YBa2Cu3O7-y超导体的50Hz交流损耗研究

利用瓦特计技术,研究了YBa_2Cu_3O_(7-y)烧结样品和粉末熔化法(PMP)织构样品在77K和50Hz交变磁场下的交流(ac)损耗(?)实验结果表明,ac损耗(?)同外磁场振幅H_m之间遵从幂函数规律:(?)∝H_m~n对于YBa_2Cu_3O_(7-y)的烧结样品:(1)当H_m<40Oe时,这样低的磁场已穿透弱连接的晶粒边界网络,导至晶粒间的损耗,(?)∝H_m~(1.6)(2)当40Oe≤H_m<170Oe时,中等磁场破坏了晶粒间的耦合,并且磁通穿进了晶粒内,引起不完全穿透的晶粒内损耗,(? 关键词：     

聚合物光诱导电荷转移光电池的研究进展

综述了以共轭聚合物作为电子施主和 C6 0 及其衍生物作为电子受主的共混与多层器件结构的聚合物光诱导电荷转移光电池的研究进展。对这类新型结构的光电池的基本性能及机制作了介绍。低生产成本、能通过简单甩膜或印刷方式就能制备大面积器件的优势使聚合物光电池在许多实际应用领域具有广阔的前景。对今后进一步提高这类光电池的能量转换效率的研究方向进行了探讨     

Subwavelength focusing and imaging by a multimode optical waveguide

A simple subwavelength focusing system formed by a straight or bent multimode waveguide is investigated numerically. The simulation results indicate that an appropriately designed multimode waveguide can focus the outgoing waves of a point source and form an image with a full width at half-maximum of less than half a wavelength in the near-field area at the other side of the waveguide. The physical mechanism of the subwavelength focusing for this imaging system is explained.     

Study on Fourier transforms profilometry based on bi-color projecting

Projecting a bicolor sinusoidal fringe pattern consisting of two interlaced RGB format base color fringe patterns with π phase difference onto an object thought digital light projector, we can capture a deformed color pattern by color digital camera, then decode two individual sinusoidal fringe patterns with π phase difference by color-separating technique. Accessing these two fringe patterns, not only are zero-order spectra eliminated, but mask function is also built to mark valid unwrapping area in FTP, automatically.Moreover, because the wrapped phase just inside the valid areas is needed unwrapping, we can mark these areas with mask function, which avoids the error transferring resulting from unwrapping the invalid areas and shortens the unwrapping time. Furthermore, in Fourier transform processing, the full-field deformed fringe pattern generally needed to guarantee measurement precision can be formed by expanding non-full-field fringe pattern captured using the mask function.     

与偏振无关双向2×2和4×4自由空间光开关

利用成熟的偏振控制技术，设计了一种由偏振光分束器、相位型空间光调制器和反射镜构成的2×2光开关，该光开关所用器件少，具有结构简单紧凑、控制灵活方便、功能实现与信号光的偏振态无关以及可以双向交换等特点；在此基础上通过2×2光开关的串连，设计了一种与偏振无关的双向4×4光开关的实验模块，根据其路由选择与控制方法，得到了4×4光开关实现信号光全排列无阻塞输出与交换对应的路由状态表，并对该实验模块的功能实现进行了详细的分析与讨论。     

Metal-free C(sp3)–H functionalization of sulfonamides via strain-release rearrangement

With the increasing awareness of sustainable chemistry principles, the development of an efficient and mild strategy for C(sp³)–H bond activation of nitrogen-containing compounds without the utilization of any oxidant and metal is still highly desired and challenging. Herein, we present a metal-free reaction system that enables C–H bond functionalization of aliphatic sulfonamides using DABCO as a promoter under mild conditions, affording a series of α,β-unsaturated imines in good yields with high selectivities. This protocol tolerates a broad range of functionalities and can serve as a powerful synthetic tool for the late-stage modification of complex compounds. More importantly, control experiments and detailed DFT calculations suggest that this process involves [2 + 2] cyclization/ring-cleavage reorganization, which opens up a new platform for the establishment of other related reorganization reactions.

The mild base-promoted C−H bonds functionalization of amides to obtain α,β-unsaturated imines in good yields with high chemoselectivities was achieved. Control experiments show this process involves [2 + 2] cyclization/ring-cleavage reorganization.     

一类近红外电致发光芴基共聚物的合成和性能研究

基于9,9-二辛基芴与窄带隙单体5,7-二(2-噻吩基)噻[3,4-b]并[1,4]二嗪(DTP),通过Suzuki偶合反应,合成了一系列无规窄带隙的芴基共聚物(PFO-DTP),并对它们的紫外-可见吸收光谱、光致发光和电致发光性能进行了初步研究.共聚物在380 nm和632 nm处有两个明显的吸收峰,其中632 nm处的吸收随着共聚物中窄带隙单体(DTP)含量的增加而加强,最大电致发光峰随着共聚物中窄带隙单体(DTP)含量的增加,从752nm红移到了781 nm.同时与其同分异构体4,7-二(2-噻吩基)苯并噻二唑(DBT)与芴的共聚物PFO-DBT相比,该类聚合物的吸收红移,与近地太阳光谱更为匹配.     

激光片光三维传感中降低散斑影响的新方法

提出一种激光片光三维传感中降低散斑影响的新方法,片光面内扫描合成孔径法。通过向被测物体表面投射面内扫描的片状激光束,产生空间变化的动态散斑光场,这样的光场在成像透镜光瞳平面上的移动,其时间平均效果等效于利用了一个大的“合成孔径”,降低了散斑的影响,明显地提高了测量精度。文中给出了合成孔径的理论分析和三维面形测量的实验结果。     

Advanced poly-Si TFT with fin-like channels by ELA

The advanced low-temperature polysilicon (poly-Si) thin-film transistor with three-dimensional channels of fin-like profile has been demonstrated using excimer laser annealing and unique undercut structure without any additional patterning process. This approach provides a very narrow fin-like channel in devices with high ratio of film thickness to the width as well as a high-quality poly-Si film in channels with better crystallinity for the effect of columnar-like grain growth following the shrinkage of silicon stripe after laser irradiation. Due to that and the stronger electrical stress on the channel by the multigate, the new device with a fin-like channel structure shows good characteristics of the highest mobility up to 395 cm/sup 2//V/spl middot/s, a subthreshold voltage slope below 400 mV/dec, and an ON-OFF current ratio higher than 10/sup 6/.     

The self-assembly of dialdehyde-cellulose-nanofiber-based hydrogels with high compression resilience

Cellulose - Cellulose-nanofiber-based hydrogels (CNF-Gel) exhibit excellent mechanical properties and designable functions. However, it is difficult to coordinate the complex self-assembly...