymmetry in favor of the downlink. In this work, we propose and
study algorithms for efficient uplink packet-data scheduling in a CDMA cell. The algorithms attempt to maximize system throughput
under transmit power limitations on the mobiles assuming instantaneous knowledge of user queues and channels. However no channel
statistics or traffic characterization is necessary. Apart from increasing throughput, the algorithms also improve fairness
of service among users, hence reducing chances of buffer overflows for poorly located users.
The major observation arising from our analysis is that it is advantageous on the uplink to schedule “strong” users one-at-a-time,
and “weak” users in larger groups. This contrasts with the downlink where one-at-a-time transmission for all users has shown
to be the preferred mode in much previous work. Based on the optimal schedules, we propose less complex and more practical
approximate methods, both of which offer significant performance improvement compared to one-at-a-time transmission, and the
widely acclaimed Proportional Fair (PF) algorithm, in simulations. When queue content cannot be fed back, we propose a simple modification of PF, Uplink PF (UPF), that offers similar improvement.
Hereafter, we refer to users with low recieved power at the base even when transmitting at peak transmit power as “weak” users,
and the strongly recieved users at the base as “strong” users.
Krishnan Kumaran is currently a member of the Complex Systems Modeling section in the Corporate Strategic Research of ExxonMobil Corp., Clinton,
NJ. Formerly, he was a Member of Technical Staff in the Mathematics of Networks and Systems Research Department at Bell Labs
in Murray Hill, NJ, where his research interests were in modeling, analysis and simulation of design, resource management
and scheduling issues in telecommunication networks.
Lijun Qian is an assistant professor in the Department of Electrical Engineering at Prairie View A&M University. He received his B.S.
from Tsinghua University in Beijing, M.S. from Technion-Israel Institute of Technology, and Ph.D. from WINLAB, Rutgers University,
all in electrical engineering. Before joining PVAMU, he was a researcher at Networks and Systems Research Department of Bell
Labs in Murray Hill, NJ. His major research interests are in wireless communications and networking technologies, especially
in radio resource management, protocol design, TCP/RLP optimization and MPLS traffic engineering. 相似文献
14.
15.
Layered Wyner-Ziv video coding. 总被引:2,自引:0,他引:2
Following recent theoretical works on successive Wyner-Ziv coding (WZC), we propose a practical layered Wyner-Ziv video coder using the DCT, nested scalar quantization, and irregular LDPC code based Slepian-Wolf coding (or lossless source coding with side information at the decoder). Our main novelty is to use the base layer of a standard scalable video coder (e.g., MPEG-4/H.26L FGS or H.263+) as the decoder side information and perform layered WZC for quality enhancement. Similar to FGS coding, there is no performance difference between layered and monolithic WZC when the enhancement bitstream is generated in our proposed coder. Using an H.26L coded version as the base layer, experiments indicate that WZC gives slightly worse performance than FGS coding when the channel (for both the base and enhancement layers) is noiseless. However, when the channel is noisy, extensive simulations of video transmission over wireless networks conforming to the CDMA2000 1X standard show that H.26L base layer coding plus Wyner-Ziv enhancement layer coding are more robust against channel errors than H.26L FGS coding. These results demonstrate that layered Wyner-Ziv video coding is a promising new technique for video streaming over wireless networks. 相似文献
16.
光通信技术发展的新亮点 总被引:1,自引:0,他引:1
自光通信问世以来,经历了研究探索、实用化、推广应用、快速发展等时期,直至2001年,达到急剧发展的高潮。随着世界经济的滑坡,通信行业的不景气,使光通信也进入了寒冷的冬天。实际上,即使在经济低速的时期,光通信的技术依然没有停止发展,而且出现了不少继续将光通信推向前进的新亮点。从技术和应用的角度,简要介绍一些光通信的新技术。 相似文献
17.
The theory of tree-growing (RECPAM approach) is developed for outcome variables which are distributed as the canonical exponential family. The general RECPAM approach (consisting of three steps: recursive partition, pruning and amalgamation), is reviewed. This is seen as constructing a partition with maximal information content about a parameter to be predicted, followed by simplification by the elimination of ‘negligible’ information. The measure of information is defined for an exponential family outcome as a deviance difference, and appropriate modifications of pruning and amalgamation rules are discussed. It is further shown how the proposed approach makes it possible to develop tree-growing for situations usually treated by generalized linear models (GLIM). In particular, Poisson and logistic regression can be tree-structured. Moreover, censored survival data can be treated, as in GLIM, by observing a formal equivalence of the likelihood under random censoring and an appropriate Poisson model. Three examples are given of application to Poisson, binary and censored survival data. 相似文献
18.
2Mbit/s高速信令链路在移动通信七号信令网中的应用 总被引:1,自引:0,他引:1
通过对2Mbit/s高速信令链路原理、特点的介绍,阐明了该技术在现阶段使用的实际意义,并给出了2Mbit/s高速信令链路在移动通信七号信令网中的应用。 相似文献
19.
许多实验对用CsI(Tl)闪烁晶体作为探测器来寻找和探测暗物质的可行性进行了研究.本工作利用8MeV单能中子轰击CsI(Tl)晶体探测器来研究Cs核和I核的QuenchingFactor.在数据处理中,运用脉冲形状甄别(PSD)方法来分辨反冲核信号和本底信号.实验结果表明,在7keV到132keV的能区中,Quench ingFactor随着反冲核能量的减少而增加.在探测暗物质的实验中,这一性质对于CsI(Tl)晶体探测器获得较低的能量阈值是很有利的. 相似文献
20.
本文介绍了近年来普通物理实验课程体系和教学内容改革的实践,并针对目前实验教学中仍存在的一些问题提出了开放式实验教学的改革思路。 相似文献