全文获取类型
收费全文 | 6978篇 |
免费 | 217篇 |
国内免费 | 1077篇 |
专业分类
化学 | 2787篇 |
晶体学 | 2篇 |
力学 | 388篇 |
综合类 | 190篇 |
数学 | 1050篇 |
物理学 | 2092篇 |
无线电 | 1763篇 |
出版年
2021年 | 1篇 |
2020年 | 2篇 |
2018年 | 1篇 |
2016年 | 9篇 |
2015年 | 37篇 |
2014年 | 49篇 |
2013年 | 72篇 |
2012年 | 76篇 |
2011年 | 1158篇 |
2010年 | 586篇 |
2009年 | 561篇 |
2008年 | 102篇 |
2007年 | 96篇 |
2006年 | 156篇 |
2005年 | 364篇 |
2004年 | 1284篇 |
2003年 | 721篇 |
2002年 | 547篇 |
2001年 | 379篇 |
2000年 | 113篇 |
1999年 | 138篇 |
1998年 | 179篇 |
1997年 | 113篇 |
1996年 | 88篇 |
1995年 | 53篇 |
1994年 | 65篇 |
1993年 | 326篇 |
1992年 | 272篇 |
1991年 | 178篇 |
1990年 | 176篇 |
1989年 | 151篇 |
1988年 | 115篇 |
1987年 | 9篇 |
1986年 | 62篇 |
1985年 | 8篇 |
1984年 | 20篇 |
1983年 | 2篇 |
1979年 | 1篇 |
1936年 | 2篇 |
排序方式: 共有8272条查询结果,搜索用时 15 毫秒
21.
22.
NianYuanTAN XiaoMingXIAO ZeLinLI TakekoMATSUMURA-INOUE 《中国化学快报》2004,15(6):687-690
A new cobalt(Ⅱ) complex with tridentate ligand 2, 6-bis (benzimidazol-2-yl)pyridine has been synthesized by microwave irradiation method and characterized by elemental analysis,electrochemical and spectral methods. The binding of the complex with calf thymus DNA has also been investigated by absorption and fluorescence spectra. 相似文献
23.
Qing An WU Zhen Yuan XU Mei ZHENG Dan Qian XU Jun XU Yin Chu SHENCollege of Chemical Engineering Materials Zhejiang University of Technology Hangzhou 《中国化学快报》2004,(7)
Six new 13-O-acylavermectin Bl aglycones(3-8) were synthesized from avermectin B1 aglycone and their bioactivities were evaluated against Spodoptera exigua, Spodoptera eridania, Tetranychus urticae and Aphis fabae. 相似文献
24.
Ri Cheng XUAN* Wei Xiao HU Zhong Yu YANG Ya Ping LU College of Pharmaceutical Sciences Zhejiang University of Technology Hangzhou 《中国化学快报》2004,(2)
2-Chloro-5-methylpyridine is an important intermediate for the preparation of biological active compounds, especially insecticides1, e.g. imidacloprid2, and is usually manufac- tured from 3-methylpyridine N-oxide. However, the manufacturing process also forms the by-products: 3-methylpyridine and its isomer 2-chloro-3-methylpyridine3. The pro- perties of the isomers are similar, it is difficult to separate by ordinary methods, such as distillation. Scheme 1 79.4%13.6%5.2%NClCH3NCH3ClNC… 相似文献
25.
Gui Hong YAN Da XING* Shi Ci TAN Institute of Laser Life Science South China Normal University Guangzhou 《中国化学快报》2004,15(1):101-104
Electrochemiluminescence (ECL), like other chemiluminescence technique, offers high signal-to-noise ratio. Furthermore, it has the advantage over other chemiluminescence techniques of being initiated by a voltage potential. Thus, it provides a better-controlled luminescence. This technique has been used in measuring many kinds of organic and inorganic matters, and analyzing many kinds of antigen, antibody and hapten, such as carcinoembryonic antigen and alpha-fetoprotein, etc1-6. The ele… 相似文献
26.
XiangGuoSHI DaFangZHONG YuMingSUN YuFengZHANG 《中国化学快报》2004,15(4):431-434
A sensitive analytical method to identify active metabolites of bitespiramycin in rat urine and bile was developed by liquid chromatography-electrospray ionization tandem mass spectrometry(LC/ESI-MS^n).Bitespiramycin and its major active metabolites in rat urine and bile were isolated and identified as M1 serial(spiramycin Ⅰ,Ⅱ,Ⅲ),M2 serial(platenomycin A1,josamycin and leucomycin A1) and M3 serial(deisovalerylplatenomycin A1,deisovaleryljosamycin,deisovalerylleucomycin A1). 相似文献
27.
DongXiangLI WanGuoHOU ShuPingLI MingTuHAO GaoYongZHANG 《中国化学快报》2004,15(2):224-227
The relation of the isoelectric point (IEP) and the point of zero net charge (PZNC) of the hydrotalcite-like compounds was discussed. It was found that the IEP does not equal to the PZNC and the IEP is higher than the PZNC. The structural positive charges existing in the HTlc,which cause the difference between the IEP and the PZNC. The effects of the structural positive charges of the HTlc on its IEP and PZNC are the same as the specific adsorption of metal cations. 相似文献
28.
Zhong Hong YAN Chun Hao YANG Xi Han WU Yu Yuan XIEDivision of Chemistry Shanghai Second Medical University Shanghai Sate Key Laboratory of Drug Research Shanghai Institute of Materia Medica Shanghai Institutesfor Biological Sciences Shanghai 《中国化学快报》2004,(4)
The first and facile synthesis of (±)syringaresinol was described. 相似文献
29.
差分式连续时间电流型CMOS跨导—电容低通滤波器 总被引:1,自引:0,他引:1
应用信号流图法对电流系统传递函数直接模拟,提出了一种新颖的差分式连续时间电流模式CMOS跨导-电容低通滤波器的实现方案。由于采用了差分式结构和电流负反馈,整个电路方案具有差分式结构和电流型电路的优点;并且仅使用最少数量的OTA和电容,与数字CMOS工艺兼容,适于全集成。面向实际电路完成了MOS管级的计算机仿真,结果表明,所提出的电路方案正确有效 相似文献
30.
JIAO Peng ZHANG Qi-han XU Jia-xi+{**} Key Laboratory of Bioorganic Chemistry Molecular Engineering of Ministry of Education College of Chemistry Molecular Engineering Peking University Beijing China 《高等学校化学研究》2006,(6)
IntroductionN,N′-Bis [1-( hydroxymethyl) alkyl] dicarboxa-mides are important intermediates for the syntheses ofbis-oxazolines, which are a class of the most importantand widely used ligands in catalytic asymmetric reac-tions[1,2]. On determining the str… 相似文献