核磁共振弛豫速率方法测定模拟正铁色素的结构

在生命体系内正铁色素具有摄铁和输铁的功能,人工合成的模拟化合物具备了正铁色素的主要功能基团和相近的性质.本工作利用铁(Ⅲ)离子的顺磁性质,测定不同铁(Ⅲ)离子浓度下模拟正铁色素的诱导弛豫时间,根据简化了的Solomon—B1oemoergen公式,计算出铁(Ⅲ)离子到所有被测质子(即氢原子)的相对距离,比较清楚地得到模拟正铁色素在溶液中的构象。     

光抽运双光子激光朗之万量子理论

本文采用朗之万量子理论获得光抽运双光子激光具有双光子损耗时的朗之万方程,进一步获得稳态平均光子数、频率牵引、线宽和动态斯塔克效应,对激光增益来源的分析表明,非相干抽运仅有单双光子两步过程有贡献,而相干抽运,除上述过程外还有单双光子一步过程有贡献,而且,上述两个过程都受到负反馈和饱和因子的制约,线宽与稳态平均光子数无关。 关键词：     

On the design of broadband quasioptical systems for submillimeter-wave radio-astronomy receivers

In this paper, we summarize the issues that should be considered when designing broadband quasioptical systems for submillimetre-wave radioastronomy receivers. We cover topics such as bandwidth, cross-talk, truncation, and aberrations, and we argue that it should be possible to manufacture high-efficiency systems that have several octaves of bandwidth. A key feature of the paper is that we use the language of multimode Gaussian optics throughout, and in this way, we emphasize that a receiver is a diffraction-limited imaging system rather than just a collection of components for guiding Gaussian beams. The whole discussion is conducted in terms of a particular system we are constructing for the James Clerk Maxwell Telescope in Hawaii.     

Magnetic resonance imaging and pulsed Doppler sonography of poststenotic jets: Correlation between signal void and flow velocity distribution

To correlate the appearance of poststenotic jets on gradient echo images with features of localized Doppler spectra of the jets, we studied an in vitro model of steady flow-through stenoses of 86, 96, and 99% area reduction. As fluids, water and a 40% glycerol solution in water were used. MRI was performed with a 1.5 T whole body imager and gradient echo images were obtained in planes parallel to the direction of flow. Doppler spectra were acquired separately from the MR measurements at 1 cm intervals for a distance of 10 cm downstream from the stenosis. Poststenotic signal void was observed for water and for the 40% glycerol solution only if the mean velocity within the stenosis exceeded a limit of 50–60 cm/sec. On the MR images, the jets could be divided into two segments: A proximal jet segment of uniform width equal to the diameter of the stenosis, followed by a distal jet segment which was characterized by broadening and then dissipating signal void. Except for the 99% stenosis, a high signal intensity core was present within the proximal jet segment. In the proximal jet segment, the Doppler measurements showed a low temporal fluctuation of the maximal flow velocity and only little flow opposite to the main flow direction. In the distal jet segment, the velocity fluctuation and the intensity of reverse flow increased sharply. The high signal intensity core of the jet was associated with a poststenotic zone of constant maximal flow velocity. The results demonstrate a close relationship between characteristic features of poststenotic jets in MRI and pulsed Doppler sonography.     

混合流体浸润相变的研究(Ⅲ)——二元系统的四相共存态

本文讨论二元Sullivan系统的一个特殊状态——二元四相系的浸润相变性质,该系统的许多性质可以通过对两个二元二相系的讨论而得到。结果表明:这一系统同时存在一级相变和二级相变。 关键词：     

延长速调管使用寿命的方法

描述了一种延长EPR波谱仪中速调管使用寿命的方法.根据这种方法,只要正确地调谐微波桥的工作状态和适当地调整功率电平器的功率校正电平.即使对于已经严重老化的速调管仍然可以继续使用一段时间,维持仪器的正常运行.     

Testing deviations from the inverse square law with a freely falling gravity gradiometer at balloon altitudes

Summary We discuss a null experiment to search for the fifth force at ranges around 10 km. It is proposed to use a three-axis gravity gradiometer to measure the trace of the Earth gravity tensor from a freely falling elevator dropped by a balloon. The main error sources are considered to some extent. Paper presented at the V Cosmic Physics National Conference, S. Miniato, November 27–30, 1990.     

塞曼石墨炉原子吸收光谱法测定粉尘降尘中痕量锡

以KOH熔样,又以KOH作基体改进剂,研究了测定锡的灰化温度、原子化行为和消除干扰及试样前处理的方法,以KOH熔解的粉尘及降尘样液,特别适用于塞曼石墨炉的测定,背景可完全扣除。方法简便、快速、准确,灵敏度和精度高。相对标准偏差为4.0%,回收牢在96.4～110%范围内。     

Evolution of the Alfvénic correlation in the solar wind

Summary The radial evolution of Alfvénic correlation is such that its value decreases with increasing heliocentric distance. So far this behaviour has been interpreted as an increase in the local production of ?inward? modes interacting destructively with the ?outward? modes. This work, which deals with largescale turbulence, shows that local generation phenomena are not commonly found in the solar wind and that the Alfvénic character of the fluctuations mainly depend on the ?outward? modes alone. The interaction of these modes with density and/or magnetic-field structures convected by the wind causes their destruction and a consequent depletion of the Alfvénic correlation. The same effect would be obtained if ?inward? modes were really present. Our conclusions are that large-scale ?inward? modes are the spectral counterpart of non-propagating field and plasma structures convected by the solar wind and identified as both compression regions and pressure balance structures. Paper presented at the V Cosmic Physics National Conference, S. Miniato, November 27–30, 1990.     

Na2SbF5晶体倍频系数的理论计算

本文使用阴离子基团理论计算了Na₂SbF₅晶体的倍频系数,得到d₁₂₃=4.48×10^-10esu,与实验值符合较好。计算结果表明,阴离子基团中孤对电子的存在有利于产生大的倍频效应。本文还分析了Na₂SbF₅晶体倍频系数小的原因:尽管(SbF₅)^2-基团存在孤对电子可以对晶体倍频系数有较大贡献,但孤对电子能级的相对位置对其倍频系数有不利影响,从而导致它的倍频系数d₁₂₃较小。 关键词：