Dispersion-Enabled Symmetry Switching of Photonic Angular-Momentum Coupling

Photonic spin-orbit interactions describe the interactions between spin angular momentum and orbital angular momentum of photons, which play essential roles in subwavelength optics. However, the influence of frequency dispersion on photonic angular-momentum coupling is rarely studied. Here, by elaborately designing the contribution of the geometric phase and waveguide propagation phase, the dispersion-enabled symmetry switching of photonic angular-momentum coupling is experimentally demonstrated. This notion may induce many exotic phenomena and be found in enormous applications, such as the spin-Hall effect, optical calculation, and wavelength division multiplexing systems. As a proof-of-concept demonstration, two metadevices, a multi-channel vectorial vortex beam generator and a phase-only hologram, are applied to experimentally display optical double convolution, which may offer additional degrees of freedom to accelerate computing and a miniaturization configuration for optical convolution without collimation operation. These results may provide a new opportunity for complex vector optical field manipulation and calculation, optical information coding, light-matter interaction manipulation, and optical communication.     

基于高光谱激光雷达的滞尘叶片光谱特征分析

城市绿植为城市生态系统提供自净功能, 起到净化空气以及滞尘降尘等多种环境保护作用, 而滞尘等因素也 会对绿植产生影响。为了研究滞尘对城市绿植叶片光谱特征的影响, 采集了四种常绿绿植 (八角金盘、石楠、香樟和 玉兰) 叶片样本, 使用高光谱激光雷达系统获取高光谱点云数据, 分析了滞尘对叶片光谱特征的影响。分析结果表明: 对于不同种类叶片, 滞尘对可见光波段反射率均有较大影响; 对于同种类叶片, 滞尘对近红外波段的反射率差异影响 较大, 可见光波段的反射率差异为 1.21%∼3.41%, 近红外为 1.76%∼8.49%; 线性四点内插法计算和光谱导数分析表明 滞尘对四种叶片的红边位置无显著影响; 四种叶片的叶面水含量指数 (LWI) 对滞尘的响应程度最小 (均小于 3.7%), 而 比值植被指数 (RVI) 对滞尘的响应程度最大 (除香樟外, 均大于 20.0%), 红边指数 (SDr)、简单比值指数 (SR) 和叶面叶 绿素指数 (LCI) 的响应程度稳定性较差。进一步建立了滞尘植被指数和响应程度的线性相关性拟合模型并进行了检 验, 其中以 LCI 为自变量建立的模型为最稳定拟合模型, 可表示为 y = −1.527x + 0.6597, 决定系数约为 0.88。     

基于ARM的机载火控雷达元器件自动化检测技术研究

为解决传统技术针对机载火控雷达元器件检测吞吐率低的问题,设计基于ARM的机载火控雷达元器件自动化检测技术。确定机载火控雷达元器件自动化检测特征,基于ARM响应曲线拟合机载火控雷达元器件检测数据,表达其自动化检测特征属性值,以此实现机载火控雷达元器件自动化检测。设计实例分析,结果表明,设计检测技术检测吞吐率均在3reqs/s以上,对比传统手段具有明显的优势,能够解决传统检测技术检测吞吐率低的问题。     

超细粉Pb0.75Ca0.25[(Ni1/3Nb2/3)0.08Ti0.912Mn0.008]O3的制备与表征

报道了用化学共沉淀法制备掺杂Ca、Ni、Nb、Mn钛酸铅超细陶瓷粉末的方法。制得的粉料化学式为:Pb_0.75Ca_0.25[(Ni_1/3Nb_2/3)_0.08Ti_0.912Mn_0.008]O₃,粒径小于0.1μm,所有的掺杂元素均能定量掺入。     

Dehydrogenation activities of highly dispersed transition metal oxides on NaY zeolite

Highly dispersed α-Fe_2O_3/NaY,NiO/NaY,and CuO/NaY catalyst systems were pre-pared by impregnation method.Dispersion thresholds of the transition metal oxides on NaY" zeolitewere determined by XRD phase analysis.The dispersion capacities of the transition metal oxides on NaYzeolite are much lower than that estimated on the basis of a closed packed monolayer in the micropores.The catalytic activity and selectivity of the highly dispersed oxide catalyst systems for ethylben-zene and cyclohexane dehydrogenation reactions were reported.     

Polymer bound glutamic acid salicylaldehyde Schiff‐base complex ­catalyst for oxidation of olefins with ­dioxygen

The polymer bound Schiff‐base ligand (PS‐SalGlu) has been prepared from polystyrene bound salicylaldehyde and glutamic acid, and its complex (PS‐SalGlu‐Co) has also been synthesized. The polymer ligand and its complex were characterized by infrared spectroscopy, small area X‐ray photoelectron spectroscopy, and inductively coupled plasma‐atomic emission spectro (ICP‐AFS). In the presence of the complex, cyclohexene can be effectively oxidized by molecular oxygen without reductant. The long‐chain linear aliphatic olefins, such as 1‐octene, 1‐decene, 1‐dodecene and 1‐tetradecene, can be directly oxidized by molecular oxygen catalyzed by PS‐SalGlu‐Co, which affords the 1,2‐epoxy alkane. Copyright © 2001 John Wiley & Sons, Ltd.     

四(2─咪唑基)卟啉在水溶液中的性质及其在乙酸中与Co(Ⅱ)(OAc)2的反应动力学研究

合成了水溶性四（２－咪唑基）卟啉，研究了它在水溶液中的聚合性质。实验发现Ｈ２ＴＩｍＰ水溶液在ＰＨ＝０，６时遵守Ｂｅｅｒ定律，并呈单体形式存在。用光谱滴定法测定了Ｈ２ＴＩｍＰ加质子的平衡常数。用紫外可见分光光度计研究了在乙酸溶剂中Ｈ２ＴＩｍＰ与Ｃｏ（Ⅱ）（ＯＡｃ）２反应的动力淡。     

气相色谱质谱法快速测定人血浆中克仑特罗

血浆样品经0.01mol·L-1盐酸和无水乙醇浸取,在碱性条件下用氯仿萃取,GG-MS-选择离子测量法测定,外标法定量。在选定的色谱条件下,盐酸克仑特罗的检出限为0.05ng,线性范围为0.1-100ng,方法的平均回收率为95.6％,RSD小于6.82％(n=6)。该法毋需衍生化,基质无干扰,简便可靠,适用于生物材料中克仑特罗的快速分析。     

Ionic limiting molar conductivity calculation of Li-ion battery electrolyte based on mode coupling theory

A method is proposed based on mode coupling theory in which the ion transference number is introduced into the theory. The ionic limiting molar conductivities of LiPF6, LiClO4, LiBF4, LiCF3SO3, Li(CF3SO3)2N, LiC4F9SO3, and LiAsF6 in PC(propylene carbonate), GBL(gamma-butyrolactone), PC(propylene carbonate)/EMC(ethylmethyl carbonate), and PC(propylene carbonate)/DME(dimethoxyethane) are calculated based on this method, which does not involve any adjustable parameter. The results fit well to the literature data which are calculated by an empirically adjusted formula. This presents a potential way to calculate the conductivities of Li-ion battery electrolytes.     

Self-assembly of gold nanoparticles on fullerene nanospheres

A C60-pyrrolidine derivative with a hydrophobic-hydrophilic-hydrophobic structure (2-{3,4-di{2-[2-(2-decyloxyethoxy)ethoxy]ethoxy}}phenyl-3,4-fulleropyrrolidine, DTPF) has been synthesized and well-characterized. This compound could form stable nanospheres by simply injectingits tetrahydrofuran (THF) solution into water and then removing THF by purging gaseous nitrogen in sequence. Novel nanoassemblies of DTPF nanospheres and gold nanoparticles were obtained through in situ photoreduction of aqueous HAuCl4 in the presence of DTPF nanospheres, which were confirmed by UV-visible, transmission electron microscopy, X-ray powder diffraction, and X-ray photoelectron spectroscopy methods. It is proposed that the interaction between the positively charged nitrogen atom and the gold nanoparticles is the main driving force for the formation of the nanoassemblies.