瞬态荧光方法研究溶剂诱导的三苯胺衍生物的对称性破缺电荷转移动力学

在缺乏特征红外振动的情况下追踪具有四极或八极对称性分子的激发态对称性破缺电荷转移通常是很困难的.本文以一种具有八极对称性的三苯胺衍生物为研究对象,利用飞秒时间分辨瞬态荧光光谱方法获得发光跃迁偶极矩的演化动力学,进而实时表征了其溶剂诱导对称性破缺电荷转移的动力学过程.当该分子处于弱极性甲苯溶液中时,在激发态弛豫过程中其发射偶极矩变化较小;当处于较强极性的四氢呋喃溶液中时,其发射偶极矩在数皮秒内快速减小.在对比单体偶极分子的荧光动力学后,推断八极分子的发光态在强极性溶剂中经历溶剂诱导的结构变化,由激子耦合的八极对称性降低至激发定域的偶极对称性;而在较弱极性的溶剂中,其八极对称性在溶剂化稳定中得以较大程度的保持.     

Calculation of the wide-angle neutron spectra from the ~9Be(d,xn) reaction in a thick beryllium target

The multi-layer computing model is developed to calculate wide-angle neutron spectra, in the range from0° to 180° with a 5° step, produced by bombarding a thick beryllium target with deuterons. The double-differential cross-sections(DDCSs) for the ~9 Be(d, xn) reaction are calculated using the TALYS-1.8 code. They are in agreement with the experimental data, and are much better than the PHITS-JQMD/GEM results at 15°, 30°, 45° and 60° neutron emission angles for deuteron energy of 10.0 MeV. In the TALYS-1.8 code, neutron contributions from direct reactions(break-up, stripping and knock-out reactions) are controlled by adjustable parameters, which describe the basic characteristics of typical direct reactions and control the relative intensity and the position of the ridgy hillock at the tail of DDCSs. It is found that the typical calculated wide-angle neutron spectra for different neutron emission angles and neutron angular distributions agree quite well with the experimental data for 13.5 MeV deuterons. The multi-layer computing model can reproduce the experimental data reasonably well by optimizing the adjustable parameters in the TALYS-1.8 code. Given the good agreement with the experimental data, the multi-layer computing model could provide better predictions of wide-angle neutron energy spectra, neutron angular distributions and neutron yields for the ~9 Be(d, xn) reaction neutron source.     

The Linear Optical Unambiguous Discrimination of Hyperentangled Bell States Assisted by Time Bin

A linear optical unambiguous discrimination of hyperentangled Bell states is proposed for two‐photon systems entangled in both the polarization and momentum degrees of freedom (DOFs) assisted by time bin. This unambiguous discrimination scheme can completely identify 16 orthogonal hyperentangled Bell states using only linear optical elements, where the function of the auxiliary entangled Bell state is replaced by time bin. Moreover, the possibility of extending this scheme for distinguishing hyperentangled Bell states in n DOFs is discussed, and it shows that $2^{n+k+1}$ hyperentangled Bell states in n ( $n\ge 2$) DOFs can be distinguished with k ( $k<n$) auxiliary entangled states of additional DOFs by introducing a time delay, which decreases the auxiliary entanglement resource required for unambiguous discrimination of hyperentangled Bell state. Therefore, this scheme provides a new way for distinguishing hyperentangled states with current technology, which will extend the application of discrimination of hyperentangled states via linear optics to other quantum information protocols besides hyperdense coding schemes in the future.     

Numerical simulation on the operational characteristics of the pulsed inductive acceleration

To analyse the ionization and acceleration properties of an inductive plasma excited by a pulsed current flowing through the planar coil, the extended GLM formulations of the MHD (EGLM‐MHD) model, combined with the high‐temperature thermodynamic and transport model, is employed to simulate the characteristics of the flow. The two‐dimensional axisymmetric calculation captures the generation, growth, and acceleration of the current sheet, and the process is completed in the first half period. The sheet is mainly comprised of lower ionization level ions in the front and higher level ions at the back, and the density is one order higher than that of the residual plasma on the coil surface. As the abscissa value of the sheet is larger than the decoupling distance, a reversed flow emerges, generating a backward impulse, and the negative velocity can be more than 15 km/s at peak intensity B₀ = 0.5 T. In the second 1/4 period, the magnetic field and current density distribute non‐linearly on the surface and regularly in the sheet, caused by the reversing of the changing rate of the magnetic field and the particles' radial diffusion. The results at different intensities show that, for the same coil size, the time at which the maximum velocity V_max appears is advanced as the intensity increases, and V_max can be greater than 20 km/s above 0.5 T.     

基于机器视觉的量子点STM形貌图像识别研究

为减轻量子点表面形貌分析过程中的人工工作,使量子点的STM图像分析更加自动化,基于机器视觉对衬底的斜切角及量子点的形貌特性展开研究.利用腐蚀和边缘检测提取台阶形状,并通过反三角变换计算斜切角.利用二值化和阈值下降对量子点的数量与空间坐标进行提取,在此基础上,通过邻域密度计算分析其均匀性,并在解决图像中的粘连问题后找出量子点的尺寸.实验结果显示,与人工统计相比,斜切角、量子点计数及尺寸的平均误差分别为5.02%, 0.7788%及1.12%;并实现量子点均匀性的自动化统计与分析.基于机器视觉算法的自动识别过程,对协助研究者分析量子点表面形貌有实际意义.     

Effects of the triple junction types on the grain boundary carbide precipitation in a nickel-based superalloy,a statistical analysis

The morphology evolution of carbide precipitated on grain boundary nearby different triple junctions in grain boundary engineering (GBE) treated nickel-based Inconel Alloy 690 aged at 715°C for different time was investigated by scanning electron microscopy and electron backscatter diffraction. The results show that, the diversity of triple junction types was increased by GBE significantly. The size and morphology of grain boundary carbide were not only affected by the grain boundary character, but also the nearby grain boundary character at the triple junction. The higher Σ values of the nearby grain boundaries, the larger carbide precipitated on the other grain boundary. Based on the experimental results, the effects of grain boundary characters and triple junction types on the carbide precipitation behaviours are discussed.     

Fabrication of VO_2 thin film by rapid thermal annealing in oxygen atmosphere and its metal–insulator phase transition properties

Vanadium dioxide thin films have been fabricated through sputtering vanadium thin films and rapid thermal annealing in oxygen. The microstructure and the metal–insulator transition properties of the vanadium dioxide thin films were investigated by X-ray diffraction, X-ray photoelectron spectroscopy, and a spectrometer. It is found that the preferred orientation of the vanadium dioxide changes from(1ˉ11) to(011) with increasing thickness of the vanadium thin film after rapid thermal annealing. The vanadium dioxide thin films exhibit an obvious metal–insulator transition with increasing temperature, and the phase transition temperature decreases as the film thickness increases. The transition shows hysteretic behaviors, and the hysteresis width decreases as the film thickness increases due to the higher concentration carriers resulted from the uncompleted lattice. The fabrication of vanadium dioxide thin films with higher concentration carriers will facilitate the nature study of the metal–insulator transition.     

Rational doping for zinc oxide and its influences on morphology and optical properties

Zinc oxide(ZnO) nanopowders doped with different metal ions(Me, Me = Sn4+, In3+, Mn2+, and Co2+) are prepared by a simple sol–gel method. Influences of the ion doping on morphology and optical properties of the resulting ZnxMeyO are investigated by scanning electron microscopy, X-ray diffraction, UV-vis absorption spectrum, and photoluminescence. The morphology of ZnO can be tailored by ion doping, which is closely related not only to the ionic radii and electronegativities of the doped ions, but also to their oxidation states and electron configurations. The optical band gap and photoluminescence of ZnO can also be modulated by ion doping, which results from a combination of different effects, Burstein–Moss, band tail, charge compensation, sp–d exchange, non-radiative recombination, and blocking barrier. This may offer us a viable approach to tuning the(optical) properties of ZnO-based materials via rational ion doping.     

Micromagnetic simulation of Sm–Co/α-Fe/Sm–Co trilayers with various angles between easy axes and the film plane

Hysteresis loops and energy products have been calculated systematically by a three-dimensional(3D) software OOMMF for Sm–Co/α-Fe/Sm–Co trilayers with various thicknesses and β, where β is the angle between the easy axis and the field applied perpendicular to the film plane. It is found that trilayers with a perpendicular anisotropy possess considerably larger coercivities and smaller remanences and energy products compared with those with an in-plane anisotropy.Increase of β leads to a fast decrease of the maximum energy product as well as the drop of both remanence and coercivity. Such a drop is much faster than that in the single-phased hard material, which can explain the significant discrepancy between the experiment and the theoretical energy products. Some modeling techniques have been utilized with spin check procedures performed, which yield results in good agreement with the one-dimensional(1D) analytical and experimental data, justifying our calculations. Further, the calculated nucleation fields according to the 3D calculations are larger than those based on the 1D model, whereas the corresponding coercivity is smaller, leading to more square hysteresis loops and better agreement between experimental data and the theory.     

Influence of roughness on the detection of mechanical characteristics of low-k film by the surface acoustic waves

The surface acoustic wave （SAW） technique is a precise and nondestructive method to detect the mechanical charac- teristics of the thin low dielectric constant （low-k） film by matching the theoretical dispersion curve with the experimental dispersion curve. In this paper, the influence of sample roughness on the precision of SAW mechanical detection is inves- tigated in detail. Random roughness values at the surface of low-k film and at the interface between this low-k film and the substrate are obtained by the Monte Carlo method. The dispersive characteristic of SAW on the layered structure with rough surface and rough interface is modeled by numerical simulation of finite element method. The Young＇s moduli of the Black DiamondTM samples with different roughness values are determined by SAWs in the experiment. The results show that the influence of sample roughness is very small when the root-mean-square （RMS） of roughness is smaller than 50 nm and correlation length is smaller than 20 μm. This study indicates that the SAW technique is reliable and precise in the nondestructive mechanical detection for low-k films.