Rheological Behavior for Mica-filled Polypropylene Composite Melts

The study on rheological properties of a series of mica-filled polypropylene (PP) composites was carried out. The influence of surface-treatment of mica particles on dynamic rheological behavior of the composites were dealt with. The viscosity (η) and dynamic modulus ( G‘ ) of the composite melts were higher than those of PP matrix, especially those for systems treated with silane, which was attributed to the interfacial adhesion enhancement. However, surface-treatment of mica by titanate resulted in lower η and G‘, as compared with the treatment by silane. The reason for this is believed to be the formation of the mono-molecular layer on the mica surface.     

Large third-order nonlinear optical properties of C70 fullerene in the infrared regime

The nonlinear third-order optical susceptibility of C₇₀ in a toluene solution is measured for the first time by the method of degenerate four-wave mixing using 10 ns laser pulses at 1.06 m. The third-order susceptibility X _in ⁽³⁾ is 5.6×10^–12 esu for a C₇₀ toluene solution at a concentration of 0.476 g/l. The correspondent magnitude of the hyperpolarizability ₁₁₁₁ of the C₇₀ molecule is 1.2×10^–30 esu which is in a good agreement with the prediction given by the model of a free electron in a spherical box.     

A dual-electrode approach for highly selective detection of glucose based on diffusion layer theory: experiments and simulation

A dual-electrode configuration for the highly selective detection of glucose in the diffusion layer of the substrate electrode is presented. In this approach, a glassy carbon electrode (GCE, substrate) modified with a conductive layer of glucose oxidase/Nafion/graphite (GNG) was used to create an interference-free region in its diffusion layer by electrochemical depletion of interfering electroactive species. A Pt microelectrode (tip, 5 microm in radius) was located in the diffusion layer of the GNG-modified GCE (GNG-G) with the help of scanning electrochemical microscopy. Consequently, the tip of the electrode could sense glucose selectively by detecting the amount of hydrogen peroxide (H2O2) formed from the oxidization of glucose on the glucose oxidase layer. The influences of parameters, including tip-substrate distance, substrate potential, and electrolyzing time, on the interference-removing efficiency of this dual-electrode approach have been investigated systematically. When the electrolyzing time was 30 s, the tip-substrate distance was 1.8 a (9.0 microm) (where a is the radius of the tip electrode), the potentials of the tip and substrate electrodes were 0.7 V and 0.4 V, respectively, and a mixture of ascorbic acid (0.3 mM), uric acid (0.3 mM), and 4-acetaminophen (0.3 mM) had no influence on the glucose detection. In addition, the current-time responses of the tip electrode at different tip-substrate distances in a solution containing interfering species were numerically simulated. The results from the simulation are in good agreement with the experimental data. This research provides a concept of detection in the diffusion layer of a substrate electrode, as an interference-free region, for developing novel microelectrochemical devices.     

Complexation of plutonium(IV) with sulfate at variable temperatures

The complexation of plutonium(IV) with sulfate at variable temperatures has been investigated by solvent extraction method. A NaBrO₃ solution was used as holding oxidant to maintain the plutonium(IV) oxidation state throughout the experiments. The distribution ratio of Pu(IV) between the organic and aqueous phases was found to decrease as the concentrations of sulfate were increased. Stability constants of the 1:1 and 1:2 Pu(IV)-HSO₄ ⁻ complexes, dominant in the aqueous phase, were calculated from the effect of [HSO₄ ⁻] on the distribution ratio. The enthalpy and entropy of complexation were calculated from the stability constants at different temperatures using the Van’t Hoff equation.     

Shift-full-rank matrices and applications in space-time trellis codes for relay networks with asynchronous cooperative diversity

To achieve full cooperative diversity in a relay network, most of the existing space-time coding schemes require the synchronization between terminals. A family of space-time trellis codes that achieve full cooperative diversity order without the assumption of synchronization has been recently proposed. The family is based on the stack construction by Hammons and El Gamal and its generalizations by Lu and Kumar. It has been shown that the construction of such a family is equivalent to the construction of binary matrices that have full row rank no matter how their rows are shifted, where a row corresponds to a terminal (or transmit antenna) and its length corresponds to the memory size of the trellis code on that terminal. We call such matrices as shift-full-rank (SFR) matrices. A family of SFR matrices has been also constructed, but the memory sizes of the corresponding space-time trellis codes (the number of columns of SFR matrices) grow exponentially in terms of the number of terminals (the number of rows of SFR matrices), which may cause a high decoding complexity when the number of terminals is not small. In this paper, we systematically study and construct SFR matrices of any sizes for any number of terminals. Furthermore, we construct shortest (square) SFR (SSFR) matrices that correspond to space-time trellis codes with the smallest memory sizes and asynchronous full cooperative diversity. We also present some simulation results to illustrate the performances of the space-time trellis codes associated with SFR matrices in asynchronous cooperative communications.     

A 10-bit 44-MS/s 20-mW configurable time-interleaved pipeline ADC for a dual-mode 802.11b/Bluetooth receiver

This work presents a configurable time-interleaved pipeline architecture as an efficient solution for the ADC design in high data rate multi-standard radios. The ADC is implemented in a 0.25-/spl mu/m BiCMOS process as part of an integrated dual mode 802.11b/Bluetooth direct conversion receiver. Its structure can be configured to accommodate the different sampling rate and dynamic range requirements of both standards. The different techniques employed at the system and circuit levels to optimize the power consumption are described. An on-line digital calibration scheme is also incorporated to assure the conversion linearity and reduce mismatch among the parallel branches. The proposed ADC is a switched-capacitor implementation occupying an area of 2.1 mm/sup 2/. It achieves 60 dB/64 dB dynamic range at 44 MHz/11 MHz sampling frequency with a power consumption of 20.2 mW/14.8 mW for the 802.11b/Bluetooth baseband signals.     

采用栅格理论的多机器人系统任务元管理方法

以目标为研究对象以及传统的传感器管理方法已难以满足多机器人系统中的多传感器管理研究,但如果将目标与系统任务状态结合为目标任务状态,以其对应的任务元作为研究对象会使复杂系统简单化,而基于栅格理论的管理网络也可以有效地管理不同层次不同类别的任务元.并且可以实时地监测多机器人协同工作系统任务元权重的变化情况.首先将栅格网络中每一层的目标元素对应为多机器人系统不同级别的工作任务;其次从顶层开始,逐一确定上层任务包含哪些下层任务;然后采用基于离差最大化的多属性决策方法确定任务元的权重概率,最后以一简单算例验证该管理方法的简单有效.     

铝及铝合金用钎剂的发展现状和趋势

综述了铝及铝合金用钎剂的发展概况.根据其组织结构和表面特性分析了钎剂在焊接时必须具备的独特性能,依此详细介绍了铝用钎剂的种类和优缺点.同时也对钎剂焊接时的作用机理作了深入探讨,最后阐述了铝及铝合金钎剂的未来研究方向.