3,7-二硝基亚氨基-2,4-二氮杂双环[3,3,0]辛烷的放热分解反应动力学

在程序升温条件下 ,用DSC研究了标题化合物的放热分解反应动力学 .用线性最小二乘法、迭代法以及二分法与最小二乘法相结合的方法 ,以积分方程、微分方程和放热速率方程拟合DSC数据 .在逻辑选择建立了微分和积分机理函数的最可几一般表达式后 ,用放热速率方程得到相应的表观活化能 (Ea)、指前因子 (A)和反应级数 (n)的值 .结果表明 :该反应的微分形式的经验动力学模式函数、Ea 和A值分别为 (1-α) 0 .44、2 30 .4kJ/mol和 10 18.16s-1.借助加热速率和所得动力学参数值 ,提出了标题化合物放热分解反应的动力学方程 .该化合物的热爆炸临界温度为 30 2 .6℃ .上述动力学参数对分析、评价标题化合物的稳定性和热变化规律十分有用 .     

Crystallographic report: catena‐Aqua(2,2′‐bipyrimidine)lithium(I) perchlorate

A lithium(I) coordination polymer has been formed from LiClO₄ and the 2,2′‐bipyrimidine (bpym) ligand in which each square pyramidal lithium(I) atom is coordinated in the basal plane by four nitrogen donor atoms derived from two bpym ligands and one water molecule at the apical position. These are connected into a layer structure via hydrogen‐bonding interactions involving the perchlorate anions. Copyright © 2004 John Wiley & Sons, Ltd.     

Generation of UV laser light by stimulated Raman scattering in D2, D2/Ar and D2/He using a pulsed Nd:YAG laser at 355nm

A pulsed Nd:YAG laser at 355nm is used to pump Raman cell filled with D_2, D_2/Ar and D_2/He. With adequately adjusted parameters, the maximum photon conversion efficiency of the first-order Stokes light (S_1, 396.796nm) reaches 33.33% in D_2/Ar and the stability of S_1 in pure D_2 is fairly high, the energy drift being less than 10% when the pump energy drifts in the range of 5%. The conversion efficiency and stability, which are functions of the composition and pressure of the Raman medium and the energy of pump laser, are investigated. The result has been used to optimize the laser transmitter system for a differential absorption lidar system to measure NO_2 concentration profiles.     

环境对MgB_2氧化过程中MgO晶须生长形状的影响

用扫描电镜研究了在 Mg B2 氧化过程中环境对 Mg O晶须生长形状的影响。仅有 Mg B2 时 ,在 80 0℃左右空气气氛中 ,可生长出纳米尺寸的 Mg O晶须。若把 Mg B2 添加到氧化铝陶瓷基体中 ,则生长成竹节状晶须。Mg O晶须生长形状的差别可能是由于氧浓度以及位错等因素造成的。     

DSSS数字接收机的AFC算法及其实现

介绍了一种零中频直接序列扩频(DSSS)数字接收机的自动频率控制(AFC)算法及其仿真和实现.该算法从残留载波跟踪解调环的鉴相信号中提取频偏信息,对下变频本振进行AFC,并且可根据对频偏的估计切换环路特性,使环路既有较大的捕获带宽,又具有较好的跟踪和滤波性能.该算法适用于无导频的直扩BPSK信号接收机,其特点是算法复杂度低,特别易于FPGA实现.     

基于DTW算法的语音识别系统实现

动态时间归整(DTW)算法的实现简单有效,在孤立词语音识别系统中得到了广泛的应用.介绍了将DTW算法移植到TMS320VC5402上实现孤立词语音识别的原理、系统硬件组成和软件设计.研究结果表明,系统能满足实时性能要求,识别效果良好.     

面向WLAN的MPC852T嵌入式系统设计

MPC852T是Motorola新近推出的MPC866/MPC859T家族中面向低端的一款通信处理器.嵌入式Linux由于其费用低廉及开放源码而具有广阔的发展前景.文中在分析了MPC852T通信处理器和嵌入式Linux操作系统的基础上,将二者结合给出了一种嵌入式硬件系统的设计与实现,以及该硬件系统在无线局域网WLAN中的一种应用.实践证明,该硬件系统具有性能稳定、廉价、可扩展性强、适用面广等优点.     

中兴宽带线路测试技术及功能介绍

宽带线路测试是中兴通讯ZXDSL综合宽带运维系统的核心功能，在DSL业务提供过程中主要应用在开通前的预测试、线路测试、开通后的例测试以及故障时的在线测试。对其测试技术和功能作了介绍。     

70K温区混合工质分凝分离循环节流制冷机实验研究

混合工质节流制冷机正在许多方面获得越来越广泛的应用。文中设计了一种新型的混合工质分凝分离循环 ,建立了实验系统 ,并在 70 K温区进行了实验。实验结果表明 ,节流制冷机可以达到 6 5 .3K的低温 ,并在 72 K温度提供 1W的制冷量 ,输入功率为 5 0 0 W。     

Spectral Anomalies in the Fraunhofer Diffraction Pattern

We study the spectral characteristics theoretically and experimentally in the Fraunhofer diffraction pattern formed by the diffraction of a spatially coherent, polychromatic light through a slit. It is found that the spectrum in some diffraction directions close to the singular direction is redshifted, compared to the spectrum of the incident polychromatic light, and blueshifted in other directions, and splits into two lines at the singular direction. We show that the experimental results are consistent with the theoretical expectations.