Carbene-catalyzed activation of cyclopropylcarbaldehydes for mannich reaction and δ-lactam formation: remote enantioselecitvity control and dynamic kinetic asymmetric transformation

An N-heterocyclic carbene(NHC)-catalyzed enantioselective Mannich reaction of the remote γ-carbon of cyclopropylcarbaldehydes is disclosed for the first time. Diastereo-and enantiomerically enriched multicyclic δ-lactam compound is afforded as the main product from 8 possible stereo-specific isomers through dynamic kinetic asymmetric transformation(DYKAT) processes. Multiple chiral functional molecules can be afforded from the lactam products through simple protocols with retentions of the optical purities.     

下一代互联网真实地址寻址技术实现及试验情况

随着网络规模的不断扩大和应用方式的多样化,互联网在安全可信方面正面临着挑战.作为可信任下一代互联网的重要基础,研究真实地址寻址技术具有十分重要的意义.本文从体系结构出发,对真实地址寻址结构各个层面的技术实现进行了说明,并介绍了基于CNGI-CERNT2的真实地址寻址试验网.     

CMMB运营支撑系统设计方案思考

本文针对移动多媒体广播（CMMB）业务运营支撑系统的建设原则和系统结构体系进行了初步探讨,并对CMMB的业务模型进行了简要介绍。     

The working mechanism of organic photovoltaic cell by using copper phthalocyanine as exciton blocking layer

We demonstrate the working mechanism of organic photovoltaic (OPV) cell with copper phthalocyanine (CuPc) as exciton blocking layer (EBL). The new EBL material CuPc, commonly has been used as electron donor in the organic solar cells due to its electron-donating and hole-transporting properties. But here we proves that the α-polymorph CuPc layer can transfer electrons to Al cathode through the half-filled b_1g level, this mechanism is different from that of general EBL material with larger band gap and electron-transporting property, which is based on damage states induced by the heat of evaporating Al.     

新型Sb基二类超晶格红外探测器

InAs/Ga(In)SbⅡ类超晶格材料由于特殊的二型能带结构,可以通过人造低维结构获得类似于体材料的带间吸收,从而获得较高的量子效率;另外,通过调节材料参数调节能带结构,器件响应波段可调;通过能带结构设计抑制俄歇复合,获得较小的暗电流和较高的器件性能。因为以上特有的材料性能和器件特性,Sb基二类超晶格在国际上被认为是第三代红外焦平面探测器的优选材料。对二类超晶格材料的设计和器件特性进行了研究,设计了峰值波长4μm的nBn结构的中波红外探测器,在没有蒸镀抗反膜的条件下,77 K温度下测试得到的峰值探测率为2.4×1011cm Hz1/2W-1,计算得到的量子效率为47.8%,峰值探测率已经接近目前的碲镉汞中波红外探测器器件性能。研究结果充分显示了二类超晶格优越的材料和器件性能。     

通信电源设计中创新思想的探讨

在分析创新思想在通信电源设计中的意义和重要作用的基础上,通过5个应用案例阐述了创新思想在通信电源设计中的应用。     

On the Drinfeld-Sokolov hierarchy of type E(1)6 and its topological solution

In this paper we report some explicit evolutionary PDEs of the Drinfeld-Sokolov hierarchy of type E(1)6,and show how the unknown functions in these PDEs are rel...     

Transition-metal-free synthesis of 1,4-benzoxazepines via [4+3]-cycloaddition of para-quinone methides with azaoxyallyl cations

A formal[4+3]-cycloaddition reaction of ortho-hydroxyphenyl-substituted para-quinone methides(p-QMs)with in-situ generated azaoxyallyl cations is reported.The reaction occurs under very mild reaction conditions(transition-metal free,room temperature,cheap inorganic base)and provides a very efficient route to a series of biologically important 1,4-benzoxazepine derivatives in good to excellent yields.     

Terahertz Direct Modulation Techniques for High-speed Communication Systems

Terahertz communication technology can provide abundant frequency resources,strong confidentiality,antijamming capability,communication tracking capability and ...     

Decomposition Reaction of Zn-MPA（3-Mercaptopropionic Acid） Complex Under Microwave Irradiation

The thermal decomposition of Zn-MPA complex was investigated under microwave irradiation. ZnO and ZnS nanocrystals could be obtained by decomposing Zn-MPA（3-mercaptopropionic acid） complex under different reaction conditions. It was found that both the pH value of the solution and the molar ratio of Zn2＋ and MPA can play an important role in the formation of ZnO and ZnS nanocrystals. MPA mainly acts as an S source or as a complexing agent. This study provides a new route for the controllable preparation of semiconductor nanocrystals.