烯烃聚合数学模拟研究与现状

综述了近年来国内外在烯烃聚合微观形态和宏观反应器数学模拟方面取得的研究成果，指出了烯烃聚合过程数学模拟的发展方向。     

褪黑素的电化学氧化行为及伏安法测定

采用电化学方法研究了褪黑素在金电极上的不可逆氧化行为.结果表明：其伏安过程为受弱吸附和扩散共同控制的过程,氧化反应电荷转移数为2.采用伏安法对褪黑素进行测定,方法的检出限可达10^-10ml/L数量级.方法可用于脑白金胶囊中褪黑素含量的测定.     

痤疮患者血清中微量元素含量的变化

测定了52例痤疮患者血清Ca,Mg,Zn,Cu,Fe五种元素的含量。结果表明，痤疮患者血清Zn水平显著低于正常人（P＜0．001），血清Ca,Mg,Cu,Fe水平则与正常人无差别（P＞0．05）。部分病人口服补充锌剂后痤疮症状有所好转。提示痤疮患者应重视体内微量元素含量的变化，并做适当的补充。     

温度对贮氢合金MlNi3.75Co0.65Mn0.4Al0.2动力学性能的影响

在-20℃～85℃的范围内系统地研究了温度对贮氢合金MINi3.75Co0.65Mn0.4Al0.2动力学性能的影响.结果表明:该贮氢合金电极的电化学反应电阻Rt,欧姆内阻Ro,阴极极化过电位,阳极极化过电位,阳极极化过程中的电化学反应过电位ηa和浓差极化过电位ηa均随温度的升高而减小,该电极的交换电流密度i0,对称因子β和电极中氢的扩散系数D随温度的升高而增大.当放电电流密度较低时,电化学反应是整个电极过程的速度控制步骤;当放电电流密度较高时,氢的扩散是整个电极过程的速度控制步骤;在中等放电电流密度下,电极过程由电化学过程和氢的扩散过程混合控制.该电极中电化学反应过程和氢扩散过程的活化能分别为28.1 kJ·mol-1和19.9 kJ·mol-1.     

Correlation Analysis of the Runoff of the Rivers and the Seisms in China

In recent hundred years the annual discharge variations of the Changjiang River (represented by the Yichang station) and the Huanghe River (represented by Shanxian and Tangnaihe, respectively) have closely related to the geographical distribution of the earthquakes coming about in China in the same year, Both the occurrence of the destructive seism or seismic swarm in the river basins and the disappearance of the shocks in the east and south of the basins are the conditions that the Changjiang and Huanghe Rivers are the high flow while that the strong earthquake of magnitude 7 or more occurred in North China is the condition for the Changjiang low flow year and that of 6 or more in the Qilian Mountains area is for the Huanghe River. In the latter part of this paper, a 2-year sample is given to explain that the conditions of the 2 rivers being high flow years are that the north-south seismic belt is active and in the meanwhile no seism occurred in South China, and those of the low flow year are that the     

Controlled/“Living “Radical Polymerization of(-)-Menthyl Methacrylate

The atom transfer radical polymerization(ARP)of (-)-menthyl methacrylatc((-)-MnMA) mediated by CuCl/bipyridine and ethy1 2-bromopropionate or 1-phenylethyl bromide in THF system has been studied.The dependence of the specific rotation on molecular weight and the CD of Poly((-)-MnMA) thus obatined was investigated.     

微波固相法合成钠快离子导体Na5YSi4O12

应用微波方法合固相反应难于制备的Ｎａ５ＹＳｉ４Ｏ１２纯相，讨论了微波合成条件对产物的影响，与溶胶－凝胶法相比，微波法反应速率快，选择性强，合成的样品具有特异的聚集态，缺陷和微结构，从而导致离子导电活化能下降。     

猴头菇微量元素含量的分析

用电感耦合等离子体发射光谱仪（ICP-AES）测定了湛江市栽培的猴头茹微量元素的含量，发现其磷、硫、钙、镁、锌、铁、铜等元素的含量都比较丰富，并讨论了这些有益元素与人体健康的关系。     

抗生育植物栀子花化学成分的研究：Ⅱ.栀子花甲酸的结构

我们已报道从栀子(Gardenia jasminoidesEllis)花的乙酸乙酯提取物中分得一种对大鼠有明显抗早孕作用的新三萜酸——栀子花乙酸(1),本文继续报道从该提取物中分得的另一种新三萜酸——栀子花甲酸(Gardenolicacid A,以下简称甲酸,2)的结构。 2为白色针状结晶,m.p.212～214℃,Liebermann-Burchard试验阳性,[α]_D~(17) 38.3,C_(30)H(46)O_(4),属三萜类。