Near-field infrared response of graphene on copper substrate

The electronic properties of graphene are very sensitive to its dielectric environment. The coupling to a metal substrate can give rise to many novel quantum effects in graphene, such as band renormalization and plasmons with unusual properties, which are of high technological interest. Infrared nanoimaging are very suitable for exploring these effects considering their energy and length scales. Here, we report near-field infrared nanoimaging studies of graphene on copper synthesized by chemical vapor deposition. Remarkably, our measurements reveal three different types of near-field optical responses of graphene, which are very distinct from the near-field edge fringes observed in the substrate. These results can be understood from the modification of optical conductivity of graphene due to its coupling with the substrate. Our work provides a framework for identifying the near-field response of graphene in graphene/metal systems and paves the way for studying their novel physics and potential applications.     

一类状态依赖脉冲控制的害虫管理数学模型研究

研究一类状态依赖脉冲控制的害虫管理数学模型,当害虫的数量达到一定的临界值时,通过释放天敌和喷洒农药使得害虫的数量不超过经济危害水平.首先利用几何分析和后继函数方法得到了系统阶1周期解的存在性,进而运用类Poincare准则证明系统阶1周期解是轨道渐近稳定的.结论表明在一定的条件下,总能将害虫控制在经济危害水平以内,从而人们在农业生产过程中能够获得最大收益.证明系统存在阶1周期解的方法可推广到其它状态依赖脉冲反馈模型中.     

手性离子液体配体交换色谱拆分扁桃酸对映体的研究

本文基于配体交换的机理,研究了以脯氨酸手性离子液体作为手性配体拆分扁桃酸(MA)对映体的方法及热力学过程。详细考察了手性离子液体的烷基链长、铜离子的浓度、离子液体的浓度和pH等因素对MA对映体分离的影响。研究发现,不同烷基链长的手性离子液体中,以1-丁基-3-甲基咪唑L-脯氨酸为配体时,MA对映体的拆分效果最好;随着铜离子浓度的增加,MA对映体的保留时间和分离度先增大再减小;而随着1-丁基-3-甲基咪唑L-脯氨酸离子液体的浓度和流动相pH的增大,保留时间和分离度均增大。本文还测定了拆分过程中的一些热力学参数,结果表明,MA对映体的拆分过程是一个焓控的过程,L-MA较D-MA与固定相有更强的相互作用,保留时间更长。     

MHD控制超声速边界层的理论研究和数值分析

对MHD(mechanisms of magnetohy drodynamics)控制超声速平板湍流边界层的机理进行了理论研究和数值模拟. 理论上,采用等离子体低频近似碰撞频率模型,建立等离子体中电子和离子的力平衡方程,得到等离子体速度、极化电场以及边界层速度. 数值上,通过空间HLLE格式、LU--SGS时间推进求解时均磁流体动力学湍流方程,其中湍流模型采用sst--k\omega双方程模型. 研究结果表明:(1)边界层速度的理论结果和数值结果误差在7%范围内;(2)只有磁场而电场为零时,洛仑兹力起到减小摩阻的作用. 施加电场后,洛仑兹力能够加速边界层低速区流体;(3) 在边界层外层,越靠近壁面,作用参数越小;而在边界层近壁区黏性底层,虽然惯性力减小, 但黏性力却迅速增加,因此越靠近壁面,作用参数反而越大,加速低速流的代价增加.      

Multi-Scale Permutation Entropy: A Potential Measure for the Impact of Sleep Medication on Brain Dynamics of Patients with Insomnia

Insomnia is a common sleep disorder that is closely associated with the occurrence and deterioration of cardiovascular disease, depression and other diseases. The evaluation of pharmacological treatments for insomnia brings significant clinical implications. In this study, a total of 20 patients with mild insomnia and 75 healthy subjects as controls (HC) were included to explore alterations of electroencephalogram (EEG) complexity associated with insomnia and its pharmacological treatment by using multi-scale permutation entropy (MPE). All participants were recorded for two nights of polysomnography (PSG). The patients with mild insomnia received a placebo on the first night (Placebo) and temazepam on the second night (Temazepam), while the HCs had no sleep-related medication intake for either night. EEG recordings from each night were extracted and analyzed using MPE. The results showed that MPE decreased significantly from pre-lights-off to the period during sleep transition and then to the period after sleep onset, and also during the deepening of sleep stage in the HC group. Furthermore, results from the insomnia subjects showed that MPE values were significantly lower for the Temazepam night compared to MPE values for the Placebo night. Moreover, MPE values for the Temazepam night showed no correlation with age or gender. Our results indicated that EEG complexity, measured by MPE, may be utilized as an alternative approach to measure the impact of sleep medication on brain dynamics.     

Design,Synthesis, and In Vivo and In Silico Evaluation of Coumarin Derivatives with Potential Antidepressant Effects

In this study, a series of coumarin derivatives were designed and synthesized, their structures were characterized using nuclear magnetic resonance (NMR) and high-resolution mass spectrometry (HRMS) testing methods. In the pharmacological experiment, two behavior-monitoring methods, the forced swim test (FST) and the tail suspension test (TST), were used to determine the antidepressant activity of coumarin derivatives. Compounds that showed potential activity were analyzed for their effects on 5-hydroxytryptamine (5-HT) levels in the brains of mice. Molecular docking experiments to simulate the possible interaction of these compounds with the 5-HT_1A receptor was also be predicted. The results of the pharmacological experiments showed that most coumarin derivatives exhibited significant antidepressant activity. Among these compounds, 7-(2-(4-(4-fluorobenzyl)piperazin-1-yl)-2-oxoethoxy)-2H-chromen-2-one (6i) showed the highest antidepressant activity. The results of the measurement of 5-HT levels in the brains of mice indicate that the antidepressant activity of coumarin derivatives may be mediated by elevated 5-HT levels. The results of molecular docking demonstrated that compound 6i had a significant interaction with amino acids around the active site of the 5-HT_1A receptor in the homology model. The physicochemical and pharmacokinetic properties of the target compounds were also predicted using Discovery Studio (DS) 2020 and Chemdraw 14.0.     

基于AlGaN/GaN HEMT的C波段混合集成功率合成放大器的设计

研制了一种基于AlGaN/GaN HEMT的功率合成技术的混合集成放大器电路.该电路包含4个10×120 μm的HEMT晶体管以及一个Wilkinson功率合成器和分配器.在偏置条件为VDS=40V,IDS=0.9A时,输出连续波饱和功率在5.4GHz达到41.4dBm,最大的PAE为32.54%,并且功率合成效率达到69%.     

氧化铝钝化在晶体硅太阳电池中的应用

首先,回顾了氧化铝钝化技术的发展历程,对制备氧化铝钝化薄膜的手段进行了总结,并且详细描述了氧化铝的材料性质和钝化的机理。其次,指出氧化铝薄膜的优点在于优异的场效应钝化特性和良好的化学钝化性质,因此可以应用于低掺和高掺p型硅表面的钝化。此外,氧化铝薄膜及其叠层还具有良好的热稳定性,符合丝网印刷太阳电池的要求。最后,总结了氧化铝薄膜钝化技术在晶体硅太阳电池中的最新研究动态,指出氧化铝钝化薄膜用于工业生产中存在的问题,并针对这些问题提出了有效的解决方案。     

带有多层介质衬底FSS的损耗和带宽特性分析

本文简要介绍应用模匹配方法分析带有多层介质衬底的FSS频率响应技术,在此基础上研究带有多层介质衬底的平面Y形缝隙周期阵列对平面波的频率传输特性。重点讨论介质层厚度变化对FSS传输损耗及带宽的影响。