The Synthesis and Biological Activities of [5-(4-Substituted Phenylsulfinyl/Sulfonyl)-1,3-Dimethyl-1H-Pyrazol-4-Yl]-Arylmethanones

Abstract

A novel series of pyrazole derivatives containing substituted phenylsulfinyl/sulfonyl group have been synthesized via the oxidation of intermediate pyrazole sulfoether with H₂O₂ in acetic acid. The novel compounds were characterized by melting point, ¹H NMR, FT-IR, MS, and elemental analysis or HRMS. The biological activity results showed that most of the title compounds exhibit significant fungicidal activities against Alternaria solani Sorauer, Phytophthora capsici, and Corynespora cassiicola.

[Supplementary materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements for the following free supplemental files: Additional text and figures.]     

JMAWR: joint optimization of monitoring trail allocation and wavelength routing with limited monitoring resources

In all-optical networks, monitoring trail (m-trail) has long been proposed as an effective way for link failure localization. Previous works tried to minimize the number of used m-trails for localizing network-wide single link failures, and they all supposed that the monitoring resources were enough. However, failures are rare events and the traffic demand is increasing rapidly. The dedicated wavelengths for m-trails cannot be used to transmit data traffic, and some traffic demand may not be served during the peak period. Considering the operators prefer to serve customers’ demand as much as possible, if the resources allocated for m-trails are limited, more traffic will be carried. In this paper, we focus on the scenario where there are not enough resources for allocating m-trails. In this scenario, as only part of single link failures can be unambiguously localized, we aim to monitor the most valuable links, which carry more traffic demand, and minimize the maximum number of used wavelengths for traffic demand on the links which cannot be unambiguously localized. As we can also control the wavelength routing for traffic demand, we try to jointly optimize the m-trail allocation and wavelength routing. We first formulate this joint optimization problem as a mathematical model and present concrete analyses on this model. According to these analyses, a joint m-trail allocation and wavelength routing (JMAWR) heuristic algorithm is proposed based on graph-constrained group testing. Simulation results show that JMAWR outperforms the state-of-the-art m-trail allocation algorithm by up to 88.46% improvement in terms of maximum number of used wavelengths for traffic demand on links which cannot be unambiguously localized.     

Quantum HeisenbergS=1/2 spin glass with ferromagnetic coupling and random Dzyaloshinskii-Moriya interactions

By means of the generalized static replica symmetric spin glass theory, a quantum HeisenbergS=1/2 spin glass model with the infinite-ranged random Dzyaloshinskii-Moriya (DM) interaction and ferromagnetic coupling is investigated. The dependence of entropy, specific heat, susceptibility and the corresponding order parameters on temperature is studied numerically for different ferromagnetic interactions and fixed anisotropy. Two spin glass phases has been found including transverse and mixed spin glass phases. It has been shown that the local susceptibility exhibits double-cusp features for different ferromagnetic coupling (J ₀). Phase transition poins are found in the specific heat-temperature plane at various ferromagnetic coupling values. Additionally, the dependence of the spontaneous moment on temperature is calculated.     

Analysis of User＇s Weight in Microblog Network Based on User Influence and Active Degree

Based on user’s in-degree distribution, traditional ranking algorithms of user’s weight usually neglect the considerations of the differences among user’s followers and the features of user’s tweets. In order to analyze the factors which impact on user’s weight, under the analysis of the data collected from SINA Microblog network, this paper discovers that user influence and active degrees are the dominant factors for this issue. The proposed algorithm evaluates user influence by user’s follower number, the influence of user’s followers and the reciprocity between users. User’s active degree is modeled by user’s participation and the quality of user’s tweets. The models are tested by different data groups to confirm the parameters for the final calculation. Eventually, this paper compares the computational results with the user’s ranking order given by the SINA official application. The performance of this algorithm presents a stronger stability on the fluctuant range of the value of user’s weight.     

多功能教堂音视频系统设计与实现

依据智能建筑弱电工程的系统组成原理,结合某基督教堂的具体结构及业主对弱电工程的具体要求,对教堂的综合布线、视频音频的广播、录音录像、闭路电视监控等系统进行了设计与实施,结果表明,各个系统性能指标基本达到设计要求。     

一种基于面阵CCD的单波长辐射测温方法

介绍了一种基于面阵CCD的单波长辐射测量三维温度场的方法.通过引入一种新型的多路面阵CCD数据实时采集系统采集待测温度场多个方向投影数据,利用计算机层析技术重建温度场内部空间物理量的分布,然后根据维恩近似公式获得空间温度场的分布.对多路CCD数据实时采集系统的内部构造以及工作原理进行了较为详细的阐述.并对蜡烛的火焰温度场进行了测量,最后用热电偶验证此方法的正确性.利用此系统可以做到数据实时采集,为三维流场的实时测量奠定了良好的基础.     

手机车机互动的应用模式及关键技术分析

基于对车载信息服务现状的思考以及业界手机车机融合创新相关应用案例的分析,提出手机车机互动将是未来车载信息服务发展的重要方向,阐述了手机车机互动的主要应用模式及几种主流的技术方向,并对其技术特点进行了分析比较,为促进该应用模式及技术的推广提供参考。     

基于以太网技术的音视频信号切换器的设计

提出一种带以太网接口的智能音视频切换器。该系统以Mega64单片机为核心,实现了4×1的音频、视频信号监测和自动切换输出。通过以太网接口连接监控中心,实现远程参数配置和监控功能。同时,该系统在无上位机时,可独立工作,灵活性较好。     

含B闪锌矿三元系半导体BxIn1-xP和BxGa1-xP带隙理论预测

利用第一性原理计算方法,用广义梯度近似 (GGA) 处理电子之间的交换关联能,计算了BxIn1-xP,BxGa1-xP的带隙结构.BxIn1-xP的带隙弯曲参数b _Eg (Γ)=4.32eV,b_Eg(X) =1.8eV,它从直接带隙转变为间接带隙时B的含量为0.47;在小量B的掺入下,可使BxIn1-xP的带隙变小,在x=0.15时带隙达到最小值1.33eV.BxGa1-xP的带隙弯曲参数b_Eg(Γ)=1.37eV,b _Eg(X)=2.46eV,在整个组分内是间接带隙.BxIn1-x-P,BxGa1-xP有较大的带隙弯曲参数,是由于组成它们的二元系之间存在较大的晶格失配.     

子脉冲序列模式Er∶YAG激光消融牙本质的实验观察

研制了一台子脉冲序列模式Er∶YAG激光器,获得了每秒80个和100个子脉冲高能量激光输出,开展了不同脉冲宽度的子脉冲对离体牙本质的激光消融实验。实验中使用的是子脉冲序列模式激光器,其重复频率为20 Hz,脉冲包络能量为45 mJ,子脉冲宽度分别为20,30,40,50μs,在无冷却水雾条件下分别对比了子脉冲宽度对牙本质消融量、牙髓腔温升和坑洞组织形貌的影响。结果表明:在相同的激光脉冲能量下,较窄的子脉冲宽度不仅能够增加消融量,降低牙髓腔温升,从而延长操作时间,而且可以获得更好的消融坑洞组织形貌,牙小管的开放程度较高,有利于黏接修复治疗。