全文获取类型
收费全文 | 133786篇 |
免费 | 25810篇 |
国内免费 | 12463篇 |
专业分类
化学 | 87443篇 |
晶体学 | 1208篇 |
力学 | 4794篇 |
综合类 | 661篇 |
数学 | 10432篇 |
物理学 | 30137篇 |
无线电 | 37384篇 |
出版年
2024年 | 408篇 |
2023年 | 2335篇 |
2022年 | 3310篇 |
2021年 | 4131篇 |
2020年 | 5390篇 |
2019年 | 6248篇 |
2018年 | 4327篇 |
2017年 | 4124篇 |
2016年 | 7721篇 |
2015年 | 8371篇 |
2014年 | 9238篇 |
2013年 | 11128篇 |
2012年 | 11416篇 |
2011年 | 10554篇 |
2010年 | 9109篇 |
2009年 | 9122篇 |
2008年 | 8895篇 |
2007年 | 7582篇 |
2006年 | 6853篇 |
2005年 | 6306篇 |
2004年 | 4962篇 |
2003年 | 4195篇 |
2002年 | 4735篇 |
2001年 | 3630篇 |
2000年 | 3201篇 |
1999年 | 2476篇 |
1998年 | 1682篇 |
1997年 | 1607篇 |
1996年 | 1503篇 |
1995年 | 1288篇 |
1994年 | 1114篇 |
1993年 | 930篇 |
1992年 | 761篇 |
1991年 | 693篇 |
1990年 | 545篇 |
1989年 | 403篇 |
1988年 | 330篇 |
1987年 | 253篇 |
1986年 | 241篇 |
1985年 | 200篇 |
1984年 | 142篇 |
1983年 | 132篇 |
1982年 | 97篇 |
1981年 | 62篇 |
1980年 | 48篇 |
1979年 | 28篇 |
1977年 | 23篇 |
1976年 | 27篇 |
1975年 | 31篇 |
1957年 | 21篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
81.
82.
Reducing the complexity of distance measurement methods for circular turbo codes that use structured interleavers
下载免费PDF全文
![点击此处可从《International Journal of Communication Systems》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Youssouf Ould‐Cheikh‐Mouhamedou 《International Journal of Communication Systems》2015,28(9):1572-1579
The knowledge of turbo code's minimum Hamming distance (dmin) and its corresponding codeword multiplicity (Amin) is of a great importance because the error correction capability of a code is strongly tied to the values of dmin and Amin. Unfortunately, the computational complexity associated with the search for dmin and Amin can be very high, especially for a turbo code that has high dmin value. This paper introduces some useful properties of turbo codes that use structured interleavers together with circular encoding. These properties allow for a significant reduction of search space and thus reduce significantly the computational complexity associated with the determination of dmin and Amin values. © 2014 The Authors. International Journal of Communication Systems published by John Wiley & Sons, Ltd. 相似文献
83.
Triazines are widely used in agriculture around the world as selective pre‐ and post‐emergence herbicides for the control of broad leaf and grassy weeds. With high toxicity and persistence, triazines can contaminate the environment and crops, so the development of rapid and sensitive methods for the determination of different triazines is necessary. Capillary electrophoresis comprises a group of techniques used to separate chemical mixtures. Analytical separation is based on different electrophoretic mobilities. This review focuses on the analysis of triazine herbicides with different modes of capillary electrophoresis, including capillary zone electrophoresis, micellar electrokinetic capillary electrophoresis, capillary electrochromatography and nonaqueous capillary electrophoresis. Determinations of triazines in various matrices such as surface water, groundwater, vegetables, soil and grains are emphasized. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
84.
85.
Liming Fan Feng Wang Dongsheng Zhao Yuxin Peng Yuxin Deng Yinwei Luo Xiutang Zhang 《应用有机金属化学》2020,34(12):e5960
Guided by the self-penetrating features can improve the stability of metal organic frameworks (MOFs), an unprecedented 3D self-penetrated framework, {[Zn (tptc)0.5(bimb)]·H2O}n ( NUC-6 , here NUC corresponding to North University of China), with 3D (4,4)-c {86} net, was designed. Benefit from the high chemical stability and excellent luminescent property, NUC-6 can be act as an efficient multi-response chemo-sensor in detecting dichloronitroaniline pesticide and nitrofuran antibiotics in water with the detection limits are 116 ppb for DCN pesticide, 16 ppb for NFT antibiotic, and 12 ppb for NTZ antibiotic. Besides, the mechanisms of luminescence quenching were revealed from the viewpoint of internal filter effect (IFE) and photo-induced electron transfer (PET), implied by the optical spectroscopy and quantum chemical calculation. This work provides a promising strategy to design stable MOFs by improving the self-penetrating features and to expand their practical applications in the detection of organic pollutants in aqueous medium. 相似文献
86.
Jia Yang Xingang Li Wenjun Li Xin Xi Qian Du Feng Pan Songqing Liu 《Biomedical chromatography : BMC》2020,34(8):e4857
Because of its unpredictable side effects and efficacy, the anticancer drug docetaxel (DTX) requires improved characterisation of its pharmacokinetic profiles through population pharmacokinetic studies. A sensitive and rugged LC–MS/MS method for the detection of DTX in human plasma was developed and optimised using paclitaxel as an internal standard (IS). The plasma samples underwent rapid extraction using hybrid solid-phase extraction-protein precipitation. The analyte and IS were separated with an isocratic system on a Zorbax Eclipse Plus C18 column using water containing 0.05% acetic acid along with 20 μM of sodium acetate and methanol (30/70, v/v) as the mobile phase. Quantification was performed using a triple quadrupole mass spectrometer through multiple reaction monitoring in positive mode, using the m/z 830.3 → 548.8 and m/z 876.3 → 307.7 transitions for DTX and paclitaxel, respectively. The range of the calibration curve was 1–500 ng/mL for DTX, and the linear correlation coefficient was >0.99. The accuracies ranged from −4.6 to 4.2%, and the precision was no higher than 7.0% for the analytes. No significant matrix effect was observed. Both DTX and the IS showed considerable recovery. This method was finally applied to the establishment of a population pharmacokinetic model to optimise the clinical use of DTX. 相似文献
87.
88.
Dr. Wan‐Ling Liu Ni‐Shin Yang Ya‐Ting Chen Stephen Lirio Cheng‐You Wu Prof. Chia‐Her Lin Prof. Hsi‐Ya Huang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(1):115-119
A green and sustainable strategy synthesizes clinical medicine warfarin anticoagulant by using lipase‐supported metal–organic framework (MOF) bioreactors (see scheme). These findings may be beneficial for future studies in the industrial production of chemical, pharmaceutical, and agrochemical precursors. 相似文献
89.
Chao Liu Liying Wang Lin Yang Famei Wang Chunhong Xu Jingwei Lv Guanglai Fu Xianli Li Qiang Liu Haiwei Mu Tao Sun Paul K. Chu 《Physics letters. A》2019,383(25):3200-3206
A single-polarization filter comprising a gold-coated photonic crystal fiber based on surface plasmon resonance is designed and investigated. The pattern matching and coupled polarization characteristics analyzed by the full-vector finite element method (FEM) and losses at 1,540 nm are achieved to 1,016.01739 dB/cm (x-pol core mode) and 33.81917 dB/cm (y-pol core mode). The crosstalk (CT) value of the 1,540 nm band is ?853.12653 dB for fiber length and the bandwidth is 850 nm. The working wavelength of the filter ranges from 1,280 nm to 1,540 nm by varying the diameter of outer air holes (), the diameter of inner air holes (), the metal film thickness (t), as well as the liquid refractive index (n). 相似文献
90.
Yeong‐Tarng Shieh Pei‐Yu Tai Chih‐Chia Cheng 《Journal of polymer science. Part A, Polymer chemistry》2019,57(21):2149-2156
Poly(methyl methacrylate) (PMMA) nanoparticles with a sensitive CO2‐responsive hydrophilic/hydrophobic surface that confers controlled dispersion and aggregation in water were prepared by emulsion polymerization at 50 °C under CO2 bubbling using amphiphilic diblock copolymers of 2‐dimethylaminoethyl methacrylate (DMAEMA) and N‐isopropyl acrylamide (NIPAAm) as an emulsifier. The amphiphilicity of the hydrophobic–hydrophilic diblock copolymer at 50 °C was triggered by CO2 bubbling in water and enabled the copolymer to serve as an emulsifier. The resulting PMMA nanoparticles were spherical, approximately 100 nm in diameter and exhibited sensitive CO2/N2‐responsive dispersion/aggregation in water. Using copolymers with a longer PNIPAAm block length as an emulsifier resulted in smaller particles. A higher concentration of copolymer emulsifier led to particles with a stickier surface. Given its simple preparation and reversible CO2‐triggered amphiphilic behavior, this newly developed block copolymer emulsifier offers a highly efficient route toward the fabrication of sensitive CO2‐stimuli responsive polymeric nanoparticle dispersions. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019, 57, 2149–2156 相似文献