Spreading resistance correction formula more suited for the Gauss-Laguerre quadrature

A modified formula is derived for the calculation of the correction factor in spreading resistance measurements. Due to its better convergence this formulation yields more accurate results when the Gauss-Laguerre quadrature formulae are used for the integration. In this way the obtained accuracy is found to be always better than 0.15% compared to 1.3% when the classic formulation is used. A very high accuracy for the correction factor is shown to be very important since an error of 2% in the correction factors may result in a 16% error in the derived resistivities.The CPU time when using the new formula is always smaller than or equal to the time used for the classic formulation and is typically about 15 seconds on a IBM 3033 computer for the calculation of 300 points.     

Microwave spectra of CH314NC and CH315NC in the 3ν8 state

The microwave spectra of methyl isocyanide and its ¹⁵N derivative in the 3ν₈ state have been observed from 40 to 180 GHz. After the assignment by a graphical method, the analysis has been carried out, first by the reuse of analytical formulas and then by the diagonalization of the energy matrix. Many accidental resonances have been shown to occur between the l = ±1 states, and A₁A₂ doublings for K, l = ±3, ±3 have been discovered. A set of constants in the 3ν₈ state is given for each molecule.     

An efficient method for the fabrication of temperature-sensitive hydrogel microactuators

In this article a new method for the photolithographical deposition of temperature-sensitive hydrogels is presented. The method can be used in conjunction with standard 365 nm UV-photolithography to accurately dimension and position temperature-sensitive hydrogel microactuators in a highly parallel fashion. A number of characteristics of the hydrogels were investigated. These include: the photolithographical reproduction quality, the effect of the crosslinking density in the hydrogels on their swelling behavior, the swelling hysteresis behavior, the effect of dimensional constraints on the swelling of the hydrogels and the effect of copolymerization with an ionizable comonomer on the temperature behavior of the hydrogels. The method presents a considerable improvement in the microfabrication of temperature-sensitive hydrogel microactuators and has potential for the mass-fabrication of these interesting microactuators.     

Monolithic catalysts for the fixed-bed hydrogenation of polymers

Monolithic catalysts were successfully applied in a true fixed-bed hydrogenation of polymers such as SBS rubbers and polystyrene.     

Dynamical diseases of brain systems: different routes to epileptic seizures

In this overview, we consider epilepsies as dynamical diseases of brain systems since they are manifestations of the property of neuronal networks to display multistable dynamics. To illustrate this concept we may assume that at least two states of the epileptic brain are possible: the interictal state characterized by a normal, apparently random, steady-state electroencephalography (EEG) ongoing activity, and the ictal state, that is characterized by paroxysmal occurrence of synchronous oscillations and is generally called, in neurology, a seizure. The transition between these two states can either occur: 1) as a continuous sequence of phases, like in some cases of mesial temporal lobe epilepsy (MTLE); or 2) as a sudden leap, like in most cases of absence seizures. In the mathematical terminology of nonlinear systems, we can say that in the first case the system's attractor gradually deforms from an interictal to an ictal attractor. The causes for such a deformation can be either endogenous or external. In this type of ictal transition, the seizure possibly may be anticipated in its early, preclinical phases. In the second case, where a sharp critical transition takes place, we can assume that the system has at least two simultaneous interictal and ictal attractors all the time. To which attractor the trajectories converge, depends on the initial conditions and the system's parameters. An essential question in this scenario is how the transition between the normal ongoing and the seizure activity takes place. Such a transition can occur either due to the influence of external or endogenous factors or due to a random perturbation and, thus, it will be unpredictable. These dynamical changes may not be detectable from the analysis of the ongoing EEG, but they may be observable only by measuring the system's response to externally administered stimuli. In the special cases of reflex epilepsy, the leap between the normal ongoing attractor and the ictal attractor is caused by a well-defined external perturbation. Examples from these different scenarios are presented and discussed.     

Ultra-Low-Power Interface Chip for Autonomous Capacitive Sensor Systems

Traditionally, most of the sensor interfaces must be tailored towards a specific application. This approach results in a high recurrent design cost and time to market. On the other hand, generic sensor interface design reduces the costs and offers a handy solution for multisensor applications. This paper presents a generic sensor interface chip (GSIC), which can read out a broad range of capacitive sensors. It contains capacitance-to-voltage converters, a switched-capacitor amplifier, an analog-to-digital converter, oscillators, clock generation circuits and a reference circuit. The system combines a very low-power design with a smart energy management, which adapts the current consumption according to the accuracy and speed requirements of the application. The GSIC is used in a pressure and an acceleration monitoring system. The pressure monitoring system achieves a current drain of 2.3 muA for a 10-Hz sample frequency and an 8-bit accuracy. In the acceleration monitoring system, we measured a current of 3.3 muA for a sample frequency of 10 Hz and an accuracy of 9 bits     

Freezing Transitions in Non-Fellerian Particle Systems

Non-Fellerian particle systems are characterized by nonlocal interactions, somewhat analogous to non-Gibbsian distributions. They exhibit new phenomena that are unseen in standard interacting particle systems. We consider freezing transitions in one-dimensional non-Fellerian processes which are built from the abelian sandpile additions to which in one case, spin flips are added, and in another case, so called anti-sandpile subtractions. In the first case and as a function of the sandpile addition rate, there is a sharp transition from a non-trivial invariant measure to the trivial invariant measure of the sandpile process. For the combination sandpile plus anti-sandpile, there is a sharp transition from one frozen state to the other anti-state.     

On the Validity of Entropy Production Principles for Linear Electrical Circuits

We explain the (non-)validity of close-to-equilibrium entropy production principles in the context of linear electrical circuits. Both the minimum and the maximum entropy production principles are understood within dynamical fluctuation theory. The starting point are Langevin equations obtained by combining Kirchoff’s laws with a Johnson-Nyquist noise at each dissipative element in the circuit. The main observation is that the fluctuation functional for time averages, that can be read off from the path-space action, is in first order around equilibrium given by an entropy production rate. That allows to understand beyond the schemes of irreversible thermodynamics (1) the validity of the least dissipation, the minimum entropy production, and the maximum entropy production principles close to equilibrium; (2) the role of the observables’ parity under time-reversal and, in particular, the origin of Landauer’s counterexample (1975) from the fact that the fluctuating observable there is odd under time-reversal; (3) the critical remark of Jaynes (1980) concerning the apparent inappropriateness of entropy production principles in temperature-inhomogeneous circuits.     

Pd-catalyzed intramolecular direct arylations at high temperature

Pd-catalyzed cyclodehydrohalogenation involving oxidative addition of aromatic C-Br or activated azaheteroaromatic C-Cl bonds and C(sp²)-H activation have been investigated at high reaction temperatures (180-200 °C). This allowed the fast (10-30 min) synthesis of a variety of azaheteroaromatic ring systems (dibenzo[f,h]phthalazine, dibenzo[f,h]cinnoline, benzofuro[2,3-d]pyridazine, 5H-pyridazino[4,5-b]indole, 7H-indolo[2,3-c]quinoline and 5H-δ-carboline) in moderate to good yields.     

On the channel-length dependence of the hot-carrier degradation ofn-channel MOSFETs

The channel-length dependence of lifetime plots is analyzed. It is shown that no unique τ*I_d versus I_sub/I_d relation can be obtained when threshold-voltage shifts are used for measuring the lifetime. In contrast, when using charge pumping as a monitor for the degradation, the lifetime plot for a given technology proves to be independent of the channel length