Polymerizable cationic iridium(III) complexes exhibiting color tunable light emission and their corresponding conducting metallopolymers

Cyclometalated iridium(III) complexes have been synthesized for use in a variety of photophysical applications, including polymer light emitting diodes (PLEDs). A series of new complexes with one electrochemically polymerizable ligand and two phenylpyridine(ppy)-based ligands have been prepared: [Ir(ppy)₂L][PF₆](1), [Ir(F-mppy)₂L][PF₆](2), and [Ir(Br-mppy)₂L][PF₆](3), where L = 3,8-bis(2,2′-bithien-5-yl)-1,10-phenanthroline. The ancillary ppy ligands can be easily varied synthetically to tune emission color of the monomer from blue–green to red. The solid state structure of complex 1 has been obtained by single crystal X-ray crystallography. Conducting polymer materials have been prepared by electropolymerization of monomers and were characterized through XPS analysis and spectroscopic studies.     

Reticular Sn nanoparticle-dispersed PAN-based carbon nanofibers for anode material in rechargeable lithium-ion batteries

Reticular tin nanoparticle-dispersed carbon (Sn/C) nanofibers were fabricated by stabilization of electrospun SnCl₄/PAN composite fibers and subsequent carbonization at different temperatures. These Sn/C composite nanofibers used as anode materials for rechargeable lithium-ion batteries (LIBs) show that the Sn/C nanofibers at 700 and 850 °C present much higher charge (785.8 and 811 mA h g^?1) and discharge (1211.7 and 993 mA h g^?1) capacities than those at 550 and 1000 °C and the as-received CNFs at 850 °C, corresponding to coulombic efficiencies of 64.9% and 81.7%, respectively. The superior electrochemical properties of the intriguing Sn/C nanofibers indicate a promising application in high performance Li-ion batteries.     

如何成就优秀的植物园科普展览

科普展览是现代人精神文化生活不可或缺的“书卷”。植物园以大量收集的活植物作为科普展览的素材向公众传播植物科学知识及开展相关的环境教育活动,帮助参观者理解人与自然的依存关系。本文详述了如何成就一个优秀的植物园科普展览的流程,希望能为成功举办植物园科普展览提供一些参考。     

丙烷脱氢反应中焙烧温度和反应气氛对 Pt-Sn/SAPO-34 催化性能的影响

 在不同的焙烧温度下制备了 Pt-Sn/SAPO-34 催化剂, 并使用 X 射线衍射、N2 吸附、X 射线荧光光谱、O2 脉冲烧炭、H2 程序升温还原和透射电镜等手段对催化剂进行了表征. 在微型反应器中评价了 Pt-Sn/SAPO-34 催化剂对丙烷脱氢制丙烯反应的催化性能, 考察了焙烧温度和反应气氛对催化剂性能的影响. 结果表明, 焙烧温度为 500 oC 时, 催化剂具有最佳的反应活性. 当焙烧温度高于 500 oC 时, 催化剂出现不希望的表面变化, 例如活性 Pt 位点的聚集、Pt 的团聚、Sn 的流失等. 当反应温度为 595 oC 时, Pt-Sn/SAPO-34 催化性能稳定, 且能够保持表面金属状态.     

A KAM Theorem for Hamiltonian Partial Differential Equations with Unbounded Perturbations

We establish an abstract infinite dimensional KAM theorem dealing with unbounded perturbation vector-field, which could be applied to a large class of Hamiltonian PDEs containing the derivative ? _x in the perturbation. Especially, in this range of application lie a class of derivative nonlinear Schrödinger equations with Dirichlet boundary conditions and perturbed Benjamin-Ono equation with periodic boundary conditions, so KAM tori and thus quasi-periodic solutions are obtained for them.     

160-Gb/s polarization-multiplexing optical NRZ-DQPSK transmission using differential detection

Using differential detection,we perform polarization-multiplexing 160-Gb/s optical non-return-to-zero(NRZ) differential quadrature phase shift keying(DQPSK) signal transmission over 100-km standard single mode fiber at a bit error rate(BER) of less than 10-9.The enabling technology includes clock recovery,fine dispersion compensation,and polarization tracking for de-multiplexing.Furthermore,a hybrid clock recovery scheme is proposed.The scheme is realized with ordinary devices using an optoelectrical modula...     

Compensation of dispersion-induced power fading for highly linear radio-over-fiber link using carrier phase-shifted double sideband modulation

A carrier phase-shifted (CPS) double sideband (DSB) modulation technique in radio-over-fiber (RoF) system is proposed and experimentally demonstrated. By tuning the biases in a single-drive dual parallel Mach-Zehnder modulator (SD-DPMZM), the optical carrier in the DSB spectrum acquires additional phase shift. The transmittance response of a dispersive RoF link is thus being controlled and shifted in the frequency domain. Experiments successfully turned the maximum transmission frequency to 10?GHz and 15?GHz for both 25 and 39?km fiber links. This is also a highly linear scheme, of which a spurious-free dynamic range (SFDR) of 111.3?dB·Hz^2/3 is experimentally obtained.     

Tunable chirped microwave photonic filter employing a dispersive Mach-Zehnder structure

A Mach-Zehnder structure with modulation in one arm and dispersive time delay in the other is proposed to implement highly flexible single-bandpass chirped microwave photonic filters based on broadband optical sources. Both the amplitude response and the time delay slope can be fully reconfigured via control of the optical spectra and dispersion. The passband can also be widely tuned without changing the shape. A chirped filter with a bandwidth of ～4?GHz, a delay slope of ～-0.6?ns/GHz, and a tunability up to 40?GHz is demonstrated experimentally.     

Tunable 360° photonic radio frequency phase shifter based on optical quadrature double-sideband modulation and differential detection

We propose a novel structure of a photonic RF phase shifter based on the vector-sum principle. The optical signal with quadrature double-sideband modulation passes through a dual-output Mach-Zehnder interferometer (MZI), and the two outputs are differentially detected. Two phase-quadrature RF terms are generated, and their amplitudes can be controlled in a triangularly complementary way by changing the phase of the MZI. A full tuning range of 0°-360° at 14?GHz is demonstrated experimentally accompanied by nearly constant RF amplitude. The validity of using our scheme in all-optical RF phase modulation is also verified.     

Applications of the molecular orbital graph theory (XI)

The tree graph method of evaluating the local molecular moment is proposed. By applying this method and the molecular moment formula of π-electron energy in the molecular orbital graph theory, a topological method of using the molecular moment to judge the relatively reactive point of even AH is achieved.